Abstract
The fractional composition of aluminum compounds was studied in soil solutions obtained using vacuum lysimeters from loamy podzolic soils on two-layered deposits. The concentration of aluminum was estimated in brooks and a river draining the area with a predominance of these soils. In soil solutions, the concentration of aluminum was experimentally determined in the following compounds: (1) organic and inorganic monomers, (2) stable complexes with HAs and FAs together with polymers, and (3) the most stable complexes with HAs and FAs together with fine-crystalline and colloidal compounds. The total Al concentration in soil solutions from forest litter was 0.111–0.175 mmol/l and decreased with depth to 0.05 mmol/l and lower in solutions from the IIBD horizons. More than 90% of the Al in the solutions was bound into complexes with organic ligands. Some amount of Al in solution could occur in aluminosilicate sols. The translocation of Al complexes from the litter through the AE horizon to the podzolic horizon was accompanied by an increase in the ratio between the Al concentration in fraction 2 and the C concentration in the solution. The concentrations of Altot in the surface waters varied in the range from 0.015 to 0.030 mmol/l. Most of the Al came to the surface waters from the litter and AE horizons and partially from the podzolic horizon due to the lateral runoff along the waterproof IIBD horizon. Approximate calculations showed that the recent annual removal of Al from the AE and E horizons with the lateral runoff was 7 to 560 mg (3–21 mmol) from 1 m2.
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References
M. M. Abramova, “Seasonal Variation in Some Chemical Properties of Forest Podzolic Soil,” in Proceedings of the Dokuchaev Soil Science Institute (Akad. Nauk SSSR, Moscow, 1947), Vol. 25, pp. 228–273 [in Russian].
I. I. Vasenev and V. O. Targulian, Windfall and Taiga Pedogenesis (Nauka, Moscow, 1995) [in Russian].
I. S. Vasil’ev, “Water Regime of Podzolic Soils,” in Proceedings of the Dokuchaev Soil Institute: Data on Studying the Water Regime of Soils (Akad. Nauk SSSR, Moscow, 1950), Vol. 32, pp. 74–296 [in Russian].
L. A. Vorob’eva, Chemical Analysis of Soils (Mosk. Gos. Univ., Moscow, 1998) [in Russian].
A. D. Voronin, Basic Physics of Soils (Mosk. Gos. Univ., Moscow, 1986) [in Russian].
Genesis and Ecology of Soils in the Central Forest State Nature Reserve (Nauka, Moscow, 1979) [in Russian].
L. O. Karpachevskii and M. N. Stroganova, “Soils of the Central Forest State Nature Biosphere Reserve and Their Ecological Assessment,” in Dynamics of Soil Structure and Recent Soil Processes (Moscow, 1987) [in Russian].
A. S. Kaurichev and E. M. Nozdrunova, “Migration and Composition of Water-Soluble Organic Matter in Soils of the Forest-Meadow Zone,” Izv. Timiryazevsk. S-Kh. Akad., Pochvoved. Agrokhim., No. 5, 91–106 (1962).
A. S. Kaurichev and E. M. Nozdrunova, “Formation Conditions and Migration Scopes of Organo-Mineral Compounds in Soils of the Taiga-Forest Zone,” Izv. Timiryazevsk. S-Kh. Akad., No. 3, 103–110 (1969).
I. S. Kaurichev, E. M. Nozdrunova, and R. P. Evseeva, “Water-Soluble Aluminum in Soils of the Taiga Zone,” Izv. Timiryazevsk. S-Kh. Akad., No. 6, 145–151 (1968).
I. S. Kaurichev, E. M. Nozdrunova, and R. P. Evseeva, “Contents and Forms of Water-Soluble Aluminum Compounds in Soil Solutions,” Pochvovedenie, No. 9, 68–79 (1969).
V. V. Ponomareva, Theory of Podzolization (Biochemical Aspects) (Akad. Nauk SSSR, Leningrad, 1964) [in Russian].
N. P. Remezov, L. N. Bykova, and K. M. Smirnova, “Biological Turnover of Nitrogen and Ash Elements in Forest Stands,” Tr. Inst. Lesa 24, 167–194 (1955).
A. A. Rode, “Possible Role of Plants in Podzolization,” in Soil Genesis and Recent Pedogenesis (Nauka, Moscow, 1984), pp. 36–56 [in Russian].
A. A. Rode, Podzol Formation (Akad. Nauk SSSR, Moscow, 1937) [in Russian].
A. A. Rode, “Podzolization and Evolution of Soils,” in Soil Genesis and Recent Pedogenesis (Nauka, Moscow, 1984), pp. 56–135 [in Russian].
A. A. Rode and I. M. Rashevskaya, “Comparative Genetic Analysis of Profiles of Podzolized Brown Forest Soil with Pseudogley and Forest Soddy-Strongly Podzolic Soil,” in Biogeochemical Processes in Podzolic Soils (Nauka, Leningrad, 1972) [in Russian].
