Abstract
Mathematical tools that can be applied to analyze the dynamics of 14C and 12C isotopes in soil humus are discussed. A system of two differential equations is suggested to describe the dynamics of the 12C and the 14C/12C ratio (normalized to the NBS standard) with due account for the initial conditions and for the 14C dynamics in the atmosphere (in particular, the bomb effect). Possible analytical solutions to these equations and algorithms that can be used in the case when these solutions are absent are discussed. Routine problems of the assessment of the dates of soil burying and the coefficient of the humus mineralization on the basis of the experimentally determined 14C/12C ratios in the soil humus are considered with the use of published data. In particular, the specific features of the assessment of the parameters of these equations in the case of the insufficiency of the experimental data are analyzed.
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References
Kh. A. Arslanov, Radiocarbon: Geochemistry and Geochronology (Izd. Leningr. Gos. Univ., Leningrad, 1987) [in Russian].
B. Bolin, “How much CO2 will remain in the atmosphere?” in The Greenhouse Effect, Climatic Change, and Ecosystems Ed. by B. Bolin, B. R Döös, J. Jäger, and R. A. Warrick (Wiley, Chichester, 1986), pp. 93–155.
G. A. Wagner, Age Determination of Young Rocks and Artifacts (Elsevier, 1998).
Yu. K. Vasil’chuk and V. M. Kotlyakov, Fundamentals of Isotopic Geocryology and Glaciology (Izd. Mosk. Gos. Univ., Moscow, 2000) [in Russian].
F. S. Zavel’skii, “Radiocarbon Dating and Theoretical Models of Carbon Turnover in Soils,” Izv. Akad. Nauk SSSR, Ser. Geogr., No. 1, 27–34 (1975).
I. V. Ivanov, L. S. Pesochina, and V. M. Semenov, “Biological Mineralization of Organic Matter in the Modern Virgin and Plowed Chernozems, Buried Chernozems, and Fossil Chernozems,” Eur. Soil Sci. 42(10), 1109–1119 (2009).
I. V. Ivanov, O. S. Khokhlova, and O. A. Chichagova, “Natural Radiocarbon and Specific Features of Humus in the Modern and Buried Chernozems,” Izv. Ross. Akad. Nauk, Ser. Geogr., No. 6, 46–58 (2009).
I. V. Ivanov, O. S. Khokhlova, V. V. Galitskii, O. A. Chichagova, and E. P. Zazovskaya, “Radiocarbon Pollution and Self-Purification of Humus in Chernozems of the East-European Plain in 1900–2008,” Eur. Soil Sci. 45(8), 802–810 (2012).
W. F. Libby, “Radiocarbon Dating,” in Isotopes in Geology (Inostr. Lit., Moscow, 1954), pp. 318–439 [in Russian].
Spline Interpolation (Numerical Analysis Library, Research Computing Center, Lomonosov Moscow State Univ.) [http://www.srcc.msu.ru/num-anal/lib-na/cat/i/iis8r.htm].
A. E. Cherkinskii and V. A. Brovkin, “A Model of the Development of the Humus Profile in Modern Soil on the Basis of Radiocarbon Dates,” Dokl. Akad. Nauk SSSR 307(5), 1227–1231 (1989).
A. E. Cherkinskii and Y. M. Paul, “Application of Radiocarbon Method for Evaluating the Mineralization Rate and Humus-Acids Renewal Time in Krasnozem (Ustox Suborder),” Eur. Soil Sci. 27, 81–85 (1995).
O. A. Chichagova, Radiocarbon Dating of Soil Humus (Nauka, Moscow, 1985) [in Russian].
I. Levin, B. Kromer, H. Schoch-Fischer, M. Bruns, M. Münnich, D. Berdau, J. C. Vogel, and K. O. Münnich, “δ14CO2 Record from Vermont,” in Trends: A Compendium of Data on Global Change (CDIAC, Oak Ridge Natl. Lab., US Dept. of Energy, Oak Ridge, Tenn., USA, 1994) [http://cdiac.esd.ornl.gov/carbonisotopes.html].
R. Nydal and K. Lövseth, Carbon-14 Measurements in Atmospheric CO 2 from Northern and Southern Hemisphere Sites, 1962–1993, (CDIAC, Oak Ridge Natl. Lab., Oak Ridge, Tenn., USA, 1996) [http://cdiac.esd.ornl.gov/ftp/ndp057/ndp057.pdf].
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Original Russian Text © V.V. Galitskii, I.V. Ivanov, 2012, published in Pochvovedenie, 2012, No. 12, pp. 1278–1286.
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Galitskii, V.V., Ivanov, I.V. Mathematical description of the dynamics of 12C and 14C in the soil humus. Eurasian Soil Sc. 45, 1129–1137 (2012). https://doi.org/10.1134/S1064229312120046
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DOI: https://doi.org/10.1134/S1064229312120046