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Reactivity of Al(III) complexes with substituted phthalocyanines

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Abstract

The results of a study of reactivity of Al(III) complexes with acido ligands (Cl−, OH−) and substituted phthalocyanine, containing 4 and 8 substituents (Cl, Br, NO2 or COOH) in different positions of annelated benzene residues, are reviewed. Reactivity of coordinated phthalocyanines is studied by quantum-chemical and spectrophotometric methods for acid-base reactions and reactivity of coordination core is estimated by chemical kinetics methods using reactions of dissociation at the Al-N bonds. The Hammett-Taft correlation equations are derived for mono-and diprotonated tetrasubstituted phthalocyanines of Al(III) with positive ρ values of 10.2 and 59.8, respectively

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  1. Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    E. E. Suslova & T. N. Lomova

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  1. E. E. Suslova
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  2. T. N. Lomova
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Original Russian Text © E.E. Suslova, T.N. Lomova, 2006, published in Koordinatsionnaya Khimiya, 2006, Vol. 32, No. 3, pp. 163–173.

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Suslova, E.E., Lomova, T.N. Reactivity of Al(III) complexes with substituted phthalocyanines. Russ J Coord Chem 32, 155–165 (2006). https://doi.org/10.1134/S1070328406030018

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