L. E. Rodin and L. I. Bazilevich, Dynamics of Organic Matter and Biological Cycle in the Main Vegetation Types (Nauka, Moscow, 1965) [in Russian].
I. N. Skrynnikova, “Studying the Dynamics of the Chemical Composition of Soil and Ground Waters in the Podzolic Zone,” Tr. Pochv. Inst., Akad. Nauk SSSR 31, 167–213 (1950).
T. A. Sokolova, T. Ya. Dronova, I. I. Tolpeshta, and S. E. Ivanova, Interaction of Loamy Forest Soils with Model Acid Rains and the Acid-Base Buffering Properties of Podzolic Soils (Mosk. Gos. Univ., Moscow, 2001) [in Russian].
V. O. Targulian, T. A. Sokolova, A. G. Birina, et al., “Organization, Composition, and Genesis of Soddy-Pale-Podzolic Soils on Mantle Loams: An Analytical Study,” in Proceedings of the X International Congress of Soil Science, Moscow, Soviet Union, 1974 (Moscow, 1974) [in Russian].
I. I. Tolpeshta and T. A. Sokolova, “Aluminum Compounds in the Eluvial Horizon of Podzolic Soil and Dynamics of Their Acid Dissolution,” Pochvovedenie, No. 6, 676–684 (2004) [Eur. Soil Sci. 37 (6), 676–684 (2004)].
V. D. Tonkonogov, Texturally Differentiated Soils of the European Plain (Moscow, 1999) [in Russian].
S. Ya. Trofimov, N. Yu. Goncharuk, and E. I. Dorofeeva, “Hydrological Conditions and the Geochemical Migration of Substances in Soils on Different Relief Elements,” in Regulatory Role of Soil in the Functioning of Taiga Ecosystems (Nauka, Moscow, 2002), pp. 109–139 [in Russian].
J. M. Arocena and K. R. Glowa, “Mineral Weathering in Ectomycorrhizosphere of Subalpine Fir (Abies lasiocarpa (Hook.) Nutt.) as Revealed by Soil Solution Composition,” For. Ecol. Manage. 133, 61–70 (2000).
R. B. Barnes, “The Determination of Specific Forms of Aluminum in Natural Water,” Chem. Geol. 15, 177–191 (1975).
P. M. Bertsch and D. R. Parker, “Aqueous Polynuclear Aluminum Species,” in The Environmental Chemistry of Aluminum, 2nd ed., Ed. by G. Sposito (Lewis, Boca Raton, 1996), Ch. 4, pp. 117–168.
J. S. Bhatti, N. B. Comerford, and C. T. Johnston, “Influence of Soil Organic Matter Removal and pH on Oxalate Sorption onto a Spodic Horizon,” Soil Sci. Soc. Am. J. 62, 152–158 (1998).
P. R. Bloom and M. S. Erich, “The Quantitation of Aqueous Aluminum,” in The Environmental Chemistry of Aluminum, 2nd ed., Ed. by G. Sposito (Lewis, Boca Raton, 1996), Ch. 1, pp. 2–38.
C. T. Driscoll, “A Procedure for the Fractionation of Aqueous Aluminum in Dilute Acidic Waters,” Int. J. Environ. Anal. Chem. 16, 267–283 (1984).
C. T. Driscoll and K. M. Postek, “The Chemistry of Aluminum in Surface Waters,” in The Environmental Chemistry of Aluminum, 2nd ed., Ed. by G. Sposito (Lewis, Boca Raton, 1996), pp. 364–417.
V. C. Farmer and D. G. Lumsdon, “Interactions of Fulvic Acid with Aluminum and a Proto-Imogolite Sol: the Contribution of E-Horizon Eluates to Podzolization,” Eur. J. Soil Sci. 52, 177–188 (2001).
R. Giesler, H. Ilversniemi, L. Nyberg, et al., “Distribution and Mobilization of Al, Fe, and Si in Three Podzolic Soil Profiles in Relation to the Humus Layer,” Geoderma 94, 249–263 (2000).
S. C. Hodges, “Aluminum Speciation: a Comparison of Five Methods,” Soil Sci. Soc. Am. J. 51, 57–64 (1987).
B. R. James, C. J. Clark, and S. J. Riha, “An 8-Hydroxyquinoline Method for Labile and Total Aluminum in Soil Extracts,” Soil Sci. Soc. Am. J. 47, 893–897 (1983).
B. Jansen, K. G. J. Nierop, and J. M. Verstraten, “Influence of pH and Metal-Carbon Ratios on Soluble Organic Complexation of Fe(II), Fe(III), and Al(III) in Soil Solutions Determined by Diffusive Gradients in Thin Films,” Anal. Chim. Acta, No. 454, 259–270 (2002).
B. Jansen, K. G. J. Nierop, and J. M. Verstraten, “Mobility of Fe(II), Fe(III), and Al in Acidic Forest Soils Mediated by Dissolved Organic Matter: Influence of Solution pH and Metal-Carbon Ratios,” Geoderma 113, 323–340 (2003).
