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Morphology Control and Optical Properties of CdSe Nanorods by Surface Ligands

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Abstract

In this paper, CdSe nanorods were prepared via solvothermal synthesis, the effect of surface ligands on the morphology of nanorods was investigated under the premise by tuning the percentage of surface ligands in the precursors. Experimental results show that the absorption and emission spectrum of CdSe nanorod with different aspect ratio varying from 4:1 to 2:1 have a red-shift, and the aspect ratio gradually decreases as the percentage of tetradecylphosphoric acid (TDPA) in the precursor increases. In addition, the CdSe optical stability improves as the percentage of TDPA increases. It is also shown that the crystal surface, which is not covered by TDPA, has an increased surface energy, which results in rapid growth of the crystal face and the formation of a rod-like structure. As a result, the effects of anisotropic absorption and emission, along the long axis properties can find many applications in the fields of optics, optical materials.

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Funding

This work is supported by the “111” Project of China (D17017), the National Natural Science Foundation of China (21703017, 11604024), the Advance Recearch Project of Weapon and Equipment (6140414020102), the Developing Project of Science and Technology of Jilin Province (20180519017JH, 20190701029GH, 20190201181JC), and the Project of Education Department of Jilin Province (JJKH20181101KJ and JJKH20181106KJ). Science Foundation for Young Scientists of Changchun University of science and technology (XQNJJ-2016-14).

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Authors and Affiliations

  1. International Joint Research Center for Nanophotonics and Biophotonics, Nanophotonics and Biophotonics Key Laboratory of Jilin Province, School of Science, Changchun University of Science and Technology, 130022, Changchun, China

    Zhiyuan Lin, Jinhua Li, Ke Feng, Yue Wang & Xueying Chu

  2. CAS Key Laboratory of Bio-medical Diagnostics, Suzhou Institute of Biomedical Engineering and Technology, Chinese Academy of Sciences, 215163, Suzhou, Jiangsu province, China

    Siyi Hu

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  1. Zhiyuan Lin
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  2. Jinhua Li
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Correspondence to Jinhua Li.

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Lin, Z., Li, J., Feng, K. et al. Morphology Control and Optical Properties of CdSe Nanorods by Surface Ligands. Tech. Phys. Lett. 45, 814–819 (2019). https://doi.org/10.1134/S1063785019080273

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  • DOI: https://doi.org/10.1134/S1063785019080273

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