Skip to main content
SpringerLink
Log in

35Cl NQR and pseudorotation in crystalline molecular complexes of antimony trichloride with aromatic hydrocarbons

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

The pseudorotation of chlorine atoms in molecular complexes of SbCl3 with benzene and its substituted derivatives was used as an example to consider the effect of the thermally activated intramolecular mobility on the quadrupole spin-lattice relaxation of moving nuclei. The data obtained by nuclear quadrupole resonance were analyzed using the model that implies the existence of a temperature dependence of the activation energy for pseudorotation. This model accounts for the great preexponential factors in the expression for the thermal activation component of the relaxation rate of chlorine nuclei found for some complexes and provides the way for rapid estimation of the pseudorotation activation energy in the characteristic temperature points using both relaxation and spectral NQR parameters.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Alexander, S. and Tzalmona, A. Phys. Rev. A: Gen. Phys., 1965, vol. 138, no 3, p. 845.

    CAS  Google Scholar 

  2. Ainbinder, N.E., Amirkhanov, B.F., Izmest’ev, I.V., et al., Fiz. Tverd. Tela, 1971, vol. 13, no. 2, p. 424.

    CAS  Google Scholar 

  3. Kyuntsel’, I.A. and Mokeeva, V.A., Vestn. Perm. Un-Ta, 2006, Physics, p. 54.

  4. Kyuntsel’, I.A., Vestn. Perm. Un-Ta, 2002, Physics, p. 39.

  5. Kyuntsel’, I.A., Koord. Khim., 2001, vol. 27, no. 12, p. 887 [Russ. J. Coord. Chem. (Engl. Transl.), vol. 27, no. 12, 835].

    Google Scholar 

  6. Kyuntsel’, I.A., Zh. Strukt. Khim., 2005, vol. 46, no. 5, p. 956.

    Google Scholar 

  7. Kyuntsel’, I.A., Mokeeva V.A., and Soifer G.B. J. Mol. Struct., 1995, vol, 345, p. 49.

    Article  Google Scholar 

  8. Berry, R.S., J. Chem. Phys., 1960, vol. 32, no. 3, p. 933.

    Article  CAS  Google Scholar 

  9. Gillespi, R.J., Molecular Geometry, New York: Wiley, 1972.

    Google Scholar 

  10. Yamada K., Okuda T., and Ichiba S., Bull. Chem. Soc. Jpn., 1987, vol 60, no. 12, p. 4197.

    Article  CAS  Google Scholar 

  11. Zolotarev, I.V., Osipenko, A.N., and Soifer, G.B., Vestn. Perm. Un-Ta, 2003, Physics, p. 47.

  12. Bayer, H., Z. Phys., 1951, vol. 130, no. 2, p. 227.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Perm State University, ul. Bukireva 15, Perm, 614600, Russia

    I. A. Kyuntsel’ & V. A. Mokeeva

Authors
  1. I. A. Kyuntsel’
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. A. Mokeeva
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I. A. Kyuntsel’.

Additional information

Original Russian Text © I.A. Kyuntsel, V.A. Mokeeva, 2008, published in Koordinatsionnaya Khimiya, 2008, Vol. 34, No. 1, pp. 17–21.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kyuntsel’, I.A., Mokeeva, V.A. 35Cl NQR and pseudorotation in crystalline molecular complexes of antimony trichloride with aromatic hydrocarbons. Russ J Coord Chem 34, 14–18 (2008). https://doi.org/10.1134/S107032840801003X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S107032840801003X

Keywords

Search

Navigation