Abstract
Systematic data on the amorphous–crystalline transition in Ni have been obtained by high-temperature X-ray diffraction analysis. It is established that the amorphous structure of Ni nanoparticles is stable up to 200°C. Ni nanocrystals, which have coherent-scattering regions (CSRs) 5–15 nm in size (depending on the isothermal annealing temperature) are formed in the temperature range of 300–600°C. The activation energy of nanocrystal growth has been estimated to be 67.3 kJ/mol. The dependence of the unit-cell parameter of nanocrystalline Ni on the CSR size is determined. An increase in the lattice constant is observed with an increase in CSR in nanocrystalline Ni particles.
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This study was supported by program no. 14.3 “Fundamentals and New Efficient Methods of Chemical Analysis and Investigation of the Structure of Substances and Materials” of the Presidium of the Russian Academy of Sciences.
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Kovalev, D.Y., Chuev, I.I. X-Ray Diffraction Analysis of the Amorphous–Crystalline Phase Transition in Ni. Tech. Phys. 65, 1652–1658 (2020). https://doi.org/10.1134/S1063784220100102
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DOI: https://doi.org/10.1134/S1063784220100102