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Composition and Electronic and Atomic Structure of Palladium Nanoparticles at Different Metal Concentrations in a Polyethylene Matrix

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Abstract

The composition and the electronic and atomic structure of palladium nanoparticles stabilized in high-pressure polyethylene (with 10 and 20 wt % palladium) have been studied using transmission electron microscopy, X-ray diffraction, and X-ray absorption spectroscopy. It has been found that these nanoparticles have metallic (Pd) and oxide (Pd2O3) components, and their mean size and coordination numbers in the Pd sphere decrease from 7 to 6 nm and from 7 to 5.7, respectively, together with the metal concentration.

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Funding

This study was conducted as part of project no. 3.6105.2017/8.9 (base part of a state order for scientific research).

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Authors and Affiliations

  1. Research Institute of Physics, Southern Federal University, 344090, Rostov-on-Don, Russia

    S. S. Podsukhina, A. V. Kozinkin & V. G. Vlasenko

  2. Kurnakov Intitute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    G. Yu. Yurkov

  3. Bauman Moscow State Technical University, 105005, Moscow, Russia

    O. V. Popkov

Authors
  1. S. S. Podsukhina
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  2. A. V. Kozinkin
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  3. V. G. Vlasenko
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  4. G. Yu. Yurkov
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  5. O. V. Popkov
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Corresponding author

Correspondence to S. S. Podsukhina.

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The authors declare that they have no conflict of interest.

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Translated by D. Safin

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Podsukhina, S.S., Kozinkin, A.V., Vlasenko, V.G. et al. Composition and Electronic and Atomic Structure of Palladium Nanoparticles at Different Metal Concentrations in a Polyethylene Matrix. Tech. Phys. Lett. 46, 323–326 (2020). https://doi.org/10.1134/S1063785020040124

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  • DOI: https://doi.org/10.1134/S1063785020040124

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