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Cluster compounds [Ca(DMF)6][Mo6Cl14] and [{Ca(OPPh3)4}{Mo6Cl14}]∞: Synthesis, crystal structure, and properties

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Abstract

The [Ca(DMF)6][Mo6Cl14] complex (I) was synthesized by reacting octahedral cluster Mo complex (H3O)2Mo6Cl14·6H2O with the Ca2+ cation in DMF. Analogous reaction carried out in the presence of triphenylphosphine oxide Ph3PO in acetonitrile resulted in [{Ca(OPPh3)4}{Mo6Cl14}] (II). According to X-ray diffraction data, complex I has ionic structure, while the structure of complex II consists of infinite linear chains of the cluster anionic complexes {Mo6Cl14}2− bonded to the cationic Ca complexes {Ca(OPPH3)4}2+. Both complexes exhibit intensive luminescence in red and near-IR regions of the spectrum.

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References

  1. Opalovskii, A.A., Tychinskaya, I.I., Kuznetsova, Z.M., and Samoilov, P.P., Galogenidy molibdena (Molybdenum Halides), Novosibirsk: Nauka, 1972, p. 98.

    Google Scholar 

  2. Preetz, W., Peters, G., and Bublitz, D., Chem. Rev., 1996, vol. 96, no. 3, p. 977.

    Article  CAS  Google Scholar 

  3. Prokopuk, N. and Shriver, D.F., Adv. Inorg. Chem., 1999, vol. 46, p. 1.

    Google Scholar 

  4. Gray, T.G., Coord. Chem. Rev., 2003, vol. 243, nos. 1–2, p. 213.

    Article  CAS  Google Scholar 

  5. Maverick, A.W. and Gray, H.B., J. Am. Chem. Soc., 1981, vol. 103, no. 5, p. 1298.

    Article  CAS  Google Scholar 

  6. Marverick, A.W. and Najdzionek, J.S., MacKenzie, D., et al., J. Am. Chem. Soc., 1983, vol. 105, no. 7, p. 1878.

    Article  Google Scholar 

  7. Zietlow, T.C., Hopkins, M.D., and Gray, H.B., J. Solid State Chem., 1985, vol. 57, p. 112.

    Article  CAS  Google Scholar 

  8. Chevrel, R., Sergent, M., and Prigent, J., J. Solid State Chem., 1971, vol. 3, no. 4, p. 515.

    Article  CAS  Google Scholar 

  9. Michel, J.B. and McCarley, R.E., Inorg. Chem., 1982, vol. 21, no. 5, p. 1864.

    Article  CAS  Google Scholar 

  10. Krebs, F.C., Laursen, B.W., Johannsen, I., et al., Acta Crystallogr., Sect. B: Struct. Sci., 1999, vol. 55, no. 3, p. 410.

    Article  Google Scholar 

  11. Potel, M., Perrin, C., Perrin, A., et al., Mater. Res. Bull., 1986, vol. 21, no. 10, p. 1239.

    Article  CAS  Google Scholar 

  12. Nikolaev, A.V., Opalovsky, A.A., and Fedorov, V.E., Thermal Analysis, New York: Academic, 1969, vol. 2, p. 793.

    Google Scholar 

  13. SADABS (Version 2002.2011). Bruker Advanced X-ray Solutions, Madison (WI, USA), 2004.

  14. Sheldrick, G.M., SHELXTL DOS/Windows/NT. Version 5.10, Bruker Analytical X-ray Instruments, Inc., Madison (WI, USA, 1997).

    Google Scholar 

  15. Jayaratne, K.C., Fitts, L.S., Hanusa, T.P., and Young Junior, V.G., Organometallics, 2001, vol. 20, p. 3638.

    Article  CAS  Google Scholar 

  16. Mironov, Y.V., Fedorov, V.E., Bang Hyun-Jin, and Kim Sung-Jin, Eur. J. Inorg. Chem., 2006, no. 3, p. 553.

  17. Leclaire, A. and Borel, M.M., Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem., 1977, vol. 33, no. 9, p. 2938.

    Article  Google Scholar 

  18. Wells, A.F., Structural Inorganic Chemistry, Oxford, 1984, vol. 2.

Download references

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    Zh. S. Kozhomuratova, Yu. V. Mironov, M. A. Shestopalov, Ya. M. Gaifulin, N. V. Kurat’eva, E. M. Uskov & V. E. Fedorov

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  1. Zh. S. Kozhomuratova
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  2. Yu. V. Mironov
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  3. M. A. Shestopalov
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  4. Ya. M. Gaifulin
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  5. N. V. Kurat’eva
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  6. E. M. Uskov
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  7. V. E. Fedorov
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Original Russian Text © Zh.S. Kozhomuratova, Yu.V. Mironov, M.A. Shestopalov, Ya.M. Gaifulin, N.V. Kurat’eva, E.M. Uskov, V.E. Fedorov, 2007, published in Koordinatsionnaya Khimiya, 2007, Vol. 33, No. 1, pp. 3–8.

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Kozhomuratova, Z.S., Mironov, Y.V., Shestopalov, M.A. et al. Cluster compounds [Ca(DMF)6][Mo6Cl14] and [{Ca(OPPh3)4}{Mo6Cl14}]∞: Synthesis, crystal structure, and properties. Russ J Coord Chem 33, 1–6 (2007). https://doi.org/10.1134/S1070328407010010

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  • DOI: https://doi.org/10.1134/S1070328407010010

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