Abstract
Two new soluble vic-dioxime ligands, 4-isopropylanilineglyoxime (L1H2) and 4-benzylpiperidineglyoxime (L2H2) were prepared by reacting 4-isopropylaniline and 4-benzylpiperidine with anti-chloroglyoxime. Ten metal complexes were obtanied by reacting both ligands with Cu(II),Ni(II),Co(II), Zn(II), and Cd(II) cations. The ligands and their metal complexes were elucidated by elemental analysis, IR, UV-vis, 1H NMR, and 13C NMR and also magnetic moments of the complexes were determined.
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Schrauzer, G.N. and Kohnle, J., Chem. Ber., 1964, vol. 97, p. 3056.
Schrauzer, G.N. and Windgassen, R. J., J. Am. Chem. Soc., 1967, vol. 89, p. 143.
Chakravorty, A., Coord. Chem. Rev., 1974, vol. 13, p. 1.
Kuse, S., Motomizu, S., and Toei, K., Anal. Chim. Acta, 1975, vol. 70, p. 65.
Gok, Y. and Kantekin, H., Acta Chem. Scand., 1997, vol. 51, p. 664.
Gok, Y., Yildiz, S., and Tufekci, M., J. Cooord. Chem., 1993, vol. 28, p. 237.
Gok, Y. and Bekaroglu, O., Synth. React.Inorg. Met.-Org. Chem., 1981, vol. 11, p. 621.
Karatas, I., and Ucan H.I., Synth. React. Inorg. Met.-Org. Chem., 1998, vol. 28, p. 383.
Leonard, J.P., Navotnik, D.P., and Neirinckx, R.D., J. Nucl. Med., 1986, vol. 27, p. 1819.
Dilworth, J.R. and Parrott, S. J., Chem. Soc. Rev., 1998, vol. 27, p. 43.
Blower, P. J., Transition Met. Chem., 1998, vol. 23, p. 109.
Houben, J. and Kaufmann, H., Ber. Dtsch. Chem. Ges., 1913, vol. 46, p. 2821.
Ponzio, G. and Baldrocco, F., Gazz. Chim. Ital., 1930, vol. 60, p. 415.
Ozcan, E. and Mirzaoglu, R., Synth. React. Inorg. Met.-Org. Chem., 1988, vol. 18, p. 559.
Irez, G. and Bekaroglu, O., Synth. React. Inorg. Met.-Org. Chem., 1983, vol. 13, p.781.
Gok, Y. and Kantekin, H., Polyhedron, 1997, vol. 16, p. 2413.
Tas, E., Cukurovali, A., and Kaya, M., J. Coord. Chem., 1998, vol. 44, p. 109.
Ucan, H.I. and Mirzaoglu, R., Synth. React. Inorg. Met.-Org. Chem., 1990, vol. 20, p. 437.
Pedersen, S.B. and Larsen, E., Acta Chem. Scand., 1973, vol. 27, p. 3291.
Kirschenbaum, L.J., Panda, R.K., Borish, E.T., and Montasti, E., Inorg. Chem., 1989, vol. 28, p. 3623.
Cukurovali, A. and Tas, E., Synth. React. Inorg. Met.-Org. Chem., 1998, vol. 28, p. 449.
Canpolat, E. and Kaya M., Polish J. Chem., 2003, vol. 77, p. 961.
Caton, J.E. and Banks, C.V., Inorg. Chem., 1967, vol. 6, p. 1670.
Gul, A. and Bekaroglu, O., Dalton Trans., vol. 25, p. 37.
Canpolat and M. Kaya, J. Cooord. Chem., 2005, vol. 58, p. 1217.
Canpolat, E., Kaya, M., and Bakirdere, E.G., Transition Met. Chem., 2005, vol. 30, p. 503.
Tahakkar, N.V. and Patil, R.M., Synth. React. Inorg. Met.-Org. Chem., 2000, vol. 30, p. 1159.
Ozcan, E., Karapinar, E., and Demirtas, B., Transition Met. Chem., 2002, vol. 27, p. 557.
Sacconi, L., Ciampolini, M., and Cavasino, F.R., J. Am. Chem. Soc., 1962, vol. 84, p. 3245.
Carlin, R.L., Transition Met. Chem., 1965, vol. 1, p. 25.
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Deveci, P., Özcan, E. & Taner, B. Synthesis and characterization of new (E,E)-dioximes and their divalent metal complexes. Russ J Coord Chem 33, 922–926 (2007). https://doi.org/10.1134/S1070328407120093
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DOI: https://doi.org/10.1134/S1070328407120093