Abstract
A relationship describing the probability of electron excitation in a solid crystal by the energy of a chemical reaction on its surface has been found. It is established that the probability of electron excitation in this reaction exponentially increases with decreasing energy of electron transition in the solid. A method of nonadiabatic chemoelectron energy conversion in heterostructures for hydrogen power engineering based on Schottky diodes is proposed and the efficiency of this method is calculated.
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References
B. Gergen, H. Nienhaus, W. Weinberg, and E. McFarland, Science 294, 2521 (2001).
E. Hasselbrink, Surf. Sci. 603, 1564 (2009).
A. Hervier, J. R. Renzas, J. Y. Park, and G. Somorjai, Nano Lett. 9, 3930 (2009).
V. V. Styrov and Yu. I. Tyurin, Nonequilibrium Chemoeffects on Solid Surfaces (Energoatomizdat, Moscow, 2003) [in Russian].
A. N. Georgobiani and M. K. Sheinkman, Physics of A2 B 6 Compounds (Nauka, Moscow, 1986) [in Russian].
V. P. Grankin, Tech. Phys. Lett. 20 (7), 574 (1994).
V. P. Grankin and V. Yu. Shalamov, J. Appl. Spectrosc. 66 (6), 940 (1999).
V. P. Grankin, S. A. Voloshchuk, and D. V. Grankin, Poverkhnost: Rentgen. Sinkhrotron. Neitron. Issled., No. 6, 92 (2010).
V. V. Styrov and S. V. Simchenko, JETP Lett. 96 (5), 313 (2012).
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Original Russian Text © V.P. Grankin, D.V. Grankin, 2015, published in Pis’ma v Zhurnal Tekhnicheskoi Fiziki, 2015, Vol. 41, No. 24, pp. 29–36.
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Grankin, V.P., Grankin, D.V. Nonadiabatic chemoelectron energy conversion in heterostructures for hydrogen power engineering. Tech. Phys. Lett. 41, 1173–1176 (2015). https://doi.org/10.1134/S1063785015120214
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DOI: https://doi.org/10.1134/S1063785015120214