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Syntheses and structures of mononuclear eight-coordinate Na[ErIII(Cydta)(H2O2]·5H2O (Cydta = trans-1,2-cyclohexanediaminetetraacetic acid) and binuclear nine-coordinate Na2[SmIII(Cydta)][SmIII(Cydta)(H2O)3] · 11H2O

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Abstract

The title complexes, Na[ErIII(Cydta)(H2O)2] · 5H2O (I) and Na2[SmIII(Cydta)][SmIII(Cydta)(H2O)3] · 11H2O (II) (Cydta is trans-1,2-cyclohexanediaminetetraacetic acid), are prepared and characterized using IR, elemental analyses, and single-crystal X-ray diffraction techniques. Crystal I belongs to triclinic system (space group P1), which has a mononuclear eight-coordinate slightly distorted square antiprismatic conformation. The crystal data are as follows: a = 8.371(12) Å, b = 9.952(14) Å, c = 14.74(2) Å, α = 88.32(2)°, β = 76.30(2)°, γ = 87.87(2)°, V = 1192(3) Å3, Z = 1, ρ = 1.835 g/cm3, μ = 3.612 mm−1, F(000) = 658, R = 0.0194, and wR = 0.0520 for 4130 observed reflections with I≥2σ(I). Crystal II belongs to monoclinic system (space group P21/n), which has the binuclear nine-coordinate structure with tricapped trigonal prismatic conformation for Sm(1) and the pseudomonocapped square antiprismatic conformation for Sm(2). The crystal data are as follows: a = 12.283(6) Å, b = 15.626(7) Å, c = 25.875(12) Å, β = 97.962(7)°, V = 4919(4) Å3, Z = 4, ρ = 1.717 g/cm3, μ = 2.476 mm−1, F(000) = 2536, R = 0.0781, and wR = 0.1745 for 8554 observed reflections with I ≥ 2σ(I).

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Authors and Affiliations

  1. Department of Chemistry, Liaoning University, Shenyang, 110036, China

    J. Wang, X. Zh. Liu, Zh. H. Zhang, X. D. Zhang, G. R. Gao, Y. M. Kong & Y. Li

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  1. J. Wang
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  2. X. Zh. Liu
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  3. Zh. H. Zhang
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  4. X. D. Zhang
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Wang, J., Liu, X.Z., Zhang, Z.H. et al. Syntheses and structures of mononuclear eight-coordinate Na[ErIII(Cydta)(H2O2]·5H2O (Cydta = trans-1,2-cyclohexanediaminetetraacetic acid) and binuclear nine-coordinate Na2[SmIII(Cydta)][SmIII(Cydta)(H2O)3] · 11H2O. Russ J Coord Chem 32, 590–599 (2006). https://doi.org/10.1134/S1070328406080112

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  • DOI: https://doi.org/10.1134/S1070328406080112

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