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Copper(II) complexes with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane: Synthesis, spectroscopic study, and crystal structure

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Abstract

New complexes of copper(II) nitrate, chloride, tetrafluoroborate, perchlorate, and perrhenate with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane (L) were obtained. The molecular and crystal structures of [CuL(H2O)(NO3)2] · (CH3)2CO, [CuL2(H2O)][CuL2Cl][CuCl4], [CuL2](BF4)2 · (CH3)2CO, and [CuL2(H2O)](ClO4)2 · (CH3)2CO were determined by X-ray diffraction analysis. In all the complexes, L was found to serve as a chelating bidentate ligand through the N2 and N2′ atoms of its pyrazole rings to form a six-membered chelate ring.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    E. V. Lider, E. V. Peresypkina, L. G. Lavrenova, E. G. Boguslavskii, A. I. Smolentsev & L. A. Sheludyakova

  2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    L. G. Lavrenova

  3. Institute of Chemical Kinetics and Combustion, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    O. L. Krivenko & S. F. Vasilevskii

Authors
  1. E. V. Lider
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  2. E. V. Peresypkina
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  3. L. G. Lavrenova
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  4. O. L. Krivenko
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  5. E. G. Boguslavskii
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  6. A. I. Smolentsev
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  7. L. A. Sheludyakova
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  8. S. F. Vasilevskii
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Corresponding author

Correspondence to E. V. Lider.

Additional information

Original Russian Text © E.V. Lider, E.V. Peresypkina, L.G. Lavrenova, O.L. Krivenko, E.G. Boguslavskii, A.I. Smolentsev, L.A. Sheludyakova, S.F. Vasilevskii, 2009, published in Koordinatsionnaya Khimiya, 2009, Vol. 35, No. 6, pp. 442–453.

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Lider, E.V., Peresypkina, E.V., Lavrenova, L.G. et al. Copper(II) complexes with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane: Synthesis, spectroscopic study, and crystal structure. Russ J Coord Chem 35, 433–444 (2009). https://doi.org/10.1134/S1070328409060086

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  • DOI: https://doi.org/10.1134/S1070328409060086

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