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Complexes of alkaline-earth metal β-diketonates with 15-crown-5: Synthesis, structures, and properties

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Abstract

The alkaline-earth metal complexes [M(Pta)2(15C5)] (M = Ca, Sr, and Ba; Pta is the 1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionate anion; 15C5 is 15-crown-5) were obtained from PtaH and 15C5 in toluene. The complexes were characterized by IR and 1H NMR spectra and TGA data. The structures of [Ca(Pta)2(15C5)] and [Ba(Pta)2(15C5)] were confirmed by X-ray diffraction analysis. The volatility and thermal stability decrease in the order [Ca(Pta)2(15C5)] > [Sr(Pta)2(15C5)] > [Ba(Pta)2(15C5)].

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Authors and Affiliations

  1. Institute of Organometallic Chemistry, Russian Academy of Sciences, ul. Tropinina 49, Nizhni Novgorod, 603600, Russia

    V. K. Khamylov, T. S. Pochekutova, B. I. Petrov, G. K. Fukin & S. P. Lukina

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  1. V. K. Khamylov
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  2. T. S. Pochekutova
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  3. B. I. Petrov
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  4. G. K. Fukin
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  5. S. P. Lukina
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Correspondence to V. K. Khamylov.

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Original Russian Text © V.K. Khamylov, T.S. Pochekutova, B.I. Petrov, G.K. Fukin, S.P. Lukina, 2008, published in Koordinatsionnaya Khimiya, 2008, Vol. 34, No. 12, pp. 896–903.

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Khamylov, V.K., Pochekutova, T.S., Petrov, B.I. et al. Complexes of alkaline-earth metal β-diketonates with 15-crown-5: Synthesis, structures, and properties. Russ J Coord Chem 34, 884–890 (2008). https://doi.org/10.1134/S1070328408120026

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  • DOI: https://doi.org/10.1134/S1070328408120026

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