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Synthesis and characterization of two charge-transfer salts based on Keggin-type polyoxometalates and morpholinebiguanide

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Abstract

Two new inorganic-organic salts, formulated as (C6H13N5OH)2 [HPMo12O40] · 5H2O and (C6H13N5OH)3[PW12O40], were synthesized and characterized by elemental analysis, IR, ESR, diffuse reflectance spectra, thermogravimetry, and X-ray photoelectron spectroscopy. Solid diffuse reflectance spectra showed charge-transfer interactions between the inorganic and organic moieties in the solid state. Salt I had strong photosensitivity for UV light or X-ray irradiation, and its photochromic reaction under UV light was found to exhibit first-order kinetics.

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References

  1. Pope, M.T. and Muller, A., Angew. Chem., Int. Ed. Engl., 1991, vol. 30, p. 34.

    Article  Google Scholar 

  2. Wang, E.B., Hu, C.W., and Xu, L., Concise Polyoxometallates, Beijing: Chemical Industry, 1998, p. 1.

    Google Scholar 

  3. Pavani, K., Lofland, S.E., Ramanujachary, K.V., et al., Eur. J. Inorg. Chem., 2007, p. 568.

  4. Xia, Y., Wu, P.F., Wei, Y.G., et al., Cryst. Growth Des., 2006, vol. 6, p. 253.

    Article  CAS  Google Scholar 

  5. Niu, J.Y., You, X.Z., Duan, C.Y., et al., Inorg. Chem., 1996, vol. 14, p. 4211.

    Article  Google Scholar 

  6. Wang, J.P., Han, Q.X., and Niu, J.Y., Transition Met. Chem., 2004, vol. 29, p. 170.

    Article  CAS  Google Scholar 

  7. Han, Z.G., Zhao, Y.L., Peng, J., et al., Electrochim. Acta, 2005, vol. 51, p. 218.

    Article  CAS  Google Scholar 

  8. You, W.S., Zhu, Z.M., Wang, E.B., et al., J. Chem. Crystallogr., 2006, vol. 30, p. 577.

    Article  Google Scholar 

  9. Gamelas, J.A.F., Santos, F.M., Felix, V., et al., Dalton Trans., 2006, p. 1197.

  10. Liu, S.Z., Ku, Z.J., Wang, Z., et al., Chin. J. Inorg. Chem., 1999, vol. 15, no. 2, p. 263.

    Google Scholar 

  11. Liu, S.Z., Wang, Z., Ku, Z.J., et al., Chin. J. Inorg. Chem., 1999, vol. 15, no. 5, p. 652.

    CAS  Google Scholar 

  12. Galvan-Tejada, N., Bernes, S., Castillo-Blum, S.E., et al., J. Inorg. Biochem., 2002, vol. 91, p. 339.

    Article  CAS  Google Scholar 

  13. He, T. and Yao, J.N., Prog. Mater. Sci., 2006, vol. 51, p. 810.

    Article  CAS  Google Scholar 

  14. Feng, W., Ding, Y.S., Liu, Y., et al., Mater. Chem. Phys., 2006, vol. 98, p. 347.

    Article  CAS  Google Scholar 

  15. Pope, M.T., Heteropoly and Isopoly Oxometalates, Berlin: Springer, 1983, p. 109.

    Google Scholar 

  16. Gamelas, J.A.F., Cavaleiro, A.M.V., Gomes, E.D., et al., Polyhedron, 2002, vol. 21, p. 2537.

    Article  CAS  Google Scholar 

  17. Huang, Y., Pan, Q.Y., Dong, X.W., et al., Mater. Chem. Phys., 2006, vol. 97, p. 431.

    Article  CAS  Google Scholar 

  18. Yamase, T., Chem. Rev., 1998, vol. 98, p. 307.

    Article  CAS  Google Scholar 

  19. Han, Z.B., Wang, E.B., Luan, G.Y., et al., J. Mater. Chem., 2002, vol. 12, p. 1169.

    Article  CAS  Google Scholar 

  20. Kawato, T., Koyama, H., Kanatomi, H., et al., J. Photochem., 1985, vol. 28, no. 1, p. 103.

    Article  CAS  Google Scholar 

  21. Liu, L., Jia, D.Z., Ji, Y.L., et al., J. Photochem. Photobiol., A: Chem., 2003, vol. 254, no. 1, p. 117.

    Article  Google Scholar 

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Authors and Affiliations

  1. College of Chemistry and Materials Sciences, Xiaogan University, Xiaogan, 432000, P.R. China

    Z. J. Ku & H. B. Zhou

  2. College of Science, Wuhan University of Technology, Wuhan, 430070, P.R. China

    S. R. Jin

Authors
  1. Z. J. Ku
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  2. S. R. Jin
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  3. H. B. Zhou
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Correspondence to Z. J. Ku.

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Ku, Z.J., Jin, S.R. & Zhou, H.B. Synthesis and characterization of two charge-transfer salts based on Keggin-type polyoxometalates and morpholinebiguanide. Russ J Coord Chem 35, 195–199 (2009). https://doi.org/10.1134/S1070328409030063

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  • DOI: https://doi.org/10.1134/S1070328409030063

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