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The surface structure of Langmuir-Blodgett films of comblike rigid-chain polyimide prepolymer studied by atomic force microscopy

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Abstract

The surface structure of a three-layer Langmuir-Blodgett film of comblike rigid-chain polyimide prepolymer (polyamic acid alkylammonium salt) has been studied by atomic force microscopy (AFM). The AFM data reveal the presence of supramolecular formations consisting of two-dimensional domains in which aliphatic chains of the prepolymer macromolecules are oriented perpendicularly to the substrate. A mechanism responsible for the supramolecular structure formation in the film is proposed.

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Authors and Affiliations

  1. St. Petersburg State Electrotechnical University, St. Petersburg, 197376, Russia

    S. I. Goloudina, V. V. Luchinin, V. V. Rozanov, V. M. Pasyuta, V. P. Sklizkova & V. V. Kudryavtsev

  2. Institute of Analytical Instrument Making, Russian Academy of Sciences, St. Petersburg, 198103, Russia

    S. I. Goloudina, V. V. Luchinin, V. V. Rozanov, V. M. Pasyuta, V. P. Sklizkova & V. V. Kudryavtsev

  3. Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, 199004, Russia

    S. I. Goloudina, V. V. Luchinin, V. V. Rozanov, V. M. Pasyuta, V. P. Sklizkova & V. V. Kudryavtsev

Authors
  1. S. I. Goloudina
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  2. V. V. Luchinin
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  3. V. V. Rozanov
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  4. V. M. Pasyuta
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  5. V. P. Sklizkova
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  6. V. V. Kudryavtsev
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Additional information

Original Russian Text © S.I. Goloudina, V.V. Luchinin, V.V. Rozanov, V.M. Pasyuta, V.P. Sklizkova, V.V. Kudryavtsev, 2006, published in Pis’ma v Zhurnal Tekhnicheskoĭ Fiziki, 2006, Vol. 32, No. 23, pp. 54–59.

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Goloudina, S.I., Luchinin, V.V., Rozanov, V.V. et al. The surface structure of Langmuir-Blodgett films of comblike rigid-chain polyimide prepolymer studied by atomic force microscopy. Tech. Phys. Lett. 32, 1024–1026 (2006). https://doi.org/10.1134/S106378500612008X

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  • DOI: https://doi.org/10.1134/S106378500612008X

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