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Photochemical reactions of cis-[(η4-NBD)M(CO)4] (NBD = norbornadiene; M = Cr, Mo) olefin complex with ligand, containing S and N donor atoms

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Abstract

New complexes cis-[M(CO)4-DABRd] (M = Cr(I), Mo(II) and fac-[M(CO)3-SAT] (M = Cr(III), Mo(IV)) have been synthesized by the photochemical reactions of cis-[(η4-NBD)M(CO)4] (NBD is norbornadiene; M=Cr, Mo) with 5-(4-dimethylaminobenzylidene) rhodanine (DABRd) and salicylidene-3-amino-1,2,4-triazole (SAT) ligands and characterized by elemental analysis, FT-IR and 1H NMR spectroscopy, and mass spectrometry. The spectroscopic studies show that the DABRd ligand acts as a bidentate ligand coordinating via both NH-(S)C=S sulfur donor atoms in I and II and SAT ligand behaves as a tridentate ligand coordinating via its all imine nitrogen-C=N-donor atoms in III and IV to the metal center.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science and Literature, Dokuz Eylul University, 35160, Izmir, Turkey

    E. Subasi & S. Karahan

  2. Department of Chemistry, Faculty of Engineering, Istanbul University, 34850, Istanbul, Turkey

    A. Ercag

Authors
  1. E. Subasi
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  2. S. Karahan
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  3. A. Ercag
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Correspondence to E. Subasi.

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The article was submitted by the authors in English.

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Subasi, E., Karahan, S. & Ercag, A. Photochemical reactions of cis-[(η4-NBD)M(CO)4] (NBD = norbornadiene; M = Cr, Mo) olefin complex with ligand, containing S and N donor atoms. Russ J Coord Chem 33, 886–890 (2007). https://doi.org/10.1134/S1070328407120032

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  • DOI: https://doi.org/10.1134/S1070328407120032

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