P. M. Jardine and L. W. Zelazny, “Surface Reactions of Aqueous Aluminum Species,” in The Environmental Chemistry of Aluminum, 2nd ed., Ed. by G. Sposito (Lewis, Boca Raton, 1996), pp. 221–270.
S. Lakshman, R. Mills, F. Fang, et al., “Use of Fluorescence Polarization to Probe the Structure and Aluminum Complexation of Three Molecular Fractions of a Soil Fulvic Acid,” Anal. Chim. Acta, No. 231, 113–119 (1996).
A. Lindroos, T. Brugger, J. Derome, and K. Derome, “The Weathering of Mineral Soil by Natural Soil Solutions,” Water Air Soil Pollut., No. 149, 269–279 (2003).
U. S. Lundstrom, N. Van Breemen, and D. Bain, “The Podzolization Process: A Review,” Geoderma 94, 91–107 (2000).
U. S. Lundstrom, N. Van Breemen, D. C. Bain, et al., “Advances in Understanding the Podzolization Process Resulting from a Multidisciplinary Study of Three Coniferous Forest Soils in the Nordic Countries,” Geoderma 94, 335–353 (2000).
H. M. May, P. A. Helmke, and M. L. Jackson, “Determination of Mononuclear Dissolved Aluminum in Near-Neutral Waters,” Chem. Geol. 24, 259–269 (1979).
J. Mulder, H.A. de Wit, H.W. J. Boonen, and L. R. Bakken, “Increased Levels of Aluminum in Forest Soils: Effects on the Stores of Soil Organic Carbon,” Water Air Soil Pollut. 130, 989–994 (2001).
M. Ochs, “Influence of Humified and Non-Humified Natural Organic Compounds on Mineral Dissolution,” Chem. Geol., No. 132, 119–124 (1996).
L. Ohman and S. Sjoberg, “Equilibrium and Structural Studies of Silicon(IV) and Aluminum(III) in Aqueous Solution: 8. A Potentiometric Study of Aluminum(III) Salicylates and Aluminum(III) Hydroxo Salicylates in 0.6 M NaCl,” Acta Chem. Scand. 37, 875–880 (1983).
E. Paterson, B. A. Goodman, and V. C. Farmer, “The Chemistry of Aluminum, Iron, and Manganese Oxides in Acid Soils,” in Soil Acidity, Ed. by B. Uhlrich and M. E. Sumner (Springer, Berlin, 1991), pp. 97–124.
G. Riise, P. Van Hees, U. Lundstrom, and L. T. Strand, “Mobility of Different Size Fractions of Organic Carbon, Al, Fe, Mn, and Si in Podzols,” Geoderma 94, 237–247 (2000).
F. Satoh, T. Sakuma, and H. Okajima, “A Toposequence of Fine-Textured Soils in the Hilly Area of the Northernmost of Hokkaido: IV. Hydrolytic Reaction of Aluminum in the Presence of Oxalic or Citric Acid Ligands,” Soil Sci. Plant Nutr. 36(3), 355–361 (1990).
S. H. Sutheimer and S. E. Cabaniss, “Aluminum Binding to Humic Substances Determined by High Performance Cation Exchange Chromatography,” Geochim. Cosmochim. Acta 61(1), 1–9 (1997).
N. Van Breemen, U. S. Lundstrom, and A. G. Jongmans, “Do Plants Drive Podzolization Via Rock-Eating Mycorrhizal Fungi?,” Geoderma 94, 163–171 (2000).
P. A. W. Van Hees, U. S. Lundstrom, and R. Giesler, “Low Molecular Weight Organic Acids and Their Al Complexes in Soil Solution — Composition, Distribution, and Seasonal Variation in Three Podzolized Soils,” Geoderma 94, 173–200 (2000).
G. F. Vance, F. J. Stevenson, and F. J. Sikora, “Environmental Chemistry of Aluminum-Organic Complexes,” in The Environmental Chemistry of Aluminum, 2nd ed., Ed. by G. Sposito (Lewis, Boca Raton, 1996), pp. 169–220.
Z. Xiaoping, L. Pawlowski, M. Kotowski, and A. Siek, “Mechanisms of Aluminum Mobilization in Soils,” J. Ecol. Chem. 3(3), 169–194 (1994).
H. Zhang and P. R. Bloom, “Dissolution Kinetics of Hornblende in Organic Acid Solutions,” Soil Sci. Soc. Am. J. 63, 815–822 (1999).
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Original Russian Text © I.I. Tolpeshta, T.A. Sokolova, 2009, published in Pochvovedenie, 2009, No. 1, pp. 29–41.
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Tolpeshta, I.I., Sokolova, T.A. Aluminum compounds in soil solutions and their migration in podzolic soils on two-layered deposits. Eurasian Soil Sc. 42, 24–35 (2009). https://doi.org/10.1134/S1064229309010049
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DOI: https://doi.org/10.1134/S1064229309010049