Skip to main content
Log in

Ionization of the glycerin molecule by the electron impact

  • Published:
Technical Physics Letters Aims and scope Submit manuscript

Abstract

The paper describes experimental method for and presents the results of studying positive ion yields produced due to direct and dissociative electron-impact ionization of the glycerin molecule. The mass spectra of the glycerin molecule are studied in the range of mass numbers of 10–95 amu at different temperatures. The energy dependences of the ionization efficiency cross sections of the glycerin molecule ions produced by a monoenergetic electron beam are analyzed; using these dependences, the appearance energies of fragment ions are determined. The dynamics of fragment ion formation is investigated in the temperature range of 300–340 K.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A. N. Zavilopulo, M. I. Mykyta, and O. B. Shpenik, Tech. Phys. 57(7), 923 (2012).

    Article  Google Scholar 

  2. E. E. Kontros, I. V. Chernyshova, and O. B. Shpenik, Opt. Spectrosc. 101, 537 (2006).

    Article  ADS  Google Scholar 

  3. A. T. Lebedev, The Mass Spectroscopy in the Organic Chemistry (BINOM, Moscow, 2003) [in Russian].

    Google Scholar 

  4. A. N. Zavilopulo, O. B. Shpenik, and L. G. Romanova, Publ. Astron. Obs., No. 84, 69 (2008).

    Google Scholar 

  5. V. V. Afrosimov, A. A. Basalaev, E. A. Berezovskaya, M. N. Panov, O. V. Smirnov, and A. V. Tulub, Tech. Phys. 51, 1553 (2006).

    Article  Google Scholar 

  6. F. P. Lossing, R. H. Emmel, B. G. Giessner, et al., J. Chem. Phys. 54(12), 5431 (1971).

    Article  ADS  Google Scholar 

  7. T. Fiegele, G. Hanel, I. Torres, M. Lezius, and T. D. Mark, J. Phys. 33, 4263 (2000).

    ADS  Google Scholar 

  8. A. N. Zavilopulo, O. B. Shpenik, P. P. Markush, and M. I. Mykyta, Tech. Phys. Lett. 40(1), 13 (2014).

    Article  ADS  Google Scholar 

  9. NIST Standard Reference Database, http://www.web-book.nist.gov.

  10. B. Franziska, N. R. Qiao, G. Amir, et al., J. Am. Chem. Soc. 135, 14229 (2013).

    Article  Google Scholar 

  11. M. R. Nimlos, S. J. Blanksby, X. Qian, et al., J. Phys. Chem. A 110, 6145 (2006).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. N. Zavilopulo.

Additional information

Original Russian Text © A.N. Zavilopulo, O.B. Shpenik, P.P. Markush, E.E. Kontrosh, 2014, published in Pis’ma v Zhurnal Tekhnicheskoi Fiziki, 2014, Vol. 40, No. 19, pp. 1–10.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zavilopulo, A.N., Shpenik, O.B., Markush, P.P. et al. Ionization of the glycerin molecule by the electron impact. Tech. Phys. Lett. 40, 829–833 (2014). https://doi.org/10.1134/S1063785014100150

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063785014100150

Keywords

Navigation