Abstract
A series of novel binuclear Cu(II) complexes based on 2,6-diformyl-4-methylphenol and containing aminoguanidine and hydrazinobenzthio(oxo)zole as variable chelatophore fragments were synthesized. In these complexes, Cl−, Br−, NO −3 , and ClO −4 are both the inner-and outer-sphere ions. The magnetochemical properties of the title complexes were compared and the anion nature was shown to influence the structure of the complexes and the strength of antiferromagnetic interaction.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Brooker, S., Caygill, G.B., Davidson, T.S., et al., J. Chem. Soc., Dalton Trans., 2000, p. 3113.
Gradinaru, J., Formi, A., Simonov, Y., et al., Inorg. Chim. Acta, 2004, vol. 357, no. 9, p. 2728.
Sengottuvelan, N., Manonmani, J., and Kandaswamy, M., Polyhedron, 2002, vol. 21, nos. 27–28, p. 2767.
Xu, Z., Thompson, L.K., and Miller, D.O., Polyhedron, 2002, vol. 21, no. 17, p. 1715.
Kogan, V.A. and Lukov, V.V., Koord. Khim., 2004, vol. 30, no. 3, p. 219.
Paolucci, G., Vigato, P.A., Rosseto, G., and Casellato, U., Inorg. Chim. Acta, 1982, vol. 65, no. 1, p. 71.
Shetti Velas, N., Revankar Vidyanad, K., and Mahale Vinayak, B., Proc. Indian Acad. Sci. Chem. Sci., 1997, vol. 109, no. 1, p. 7.
Kalinnikov, V.T. and Rakitin, Yu.V., Vvedenie v magnetokhimiyu (Introduction to Magnetochemistry), Moscow: Nauka, 1990.
Shiping Yau, Peng Chehg, Daizheng Liao, et al., Synth. React. Inorg. Met.-Org. Chem., 1993, vol. 23, no. 3, p. 501.
Geary, W.J., Coord. Chem. Rev., 1971, vol. 7, no. 1, p. 81.
Antsyshkina, A.S., Porai-Koshits, M.A., Sadikov, G.G., et al., Zh. Neorg. Khim., 1994, vol. 39, no. 6, p. 905.
Levchenkov, S.I., Kogan, V.A., Lukov, V.V., et al., Zh. Neorg. Khim., 1993, vol. 38, no. 10, p. 1687.
Rakitin, Yu.V., Itogi nauki tekh., Ser. Stroenie molekul i khimicheskaya svyaz’, Moscow: VINITI, 1986, p. 95.
Lukov, V.V., Levchenkov, S.I., and Kogan, V.A., Koord. Khim., 1999, vol. 25, no. 1, p. 51.
Levchenkov, S.I., Lukov, V.V., Shcherbakov, I.N., and Kogan, V.A., Koord. Khim., 1999, vol. 25, no. 12, p. 915.
Levchenkov, S.I., Lukov, V.V., Shcherbakov, I.N., et al., Koord. Khim., 2001, vol. 27, no. 2, p. 148.
Kogan, V.A. and Lukov, V.V., Koord. Khim., 1998, vol. 24, no. 3, p. 189.
Author information
Authors and Affiliations
Additional information
Original Russian Text © O.V. Maevskii, Yu.P. Tupolova, V.A. Kogan, V.V. Lukov, L.D. Popov, 2006, published in Koordinatsionnaya Khimiya, 2006, Vol. 32, No. 9, pp. 704–707.
Rights and permissions
About this article
Cite this article
Maevskii, O.V., Tupolova, Y.P., Kogan, V.A. et al. The effect of substituents in ligands and of anionic composition on the exchange interaction in binuclear Cu(II) complexes based on 2,6-diformyl-4-methylphenol. Russ J Coord Chem 32, 676–679 (2006). https://doi.org/10.1134/S1070328406090090
Received:
Issue Date:
DOI: https://doi.org/10.1134/S1070328406090090