Abstract
Crystals of phenylbismuth bis(chloroacetate) were synthesized by the reaction of triphenylbismuth with chloroacetic acid. Tridentate chelate-bridging chloroacetate ligands are bonded to neighboring molecules through the O atoms to form polymer chains. The Bi-O distances are equal to 2.36(1), 2.55(1), 2.78(1) and 2.30(1), 2.67(1), 2.85(2) Å. the length of the Bi-C bond is 2.26(2) Å.
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Original Russian Text © I.V. Egorova, V.V. Sharutin, T.K. Ivanenko, N.A. Nikolaeva, A.A. Molokov, 2006, published in Koordinatsionnaya Khimiya, 2006, Vol. 32, No. 5, pp 336–339.
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Egorova, I.V., Sharutin, V.V., Ivanenko, T.K. et al. Synthesis and structure of phenylbismuth bis(chloroacetate). Russ J Coord Chem 32, 321–324 (2006). https://doi.org/10.1134/S1070328406050022
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DOI: https://doi.org/10.1134/S1070328406050022