Abstract
A combined approach for fractioning metal compounds in soils on the basis of sequential and parallel extractions is proposed. This approach has been used to assess the group composition of Zn, Cu, and Pb compounds in an ordinary chernozem and its changes upon the soil contamination with metals. The contents of firmly and loosely bound metal compounds that are presumably fixed by the particular soil components (organic substances, carbonates, and silicate and nonsilicate minerals) have been determined.
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References
E. V. Arinushkina, Textbook on the Chemical Analysis of Soils (Mosk. Gos. Univ., Moscow, 1961) [in Russian].
Yu. N. Vodyanitskii, Manganese Oxides in Soils (Moscow, 2005) [in Russian].
Yu. N. Vodyanitskii, Study of Heavy Metals in Soils (Moscow, 2005) [in Russian].
K. K. Gedroits, Selected Works, Vol. 2: Chemical Analysis of Soils (Moscow, 1955) [in Russian].
K. E. Ginzburg and L. S. Lebedeva, “Procedure for Determining Mineral Phosphates in Soils,” Agrokhimiya, No. 1, 125–131 (1971).
V. S. Gorbatov, “Stability and Transformation of Heavy Metal (Zn, Pb, Cd) Oxides in Soils,” Pochvovedenie, No. 1, 35–42 (1988).
O. N. Gordeeva and G. A. Belogolova, “Methodology of Studying the Forms of Heavy Metals in Soils of the Southern Baikal Region and Northeastern China,” in Proceedings of the II International Scientific Conference “Current Problems of Soil Contamination,” Moscow, Russia, 2007 (Mosk. Gos. Univ., Moscow, 2007), Vol. 2, pp. 191–194 [in Russian].
V. A. Zhideeva, I. I. Vasenev, and A. P. Shcherbakov, “Fractionation of Pb, Cd, Ni, and Zn Compounds in Meadow-Chernozemic Soils Polluted by Emissions of the Accumulator Plant,” Pochvovedenie, No. 6, 725–733 (2002) [Eur. Soil Sci. 35 (60), 643–650 (2002)].
S. V. Zonn, Iron in Soils (Nauka, Moscow, 1982) [in Russian].
S. V. Zonn and A. P. Travleev, Aluminum, Its Role in Pedogenesis, and Effect on Plants (Dnepropetrovsk, 1992) [in Russian].
N. G. Zyrin, A. I. Obukhov, and G. V. Motuzova, “Trace Elements in Soils and Methods of Their Study,” in Proceedings of the X International Congress of Soil Science, Moscow, Soviet Union, 1974 (Moscow, 1974), Vol. 2, pp. 48–49 [in Russian].
L. O. Karpachevskii, V. F. Babanin, T. S. Gendler, et al., “Diagnostics of Iron Minerals Using Mossbauer Spectroscopy,” Pochvovedenie, No. 10, 110–120 (1972).
D. V. Ladonin and O. V. Plyaskina, “Fractional Composition of Copper, Zinc, and Lead Compounds in Some Soils under Polyelement Contamination,” Vestn. Mosk. Univ., Ser. 17: Pochvoved., No. 1, 9–16 (2003).
V. G. Mineev, A. A. Alekseev, and T. A. Trishina, “Zinc in the Environment,” Agrokhimiya, No. 3, 94–104 (1984).
T. M. Minkina, D. L. Pinskii, A. P. Samokhin, and A. A. Statovoi, “Adsorption of Copper, Zinc, and Lead by Ordinary Chernozem under Mono-and Polyelement Contamination,” Agrokhimiya, No. 8, 58–64 (2005).
G. V. Motuzova, R. S. Aptikaev, and E. A. Karpova, “Fractionation of Soil Arsenic Compounds,” Pochvovedenie, No. 4, 432–442 (2006) [Eur. Soil Sci. 39 (4), 387–396 (2006)].
G. V. Motuzova and A. K. Degtyareva, “Effect of 0.1 N H2SO4, Tamm, and Mehra-Jackson Solutions on Iron Compounds in Soddy-Alluvial Soil,” Vestn. Mosk. Univ., Ser. 17: Pochvoved., No. 1, 36–48 (1991).
V. V. Okorkov and M. A. Mazirov, “Some Physicochemical Aspects of Remediation of Soils Contaminated with Heavy Metals,” in Proceedings of the 1st International Geoecological Conference “Geoecological Problems of Environmental Contamination with Heavy Metals,” Tula, 2003 (Tula, 2003), pp. 529–533.
