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Cubane pyridine-acetylacetonate cluster complexes with the M3CuS 5+4 core (M = Mo, W)

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Abstract

The reactions between [Mo3(μ3-S)(μ2-S)3(Acac)3(Py)3]PF6 (HAcac is acetylacetone, Py is pyridine) and CuX (X = Cl, I, SCN) afford heterometallic cubane clusters [Mo3(CuX)(μ3-S)4(Acac)3(Py)3]PF6. The structures of two new compounds, [Mo3(CuCl)S4(Acac)3(Py)3]PF6 · 3.25CH2Cl2 · 0.5C6H5CH3 and [Mo3(CuI)S4(Acac)3(Py)3]PF6 · 4C6H6, are determined by X-ray diffraction analysis. All synthesized compounds are characterized by elemental analysis and IR spectra. According to the vibrational spectra, the thiocyanate complex in the solid state is a mixture of the bond isomers [Mo3(CuNCS)S4(Acac)3(Py)3]PF6 and [Mo3(CuSCN)S4(Acac)3(Py)3]PF6, whereas in solution this complex exists as a isothiocyanate form.

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References

  1. Llusar, R. and Uriel, S., Eur. J. Inorg. Chem., 2003, p. 1271.

  2. Andres, J., Feliz, M., Fraxedas, J., et al., Inorg. Chem., 2007, vol. 46, p. 2159.

    Article  CAS  Google Scholar 

  3. Feliz, M., Guillamon, E., Llusar, R., et al., Chem.-Eur. J., 2006, vol. 12, p. 1486.

    Article  CAS  Google Scholar 

  4. Feliz, M., Garriga, J.M., Llusar, R., et al., Inorg. Chem., 2001, vol. 40, p. 6132.

    Article  CAS  Google Scholar 

  5. Feliz, M., Llusar, R., Uriel, S., et al., Inorg. Chim. Acta, 2003, vol. 349, p. 69.

    Article  CAS  Google Scholar 

  6. Zheng, Y., Zhang, H., and Wu, X., Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 1989, vol. 45, p. 1990.

    Article  Google Scholar 

  7. Wu, X., Lu, S., Zu, L., et al., Inorg. Chim. Acta, 1987, vol. 133, p. 39.

    Article  CAS  Google Scholar 

  8. Lu, S., Chen, H., Huang, J., et al., Inorg. Chim. Acta, 1995, vol. 232, p. 43.

    Article  CAS  Google Scholar 

  9. Diller, H., Keck, H., Kuchen, W., et al., Z. Naturforsch., A: Phys. Sci., 1993, vol. 48, p. 291..

    Google Scholar 

  10. Diller, H., Keck, H., and Wunderlich, H., J. Organomet. Chem., 1995, vol. 489, p. 123.

    Article  CAS  Google Scholar 

  11. Herbst, K., Monari, M., and Brorson, M., Inorg. Chim. Acta, 2004, vol. 357, p. 895.

    Article  CAS  Google Scholar 

  12. Hegetschweiler, K., Worle, M., Meienberger, M.D., et al., Inorg. Chim. Acta, 1996, vol. 250, p. 35.

    Article  CAS  Google Scholar 

  13. Shibahara, T. and Akashi, H., Inorg. Chim. Acta, 1998, vol. 282, p. 50.

    Article  Google Scholar 

  14. Akashi, H. and Shibahara, T., Inorg. Chim. Acta, 2000, vol. 300, p. 572.

    Article  Google Scholar 

  15. Shibahara, T., Akashi, H., and Kuroya, H., J. Am. Chem. Soc., 1988, vol. 110, p. 3313.

    Article  CAS  Google Scholar 

  16. Nasreldin, M., Li, Y.-J., Mabbs, F.E., et al., Inorg. Chem., 1994, vol. 33, p. 4283.

    Article  CAS  Google Scholar 

  17. Hernandez-Molina, R., Sokolov, M., Esparza, P., et al., Dalton Trans., 2004, p. 847.

  18. Gushchin, A.L., Kovalenko, K.A., Sokolov, M.N., et al., Izv. Akad. Nauk, Ser. Khim., 2007, p. 1635.

  19. Mikhalychko, B.M., Temkin, O.N., and Mys’kin, M.G., Usp. Khim., 2000, vol. 69, p. 1042.

    Google Scholar 

  20. Hernandez-Molina, R., Sokolov, M., Clegg, W., et al., Inorg. Chim. Acta, 2002, vol. 331, p. 52.

    Article  CAS  Google Scholar 

  21. Karyakin, Yu.V. and Angelov, I.I., Chistye Khimicheskie Veshchestva (Pure Chemical Substances), Moscow: Khimiya, 1974.

    Google Scholar 

  22. APEX2 (version 1.08), SAINT (version 7.03), SADABS (version 2.11), Bruker Advanced X-Ray Solutions, Madison (WI, USA): Bruker AXS Inc., 2004.

  23. SHELXTL (version 6.12), Bruker Advanced X-ray Solutions, Madison (WI, USA): Bruker AXS Inc., 2004.

  24. Nakamoto, K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, New York: Wiley, 1997.

    Google Scholar 

  25. Mitchell, P.C.H. and Williams, R.J.P., J. Chem. Soc., 1960, p. 1912.

  26. Sabatini, A. and Bertini, I., Inorg. Chem., 1965, vol. 4, p. 959.

    Article  CAS  Google Scholar 

  27. Jianhui, W., Nianyong, Z., Shaowu, D., et al., Inorg. Chim. Acta, 1991, vol. 185, p. 181.

    Article  Google Scholar 

  28. Zanina, A.S., Shergina, S.I., Sokolov, I.E., et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1981, no. 5, p. 1158.

  29. Xintao, W., Shaofeng, L., and Liangyong, Z., Inorg. Chim. Acta, 1987, vol. 133, p. 39.

    Article  Google Scholar 

  30. Xintao, W., Yifan, Z., Nianyong, Z., et al., Jiegou Huaxue, 1988, vol. 7, p. 137.

    Google Scholar 

  31. Shaofang, L., Nianyong, Z., Xintao, W., et al., J. Mol. Struct., 1989, vol. 197, p. 15.

    Article  Google Scholar 

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    A. L. Gushchin, M. N. Sokolov, K. A. Kovalenko, E. V. Peresypkina, A. V. Virovets, N. I. Alferova & V. P. Fedin

  2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    A. L. Gushchin, M. N. Sokolov, K. A. Kovalenko & V. P. Fedin

Authors
  1. A. L. Gushchin
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  2. M. N. Sokolov
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  3. K. A. Kovalenko
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  4. E. V. Peresypkina
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  5. A. V. Virovets
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  6. N. I. Alferova
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  7. V. P. Fedin
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Correspondence to M. N. Sokolov.

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Original Russian Text © A.L. Gushchin, M.N. Sokolov, K.A. Kovalenko, E.V. Peresypkina, A.V. Virovets, N.I. Alferova, V.P. Fedin, 2009, published in Koordinatsionnaya Khimiya, 2009, Vol. 35, No. 6, pp. 403–409.

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Gushchin, A.L., Sokolov, M.N., Kovalenko, K.A. et al. Cubane pyridine-acetylacetonate cluster complexes with the M3CuS 5+4 core (M = Mo, W). Russ J Coord Chem 35, 395–400 (2009). https://doi.org/10.1134/S1070328409060013

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  • DOI: https://doi.org/10.1134/S1070328409060013

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