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Aggregates of complexes [Sc(H2O)4(NCS)2]+ and [Sc(H2O)2(NCS)4]− with 18-crown-6

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Abstract

The compounds [Sc(H2O)4(NCS)2][Sc(H2O)2(NCS)4] ·2(18C6) (I) and [Sc(H2O)4(NCS)2][Sc(H2O)2(NCS)4] · 3(18C6) · H2O (II) were synthesized and studied by X-ray diffraction analysis. It was found that the cations in the structures of compounds I and II form sandwiches [Sc(H2O)4(NCS)2] · 2(18C6). In the case of I, the sandwiches are united by the [Sc(H2O)2(NCS)4]− anions into chains, while in compound II, the sandwiches and infinite chains of [Sc(H2O)2(NCS)4] · 18C6 · H2O are bonded by van der Waals contacts only.

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References

  1. Petrosyants, S.P. and Ilyukhin, A.B., Koord. Khim., 2007, vol. 33, no. 3, p. 163.

    Google Scholar 

  2. Sheldrick, G.M., SHELXS-97. Program for the Solution of Crystal Structures, Göttingen (Germany), Univ. of Göttingen, 1997.

    Google Scholar 

  3. Sheldrick, G.M., SHELXL-97. Program for the Refinement of Crystal Structures, Göttingen (Germany), Univ. of Göttingen, 1997.

    Google Scholar 

  4. Petrosyants, S.P., Doctoral (Chem.) Dissertation, Moscow: Inst. of General and Inorg. Chem., 1992. 298 p.

    Google Scholar 

  5. Petrosyants, S.P. and Ilyukhin, A.B., Zh. Neorg. Khim., 2003, vol. 48, no. 9, p. 1463 [Russ. J. Inorg. Chem. (Engl. Transl.), vol. 48, no. 9, p. 1327].

    CAS  Google Scholar 

  6. Olszanski, D.J. and Melson, G.A., Inorg. Chim. Acta, 1978, vol. 26, no. 2, p. 263.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. B. Ilyukhin & S. P. Petrosyants

Authors
  1. A. B. Ilyukhin
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  2. S. P. Petrosyants
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Original Russian Text © A.B. Ilyukhin, S.P. Petrosyants, 2007, published in Koordinatsionnaya Khimiya, 2007, Vol. 33, No. 4, pp. 275–281.

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Ilyukhin, A.B., Petrosyants, S.P. Aggregates of complexes [Sc(H2O)4(NCS)2]+ and [Sc(H2O)2(NCS)4]− with 18-crown-6. Russ J Coord Chem 33, 265–271 (2007). https://doi.org/10.1134/S1070328407040057

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  • DOI: https://doi.org/10.1134/S1070328407040057

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