Skip to main content
SpringerLink
Log in

Interpretation of the parameters of the EPR spectra of complexes containing ns 1 ions

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

The parameters of the EPR spectra of complexes containing paramagnetic ions with an unpaired ns electron (ns 1 ions) were interpreted. The effect of the ligand spin-orbital coupling on the parameter of the Zeeman splitting was discussed. The effect of spin polarization on the parameters of hyperfine and ligand hyperfine couplings was considered. The reasons for the anomalous behavior of the EPR parameters were noted. The character of the covalent bonding was analyzed from the EPR spectra. The anomalous behavior of the parameters of ligand hyperfine couplings in tetragonal complexes with ns 1 ions was discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Frey, W., Huss, R., Seidel, H., and Werkman, E., Phys. Status Solidi B, 1975, no. 68, p. 257.

  2. Krutikov, F.V., Silkin, N.I., and Stepanov, V.G., Fiz. Tverd. Tela, 1975, vol. 17, no. 11, p. 3363.

    CAS  Google Scholar 

  3. Krutikov, F.V., Silkin, N.I., and Stepanov, V.G., Fiz. Tverd. Tela, 1976, vol. 18, no. 10, p. 2958.

    CAS  Google Scholar 

  4. Krutikov, F.V., Silkin, N.I., and Stepanov, V.G., Paramagnitnyi rezonans (Paramagnetic Resonance), Kazan: Kazan Gos. Univ., 1978, nos. 10–11, p. 113.

    Google Scholar 

  5. Krutikov, F.V., Silkin, N.I., and Stepanov, V.G., Paramagnitnyi rezonans (Paramagnetic Resonance), Kazan: Kaazan Gos. Univ., 1978, no. 13, p. 79.

    Google Scholar 

  6. Mikheev, Yu.A. and Stepanov, V.G., Fiz. Tverd. Tela, 1985, vol. 27, no. 1, p. 253.

    CAS  Google Scholar 

  7. Mikheev, Yu.A. and Stepanov, V.G., Fiz. Tverd. Tela, 1985, vol. 27, no. 10, p. 3177.

    CAS  Google Scholar 

  8. Abragam, A. and Bleaney, B., Electron Paramagnetic Resonance of Transition Ions, Oxford: Clarendon, 1970, vol. 1.

    Google Scholar 

  9. Abragam, A. and Bleany, B., Electron Paramagnetic Resonance of Transition Ions, Oxford: Clarendon, 1970, vol. 2.

    Google Scholar 

  10. Hall, J.L. and Schumacher, R.T., Phys. Rev., 1962, vol. 127, no. 6, p. 1892.

    Article  CAS  Google Scholar 

  11. Krutikov, F.V., Cand. Sci. (Phys-Math.) Dissertation, Kazan: Kazan State Univ., 1979.

  12. Mikheev, Yu.A., Cand. Sci. (Phys-Math.) Dissertation, Kazan: Kazan State Univ., 1987.

  13. Eremin, M.V., Opt. Spektrosk., 1976, vol. 41, no. 2, p. 257.

    CAS  Google Scholar 

  14. Eremin, M.V. and Kornienko, A.A., Fiz. Tverd. Tela, 1977, vol. 19, no. 10, p. 3024.

    CAS  Google Scholar 

  15. Watanabe, H., Phys. Rev., 1966, vol. 149, no. 1, p. 402.

    Article  CAS  Google Scholar 

  16. Moreno, M., Phys. Status Solidi, A, 1979, no. 96, p. 647.

  17. Murav’ev, V.I. and Stepanov, V.G., Fiz. Tverd. Tela, 1987, vol. 25, no. 8, p. 2533.

    Google Scholar 

  18. Morton, J.R. and Preston, K.F., J. Magn. Res., 1978, no. 30, p. 577.

  19. Murav’ev, V.I. and Stepanov, V.G., Fiz. Tverd. Tela, 1983, vol. 25, no. 11, p. 3495.

    CAS  Google Scholar 

  20. Murav’ev, V.I., Fiz. Tverd. Tela, 1987, vol. 29, no. 2, p. 567.

    CAS  Google Scholar 

  21. Murav’ev, V.I., Fiz. Tverd. Tela, 2004, vol. 46, no. 5, p. 830.

    Google Scholar 

  22. Murav’ev, V.I., Koord. Khim., 1989, vol. 15, no. 10, p. 1314.

    CAS  Google Scholar 

  23. McGarvey, B.R., Transition Metal Chemistry, New York: Dekker, 1966, vol. 3, p. 89.

    Google Scholar 

  24. Wayckoff, R.W.G., The Structure of Crystals, New York: Academic, 1953, p. 211.

    Google Scholar 

  25. Misetich, A.A. and Watson, R.E., Phys. Rev., 1966, vol. 143, no. 2, p. 335.

    Article  CAS  Google Scholar 

  26. Murav’ev, V.I. and Yunusov, N.B., Phys. Status Solidi, B, 1977, no. 84, p. 791.

  27. Murav’ev, V.I., Ovchinnikov, I.V., and Yunusov, N.B., Koord. Khim., 1978, vol. 4, no. 6, p. 899.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Research and Production Enterprise “Izmeritel’”, Ulyanovsk, Russia

    V. I. Murav’ev

Authors
  1. V. I. Murav’ev
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © V.I. Murav’ev, 2006, published in Koordinatsionnaya Khimiya, 2006, Vol. 32, No. 3, pp. 223–229.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Murav’ev, V.I. Interpretation of the parameters of the EPR spectra of complexes containing ns 1 ions. Russ J Coord Chem 32, 214–220 (2006). https://doi.org/10.1134/S1070328406030080

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328406030080

Keywords

Search

Navigation