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Synthesis of zinc sulfide nanoparticles during zinc oxidization by H2S and H2S/H2O supercritical fluids

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Abstract

Formation of zinc sulfide nanoparticles was detected during interaction of bulk samples with hydrogen sulfide at supercritical parameters. Synthesis proceeds with liberation of H2 by the reaction nZn + nH2S = (ZnS) n + nH2. It has been found by the X-ray diffraction method, scanning electron microscopy, and mass spectrometry that the addition of water stimulates coupled reactions of nanoparticle synthesis nZn + nH2O = (ZnO) n + nH2 and (ZnO) n + nH2S = (ZnS) n + nH2O and brings about an increase in the synthesis rate and morphological changes of (ZnS) n nanoparticles.

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Authors and Affiliations

  1. Kutateladze Institute of Thermophysics, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    A. A. Vostrikov, O. N. Fedyaeva, M. Ya. Sokol & A. V. Shatrova

Authors
  1. A. A. Vostrikov
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  2. O. N. Fedyaeva
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  3. M. Ya. Sokol
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  4. A. V. Shatrova
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Correspondence to A. A. Vostrikov.

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Original Russian Text © A.A. Vostrikov, O.N. Fedyaeva, M.Ya. Sokol, A.V. Shatrova, 2014, published in Pis’ma v Zhurnal Tekhnicheskoi Fiziki, 2014, Vol. 40, No. 23, pp. 41–48.

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Vostrikov, A.A., Fedyaeva, O.N., Sokol, M.Y. et al. Synthesis of zinc sulfide nanoparticles during zinc oxidization by H2S and H2S/H2O supercritical fluids. Tech. Phys. Lett. 40, 1057–1060 (2014). https://doi.org/10.1134/S1063785014120141

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  • DOI: https://doi.org/10.1134/S1063785014120141

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