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Triethylenetetramine(3-sulfinatopropanoato-O,S)cobalt(III) isomers: Synthesis and structure of α-cis-[Co(Trien)(O2CC2H4SO2)]ClO4 · 2H2O and β-cis-[Co(Trien)(O2CC2H4SO2)]ClO4

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Abstract

The α-cis-and β-cis-isomers of (triethylenetetramine)(3-sulfinatopropanoato-O,S)cobalt(III) cation were synthesized and crystal structures of their perchlorates were established. The 3-sulfinatopropanoate anion, which forms six-membered ring with the Co atom, is bonded to the latter through the S atom and the carboxyl O atom.

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Authors and Affiliations

  1. Institut für Anorganishe Chemie Universität Regensburg, Germany

    M. Zabel

  2. Institute of Molecular and Atomic Physics, National Academy of Sciences of Belarus, Minsk, Belarus

    V. I. Pavlovsky & A. L. Poznyak

Authors
  1. M. Zabel
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  2. V. I. Pavlovsky
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  3. A. L. Poznyak
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Original Russian Text © M. Zabel, V.I. Pavlovsky, A.I. Poznyak, 2006, published in Koordinatsionnaya Khimiya, 2006, Vol. 32, No. 8, pp. 592–596.

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Zabel, M., Pavlovsky, V.I. & Poznyak, A.L. Triethylenetetramine(3-sulfinatopropanoato-O,S)cobalt(III) isomers: Synthesis and structure of α-cis-[Co(Trien)(O2CC2H4SO2)]ClO4 · 2H2O and β-cis-[Co(Trien)(O2CC2H4SO2)]ClO4 . Russ J Coord Chem 32, 567–571 (2006). https://doi.org/10.1134/S1070328406080069

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  • DOI: https://doi.org/10.1134/S1070328406080069

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