Abstract
A methodological approach for determining barium, lanthanum, and cerium contents with the use of an 241Am isotope source was suggested. The new method was applied for obtaining data on the geochemistry of Ba, La, and Ce in soils of humid landscapes. The high content of La and Ce was determined in cryozems of the Kolyma Lowland. In alluvial soils of Perm’, barium was identified in rhyzoconcretions in the form of barium sulfate of probably technogenic origin. In the gleyed agrozem on the Mulyanka River floodplain, the redistribution of barium in the soil profile and its concentration in iron nodules were detected. The contents of La and Ce in the fine earth of contaminated soils remained stable, and lanthanides were accumulated in concretions: the coefficient of La accumulation was 3.5 and that of Ce was 6.9. The mean accumulation coefficients of the elements in the studied soils were as follows: Ce (3.7) > Ba (3.0) > La (2.2).
Similar content being viewed by others
References
L. E. Berenshtein, N. S. Masolovich, V. G. Sochevanov, and G. V. Ostroumov, “Metrological Basis of Quality Control of Analytical Works,” in Methodological Basis of Studying the Chemical Composition of Rocks, Ores, and Minerals (Nedra, Moscow, 1979), pp. 23–118 [in Russian].
V. A. Bol’shakov, Reliability of Soil Analyses: Problems and Solutions (Pochv. Inst. im. V.V. Dokuchaeva, Moscow, 1992), 143 pp. [in Russian].
M. A. Bronnikova and V. O. Targul’yan, The Cutan Assemblage in Texture-Differentiated Soils (Akademkniga, Moscow, 2005), 197 pp. [in Russian].
Yu. N. Vodyanitskii, A. A. Vasil’ev, A. V. Kozheva, et al., “Influence of Iron-Containing Pigments on the Color of Soils on Alluvium of the Middle Kama Plain,” Pochvovedenie, No. 3, 318–330 (2007) [Eur. Soil Sci. 40 (3), 289–301 (2007)].
Yu. N. Vodyanitskii, N. S. Mergelov, and S. V. Goryachkin, “Diagnostics of Gleyzation upon a Low Content of Iron Oxides (Using the Example of Tundra Soils in the Kolyma Lowland),” Pochvovedenie, No. 3, 261–279 (2008) [Eur. Soil Sci. 41 (3), 231–248 (2008)].
N. Greenwood and A. Earnshaw, Chemistry of the Elements 2nd ed. (Elsevier, 1997), Translated under the title Khimiya Elementov (Binom, Moscow, 2008), Vol. 1, 607 pp. Vol. 2, 670 pp. [in Russian].
S. V. Gubin, Extended Abstract of Doctoral Dissertation in Biology (Moscow, 1999).
V. V. Dobrovol’skii, Basics of Biogenochemistry (Asademia, Moscow, 2003) [in Russian].
O. Z. Eremchenko and N. V. Moskvina, “The Properties of Soils and Technogenic Surface Formations in the Multistory Districts of Perm City,” Pochvovedenie, No. 7, 782–789 (2005) [Eur. Soil Sci. 38 (7) (2005)].
L. I. Inisheva and E. E. Ezupenok, “The Content of Chemical Elements in Oligotrophic Peats,” in Modern Problems of Soil Pollution, Materials of the II Intern. Conf. (Moscow, 2007), Vol. 2, pp. 63–67 [in Russian].
G. M. Kashulina, V. A. Chekushin, and I. V. Bogatyrev, “Physical degradation and Chemical Pollution of Soils in the Northwestern Europe,” in Modern Problems of Soil Pollution, Materials of the II Intern. Conf. (Moscow, 2007), Vol. 2, pp. 74–78 [in Russian].
Yu. Yu. Lur’e, Handbook on the Analytical Chemistry (Khimiya, Moscow, 1979), 480 pp. [in Russian].
A. V. Makedonov, Recent Concretions in Sediments and Soils (Nauka, Moscow, 1966), 283 pp. [in Russian].
L. V. Perelomov, “Interaction of Rare-Earth Elements with Biotic and Abiotic Soil Components,” Agrokhimiya, No. 11, 85–96 (2007).
A. I. Perel’man, Geochemistry of Landscape (Vyssh. Shkola, Moscow, 1975), 340 pp. [in Russian].
A. T. Savichev and S. E. Sorokin, “X-Ray Fluorescent Analysis of the Contents of Microelements and Heavy Metals in Soils,” Agrokhimiya, No. 12, 71–74 (2000).
A. T. Savichev and M. S. Fogel’son, “X-ray Fluorescent Analysis of Silicate Rocks on a Spectrometer,” Izv. Akad. Nauk SSSR, Ser. Geol., No. 8, 103–108 (1987).
Standard Samples of the Chemical Composition of Natural Mineral Substances. Methodological Guidelines, Compiled by N.S. Arnautov (Novosibirsk, 1987), 204 pp. [in Russian].
V. G. Khitrov, “The Results of Attestation of the System of Standards of the Chemical Composition of Magmatic Rocks,” Izv. Akad. Nauk SSSR, Ser. Geol., 37–52 (1984).
J. J. Braun, J. Viers, B. Dupre, et al., “Solid / Liquid REE Fractionation in the Lateritic System of Goyoum, East Cameroon: The Implication For the Present Dynamics of Soil Covers of the Humid Tropical Regions,” Geochim. Cosmochim. Acta 62, 273–299 (2005).
M. Land, B. Ohlander, J. Ingri, and J. Thunberg, “Solid Speciation and Fractionation of Rare Elements in a Spodosol Profile from Northern Sweden as Revealed by Sequential Extraction,” Chem. Geol. 160, 121–138 (1999).
L. Minarik, A. Zigova, J. Bendl, et al., “The Behavior of Rare Elements and Y during the Rock Weathering and Soil Formation in the Ricany Granite Massif, Central Bohemia,” Sci. Total Environ. 211, 101–111 (1998).
B. Ohlander, J. Ingri, M. Land, and H. Schonberg, “Change of Sm-Nd Isotope Composition during Weathering of Till,” Geochim. Cosmochim. Acta 64, 813–820 (2000).
M. I. Prudencio, M. A. S. Braga, and M. A. Gouveia, “REE Mobilization, Fractionation and Precipitation during Weathering of Basalts,” Chem. Geol. 107, 121–254 (1993).
A. E. Taunton, S. A. Welch, and J. F. Banfield, “Microbial Control on Phosphate and Lanthanide Distributions during Granite Weathering and Soil Formation,” Chem. Geol. 169, 371–382 (2000).
J. K. Tripathi and V. Rajamani, “Geochemistry and Origin of Ferruginous Nodules in Weathered Granodioritic Gneisses, Mysre Plateau, Southern India,” Geochim. Cosmochim. Acta 71, 1674–1688 (2007).
G. Tyler, “Vertical Distribution of Major, Minor and Rare Elements in Haplic Podzol,” Geoderma 119, 277–290 (2004).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Savichev, A.T., Vodyanitskii, Y.N. Determination of barium, lanthanum, and cerium contents in soils by the X-ray radiometric method. Eurasian Soil Sc. 42, 1461–1469 (2009). https://doi.org/10.1134/S1064229309130067
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1064229309130067