Skip to main content
Log in

Prospects in application of thermal analysis for assessing the total water potential of soils

  • Soil Physics
  • Published:
Eurasian Soil Science Aims and scope Submit manuscript

Abstract

The theoretically derived dependence of the water vapor density (concentration) in the air on the absolute temperature permitted us to use the information obtained by thermogravimetric method for assessing the total potential of water remaining in colloids after drying at different temperatures. A close correlation and corresponding linear relationship fitting the fundamental physicochemical law by Landau–Derjaguin were observed between the logarithm modulus of the total potential of moisture left in soil colloids after drying at temperatures 27–70° and 70–200°C and their moisture. The total potential of water bound by hydrates and crystalline hydrates of substances in the soils varied in the range from–660 to–2394 J/g water, and that of water bound in soil clay minerals varied in the range from–714 to–2814 J/g water (which corresponds to the total soil water pressure of–7140 to–28140 atm.).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. S. P. Gabuda, Bound Water. Facts and Hypothesis (Nauka, Novosibirsk, 1982) [in Russian].

    Google Scholar 

  2. B. V. Deryagin and L. D. Landau, “Theory of stability of strongly charged sols and adhesion of strongly charged particles in electrolytic solutions,” Zh. Eksp. Teor. Fiz. 15 (11), 660–672 (1945).

    Google Scholar 

  3. V. I. Perel’man, A Concise Reference Book of a Chemist (Gos. Nauchno-Tekh. Khim. Liter., Moscow, 1954) [in Russian].

    Google Scholar 

  4. A. A. Rode, Fundamentals of Soil Moisture Theory (Gidrometeoizdat, Leningrad, 1965) [in Russian].

    Google Scholar 

  5. A. V. Smagin, A. S. Manucharov, N. B. Sadovnikova, G. V. Kharitonova, and I. A. Kostarev, “The effect of exchangeable cations on the thermodynamic state of water in clay minerals,” Eurasian Soil Sci. 37 (5), 473–478 (2004).

    Google Scholar 

  6. A. V. Smagin, “Theory and methods of evaluating the physical status of soils,” Eurasian Soil Sci. 36 (3), 301–312 (2003).

    Google Scholar 

  7. T. A. Sokolova, T. Ya. Dronova, and I. I. Tolpeshta, Clay Minerals in Soils (Grif i K, Tula, 2005) [in Russian].

    Google Scholar 

  8. I. I. Sudnitsyn, “Soil water content and water supply of plants in the southern Crimea,” Eurasian Soil Sci. 41 (1), 70–76 (2008).

    Article  Google Scholar 

  9. I. I. Sudnitsyn, “The role of exchangeable cations in the decrease of soil moisture energy (pressure) (dedicated to the 110th birthday of A. A. Rode),” Eurasian Soil Sci. 39 (5), 492–497 (2006).

    Article  Google Scholar 

  10. I. I. Sudnitsyn, Mobility of Soil Moisture and Water Consumption by Plants (Moscow State University, Moscow, 1979) [in Russian].

    Google Scholar 

  11. I. I. Sudnitsyn, A. V. Smagin, and A. P. Shvarov, “The theory of Maxwell–Boltzmann–Helmholtz–Gouy about the double electric layer in disperse systems and its application to soil science (on the 100th anniversary of the paper published by Gouy),” Eurasian Soil Sci. 45 (4), 452–457 (2012).

    Article  Google Scholar 

  12. W. W. Wendlandt, Thermal Methods of Analysis (Wiley, New York, 1964; Mir, Moscow, 1978).

    Google Scholar 

  13. Soil Mineralogy with Environmental Application, Ed. by J. B. Dixon and D. G. Schulze (Soil Science Society of America, Madison, WI, 2002).

  14. M. Gouy, “Sur la constitution de la charge electrique a la surface d’un electrolyte,” J. Phys. 4 (9), 457–468 (1910).

    Google Scholar 

  15. S. B. Hendricks, R. A. Nelson, and L. T. Alexander, “Hydration mechanism of the clay mineral montmorillonite saturated with various ions,” J. Am. Chem. Soc. 62, 1437–1464 (1940).

    Article  Google Scholar 

  16. M. Hoseh, “Heat of wetting of some soil colloids at different moisture content,” Soil Sci. 43, 257–276 (1937).

    Article  Google Scholar 

  17. K. Terzaghi and R. Peck, Soil Mechanics in Engineering Practice (Wiley, London, 1948).

    Google Scholar 

  18. Origin and Mineralogy of Clays, Ed. by B. Velde (Springer-Verlag, New York, 1995).

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to I. I. Sudnitsyn.

Additional information

Original Russian Text © I.I. Sudnitsyn, 2016, published in Pochvovedenie, 2016, No. 10, pp. 1186–1190.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sudnitsyn, I.I. Prospects in application of thermal analysis for assessing the total water potential of soils. Eurasian Soil Sc. 49, 1117–1121 (2016). https://doi.org/10.1134/S1064229316080135

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1064229316080135

Keywords

Navigation