Abstract
Conditions for the formation of a CoL3 complex, where L is the deprotonated benzimidazole-2-(N,N-dimethyl)carbothioamide molecule, are studied. The structure of the complex is determined by X-ray diffraction analysis. Each ligand in crystal of the complex is bonded to the metal atom by the bidentate chelate mode at the vertices of a distorted octahedron. The S and N atoms in the octahedron are in the cis-position to each other. All bonds with the same multiplicity in the ligands and in the CoS3N3 octahedron have almost the same length.
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Original Russian Text © A.G. Panasyuk, Z. G. Aliev, A. N. Ranskii, 2006, published in Koordinatsionnaya Khimiya, 2006, Vol. 32, No. 4, pp. 278–281.
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Panasyuk, A.G., Aliev, Z.G. & Ranskii, A.N. Synthesis and crystal structure of tris[2-(N,N-dimethylthiocarbamoyl)benzimidazolato-1]cobalt(III). Russ J Coord Chem 32, 266–269 (2006). https://doi.org/10.1134/S1070328406040063
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DOI: https://doi.org/10.1134/S1070328406040063