T. V. Pampura, D. L. Pinskii, V. G. Ostroumov, et al., “Experimental Study of the Buffer Capacity of Chernozem Contaminated with Copper and Zinc,” Pochvovedenie, No. 2, 104–110 (1993).
L. V. Perelomov and D. L. Pinskii, “Mn, Pb, and Zn Compounds in Gray Forest Soils of the Central Russian Upland,” Pochvovedenie, No. 6, 682–691 (2003) [Eur. Soil Sci. 36 (6), 610–618 (2003)].
A. V. Peterburskii, Laboratory Manual on Agronomical Chemistry (Kolos, Moscow, 1968) [in Russian].
D. L. Pinskii, Extended Abstract of Doctoral Dissertation in Biology (Moscow, 1992).
A. A. Ponizovskii and E. V. Mironenko, “Mechanisms of Lead(II) Sorption in Soils,” Pochvovedenie, No. 4, 418–429 (2001) [Eur. Soil Sci. 34 (4), 371–381 (2001)].
V. V. Ponomareva and T. A. Plotnikova, “Procedure and Some Results of Fractionation of Chernozem Humus,” Pochvovedenie, No. 11, 31–37 (1968).
Laboratory Manual on Agrochemistry, Ed. by V. G. Mineev (Mosk. Gos. Univ., Moscow, 1989) [in Russian].
A. P. Samokhin, Extended Abstract of Candidate’s Dissertation in Biology (Rostov-on-Don, 2003).
G. A. Solov’ev, “Use of Complex Extracts for Determining Available Trace Elements in Soils,” in Monitoring of the Background Contamination of Natural Environments (Gidrometeoizdat, Leningrad, 1989), No. 56, pp. 216–227 [in Russian].
I. V. Tyurin, Soil Organic Matter and Its Role in Pedogenesis and Fertility: Theory of Soil Humus (Moscow, 1937) [in Russian].
F. V. Chirikov, Agricultural Chemistry of Potassium and Phosphorus (Moscow, 1956) [in Russian].
A. Andersson, “The Distribution of Heavy Metals in Soils and Soil Material as Influenced by Ionic Radius,” Swed. J. Agric. Res., No. 7, 141–147 (1977).
G. Brummer, K. G. Tiller, U. Herms, and P. Clayton, “Adsorption-Desorption and/or Precipitation-Dissolution Processes of Zinc in Soils,” Geoderma 31(4), 337–354 (1983).
A. S. Knox, J. Seaman, D. C. Adriano, and G. Pierzynski, “Chemophytostabilization of Metals in Contaminated Soils,” in Bioremediation of Contaminated Soils, Ed. by D. L. Wise et al. (Dekker, New York, 2000), pp. 811–836.
J. Santillan-Medrano and J. J. Jurinak, “The Chemistry of Lead and Cadmium in Soil Solid Phase Formation,” Soil Sci. Soc. Am. Proc. 39(5), 851–856 (1975).
P. Schachschabel, “Die Bestimmung des Manganversorgunggrades der Boden,” in Rapp. 6th International Congress of Soil Scientists, Paris, France, 1956 (Paris, 1956), p. 302.
L. M. Shuman, “Zinc, Manganese, and Copper in Soil Fractions,” Soil Sci. 127, 10–17 (1979).
A. Tessier, P. G. C. Campbell, and M. Bisson, “Sequential Extraction Procedure for the Speciation of Particulate Trace Metals,” Anal. Chem., No. 51, 844–851 (1979).
C. Whalley and A. Grant, “Assessment of the Phase Selectivity of the European Community Bureau of Reference (BCR) Sequential Extraction Procedure for Metals in Sediment,” Anal. Chem. Acta 61, 2211–2221 (1994).
S. A. Wilde and G. K. Voigt, Analysis of Soils and Plants for Foresters and Horticulturists (Edwards, Michigan, 1955).
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Original Russian Text © T.M. Minkina, G.V. Motuzova, O.G. Nazarenko, V.S. Kryshchenko, S.S. Mandzhieva, 2008, published in Pochvovedenie, 2008, No. 11, pp. 1324–1333.
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Minkina, T.M., Motuzova, G.V., Nazarenko, O.G. et al. Combined approach for fractioning metal compounds in soils. Eurasian Soil Sc. 41, 1171–1179 (2008). https://doi.org/10.1134/S1064229308110057
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DOI: https://doi.org/10.1134/S1064229308110057
Keywords
- Heavy Metal
- EURASIAN Soil Science
- Residual Fraction
- Metal Compound
- Soil Component