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Complexation of Eu(Fod)3 in the ground and excited electronic states with the enantiomers of camphor in benzene: Chemiluminescence, kinetic luminescence, and polarimetric investigations

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Abstract

Complexation between europium(III) 1,1,1,2,2,3,3-heptafluoro-7,7-dimethyloctane-4,6-dionate Eu(Fod)3 in the ground and excited electronic states and D-(D) and L-camphor (L) in benzene was studied. The stability constants and thermodynamic parameters of formation of the complexes [Eu(Fod)3(L)] and [Eu(Fod)3(D)] were determined by chemiluminescent and polarimetric methods for the ground state and by kinetic luminescence spectroscopy for the excited state. The photoexcitation of Eu(Fod)3 was found to enhance the stabilities of [Eu(Fod)3(L)] and [Eu(Fod)3(D)]. It was concluded that the photoexcitation of the f-f transitions in Eu(Fod)3 increases the contribution from the 4f orbital to coordination bonding.

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References

  1. Yatsimirskii, K.B., Kostromina, N.A., Sheka, Z.A., et al., Khimiya kompleksnykh soedinenii redkozemel’nykh elementov (Chemistry of Rare-Earth Complex Compounds), Kiev: Naukova Dumka, 1966.

    Google Scholar 

  2. Kazakov, V.P., Ostakhov, S.S., Voloshin, A.I., and Alyab’ev, A.S., Koord. Khim., 2001, vol. 27, no. 2, p. 151 [Russ. J. Coord. Chem. (Engl. Transl.), vol. 27, no. 2, p. 138].

    Google Scholar 

  3. Kazakov, V.P., Ostakhov, S.S., and Alyab’ev, A.S., Izv. Akad. Nauk, Ser. Khim., 2003, no. 7, p. 1445.

  4. Kazakov, V.P., Ostakhov, S.S., Rubtsova, O.V., and Alyab’ev, A.S., Khim. Fiz., 2002, vol. 21, no. 1, p. 67.

    CAS  Google Scholar 

  5. Kazakov, V.P., Ostakhov, S.S., Rubtsova, O.V., and Akhmadeeva, G.Kh., Koord. Khim., 2002, vol. 28, no. 2, p. 116 [Russ. J. Coord. Chem. (Engl. Transl.), vol. 27, no. 2, p. 109].

    Google Scholar 

  6. Kazakov, V.P., Ostakhov, S.S., Rubtsova, O.V., and Akhmadeeva, G.Kh., Khim. Vys. Energ., 2004, vol. 38, no. 1, p. 34.

    Google Scholar 

  7. Voloshin, A.I., Sharipov, G.L., Kazakov, V.P., and Tolstikov, G.A., Izv. Akad. Nauk, Ser. Khim., 1992, no. 5, p. 1056.

  8. Sharipov, G.L., Kazakov, V.P., and Tolstikov, G.A. Khimiya i khemilyuminestsentsiya 1,2-dioksetanov (Chemistry and Chemiluminescence of 1,2-Dioxetanes), Moscow: Nauka, 1990.

    Google Scholar 

  9. Ableeva, N.Sh., Voloshin, A.I., Vasil’eva, E.V., et al., Kinet. Katal., 1993, vol. 34, no. 5, p. 811.

    CAS  Google Scholar 

  10. Hajek, M., Horska, A., Trska, P., et. al., Collect. Czech. Chem. Commun., 1988, vol. 58, p. 97.

    Article  Google Scholar 

  11. Folkesson, B. and Larsson, R., Acta Chem. Scand., 1968, vol. 22, no. 6, p. 1953.

    Article  CAS  Google Scholar 

  12. Antikainen, P.J. and Tevanen, K., J. Inorg. Nucl. Chem., 1970, vol. 32, no. 6, p. 1915.

    Article  CAS  Google Scholar 

  13. Ermolaev, V.L., Sveshnikova, E.B., and Shakhvedov, T.A., Usp. Khim., 1976, vol. 45, no. 10, p. 1753.

    CAS  Google Scholar 

  14. Sveshnikova, E.B., Morina, V.F., and Ermolaev, V.L., Opt. Spektrosk., 1974, vol. 1974, no. 4, p. 725.

    Google Scholar 

  15. Marcantonatos, M.D., Deschaux, M., and Vuilleumier, J.J., Chem. Phys. Lett., 1981, vol. 82, no. 1, p. 36.

    Article  ADS  CAS  Google Scholar 

  16. Gruzdev, V.N., Zh. Neorg. Khim., 1977, vol. 22, no. 12. p. 3208.

    CAS  Google Scholar 

  17. Becker, P. and Bilal, B.A., J. Solution Chem., 1984, vol. 13, no. 7, p. 481.

    Article  CAS  Google Scholar 

  18. Ermolaev, V.L. and Sveshnikova, E.B., Usp. Khim., 1994, vol. 63, no. 11, p. 962.

    CAS  Google Scholar 

  19. Ostakhov, S.S., Kazakov, V.P., Afonichev, D.D., and Rykova, V.V., Radiokhimiya, 1995, vol. 37, no. 6, p. 503.

    CAS  Google Scholar 

  20. Kazakov, V.P., Ostakhov, S.S., and Rubtsova, O.V., Khim. Vys. Energ., 2001, vol. 35, no. 2, p. 138.

    Google Scholar 

  21. Kazakov, V.P., Ostakhov, S.S., Alyab’ev, A.S., and Farrakhova, G.G., Dokl. Akad. Nauk, 2004, vol. 398, no. 2, p. 207.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, Ufa, 450054, Bashkortostan, Russia

    A. S. Alyab’ev, S. S. Ostakhov, I. F. Kavsarova & V. P. Kazakov

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  1. A. S. Alyab’ev
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  2. S. S. Ostakhov
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  3. I. F. Kavsarova
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  4. V. P. Kazakov
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Original Russian Text © A.S. Alyab’ev, S.S. Ostakhov, I.F. Kavsarova, V.P. Kazakov, 2007, published in Koordinatsionnaya Khimiya, 2007, Vol. 33, No. 5, pp. 386–391.

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Alyab’ev, A.S., Ostakhov, S.S., Kavsarova, I.F. et al. Complexation of Eu(Fod)3 in the ground and excited electronic states with the enantiomers of camphor in benzene: Chemiluminescence, kinetic luminescence, and polarimetric investigations. Russ J Coord Chem 33, 377–382 (2007). https://doi.org/10.1134/S1070328407050120

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  • DOI: https://doi.org/10.1134/S1070328407050120

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