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Adducts of zinc and copper(II) dialkyldithiocarbamate complexes with dibutyl-and diisobutylamines: Synthesis, structures, EPR and solid-state natural abundance 13C and 15N CP/MAS NMR spectra

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Abstract

Crystalline adducts of zinc and copper(II) dithiocarbamate complexes with dibutyl-and diisobutylamines of the general formula [M(NHR′2)(S2CNR2)2] (M = Zn, 63Cu, and 65Cu; R = CH3 and C2H5; R2 = (CH2)4O; R′ = C4H9 and i-C4H9) were synthesized. Their structures and spectroscopic properties were studied by EPR and solid-state natural abundance 13C and 15N CP/MAS NMR spectroscopy. Experimental EPR data and computer-assisted modeling confirmed the individual character of copper(II) adducts. The geometries of the copper coordination polyhedra were found to be intermediate between a tetragonal pyramid and a trigonal bipyramid (TBP). The contributions from TBP to the geometries of the adducts obtained were calculated from the EPR data. According to the X-ray diffraction data, the adduct of zinc diethyldithiocarbamate with diisobutylamine exists in two isomeric forms. The 13C and 15N CP/MAS NMR signals were assigned to the atomic positions in two crystallographically independent conformer molecules.

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Authors and Affiliations

  1. Institute of Geology and Nature Management, Amur Scientific Center, Far East Division, Russian Academy of Sciences, Ryolochyi per. 1, Blagoveshchensk, Russia

    A. V. Ivanov, A. S. Zaeva & E. V. Novikova

  2. Blagoveshchensk State Pedagogical University, Blagoveshchensk, 675000, Russia

    A. S. Zaeva & E. V. Novikova

  3. Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia

    A. V. Gerasimenko

  4. Luléa University of Technology, S-971 87, Luléa, Sweden

    W. Forsling

Authors
  1. A. V. Ivanov
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  2. A. S. Zaeva
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  3. E. V. Novikova
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  4. A. V. Gerasimenko
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  5. W. Forsling
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Additional information

Original Russian Text © A.V. Ivanov, A.S. Zaeva, E.V. Novikova, A.V. Gerasimenko, W. Forsling, 2007, published in Koordinatsionnaya Khimiya, 2007, Vol. 33, No. 4, pp. 243–253.

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Ivanov, A.V., Zaeva, A.S., Novikova, E.V. et al. Adducts of zinc and copper(II) dialkyldithiocarbamate complexes with dibutyl-and diisobutylamines: Synthesis, structures, EPR and solid-state natural abundance 13C and 15N CP/MAS NMR spectra. Russ J Coord Chem 33, 233–243 (2007). https://doi.org/10.1134/S107032840704001X

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  • DOI: https://doi.org/10.1134/S107032840704001X

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