Abstract
A composite based on ultra-high-molecular-weight polyethylene (UHMWPE) added with 1 wt % of multiwalled carbon nanotubes (MWCNTs) with a high permittivity (ε = 4.5) and a low dielectric loss (tanδ = 10–2) in the frequency range from 100 Hz to 100 MHz has been synthesized, and its main mechanical characteristics have been studied. The material has a low (22 MPa) breaking strength, a high (700%) tensile elongation, and an abrasion resistance higher than that of pure UHMWPE by 37%. It is shown using the X-ray diffraction and differential scanning calorimetry data that the changes in the mechanical properties of the composite are related to the changes in the polymer matrix structure under the action of the high-intensity ultrasonic radiation used for embedding MWCNTs into the polymer.
Similar content being viewed by others
REFERENCES
H. van der Werff and U. Heisserer, in Advanced Fibrous Composite Mater. Ballistic Protect, Ed. by X. Chen (Elsevier, 2016), Chap. 3, pp. 71–108. https://doi.org/10.1016/B978-1-78242-461-1.00003-0
R. Marissen, Mater. Sci. Appl. 2 (5), 319 (2011). https://doi.org/10.4236/msa.2011.25042
W. Li, D. Xiong, X. Zhao, L. Sun, and J. Liu, Mater. Des. 102, 162 (2016). https://doi.org/10.1016/j.matdes.2016.04.006
K. Karthikeyan and B. P. Russell, Mater. Des. 63, 115 (2014). https://doi.org/10.1016/j.matdes.2014.05.069
F. Ansaria, B. Gludovatz, A. Kozak, R. O. Ritchie, and L. A. Pruitt, J. Mech. Behav. Biomed. Mater. 60, 267 (2016). https://doi.org/10.1016/j.jmbbm.2016.02.014
A. V. Maksimkin, F. S. Senatov, V. D. Danilov, K. S. Mostovaya, S. D. Kaloshkin, M. V. Gorshenkov, A. P. Kharitonov, and D. I. Chukov, Mendeleev Commun. 26 (4), 350 (2016). https://doi.org/10.1016/j.mencom.2016.07.028
F. S. Senatov, A. N. Kopylov, N. Yu. Anisimova, M. V. Kiselevsky, and A. V. Maksimkin, Mater. Sci. Eng., C 48, 566 (2015). https://doi.org/10.1016/j.msec.2014.12.050
J. C. Baena, J. Wu, and Z. Peng, Lubricants 3 (2), 413 (2015). https://doi.org/10.3390/lubricants3020413
K. Plumlee and C. J. Schwartz, Wear 267 (5–8), 710 (2009). https://doi.org/10.1016/j.wear.2008.11.028
D. S. Xiong, J. M. Lin, and D. L. Fan, Biomed. Mater. 1 (3), 175 (2006). https://doi.org/10.1088/1748-6041/1/3/013
G. E. Selyutin, Yu. Yu. Gavrilov, O. E. Popova, E. N. Voskresenskaya, V. A. Poluboyarov, V. A. Voroshilov, and A. V. Turushev, RF Patent No. RU 2 381 242 C2, Byull. Izobret., No. 4 (2010).
M. T. Sebastian, S. Thomas, and S. George, Appl. Electromagnet. Conf. (AEMC),2009, pp. 1–4. https://doi.org/10.1109/AEMC.2009.5430628
Y. Kobayashi, T. Tanase, T. Tabata, T. Miwa, and M. Konno, J. Eur. Ceram. Soc. 28 (1), 117 (2008). https://doi.org/10.1016/j.jeurceramsoc.2007.05.007
S.-H. Xie, B.-K. Zhu, X.-Z. Wei, Z.-K. Xu, and Y.-Y. Xu, Composites, Part A 36 (8), 1152 (2005). https://doi.org/10.1016/j.compositesa.2004.12.010
K. M. Manu, S. Soni, V. R. K. Murthy, and M. T. Sebastian, J. Mater. Sci.: Mater. Electron. 24 (6), 2098 (2013). https://doi.org/10.1007/s10854-013-1064-y
J. Varghese, D. R. Nair, P. Mohanan, and M. T. Sebastian, Phys. Chem. Chem. Phys. 17, 14943 (2015). https://doi.org/10.1039/c5cp01242b
J. Macutkevic, A. Paddubskaya, P. Kuzhir, J. Banys, S. Maksimenko, V. L. Kuznetsov, I. N. Mazov, and D. V. Krasnikov, J. Nanosci. Nanotechnol. 14 (7), 5430 (2014). https://doi.org/10.1166/jnn.2014.8705
Q. Li, Q. Xue, Q. Zheng, L. Hao, and X. Gao, Mater. Lett. 62 (26), 4229 (2008). https://doi.org/10.1016/j.matlet.2008.06.047
L. J. Romasanta, M. Hernandez, M. F. López-Manchado, and R. Verdejo, Nanoscale Res. Lett. 6, 1 (2011). https://doi.org/10.1186/1556-276X-6-508
B. Meschi Amoli, S. A. Ahmad Ramazani, and H. Izadi, J. Appl. Polym. Sci. 125, E453 (2012). https://doi.org/10.1002/app.36368
S. L. Ruan, P. Gao, X. G. Yang, and T. X. Yu, Polymer 44 (19), 5643 (2003). https://doi.org/10.1016/S0032-3861(03)00628-1
A. V. Maksimkin, S. D. Kaloshkin, M. S. Kaloshkina, M. V. Gorshenkov, V. V. Tcherdyntsev, K. S. Ergin, and I. V. Shchetinin, J. Alloys Compd. 536 (1), 538 (2012). https://doi.org/10.1016/j.jallcom.2012.01.151
P.-C. Ma, N. A. Siddiqui, G. Marom, and J.-K. Kim, Composites, Part A 41 (10), 1345 (2010). https://doi.org/10.1016/j.compositesa.2010.07.003
M. O. Lisunova, Ye. P. Mamunya, N. I. Lebovka, and A. V. Melezhyk, Eur. Polym. J. 43 (3), 949 (2007). https://doi.org/10.1016/j.eurpolymj.2006.12.015
A. Mierczynska, M. Mayne-L’Hermite, G. Boiteux, and J. K. Jeszka, J. Appl. Polym. Sci. 105 (1), 158 (2007). https://doi.org/10.1002/app.26044
H. Pang, C. Chen, Y. Bao, J. Chen, X. Ji, J. Lei, and Z.-M. Li, Mater. Lett. 79, 96 (2012). https://doi.org/10.1016/j.matlet.2012.03.111
Y. Bin, A. Yamanaka, Q. Chen, Y. Xi, X. Jiang, and M. Matsuo, Polym. J. 39 (6), 598 (2007). https://doi.org/10.1295/polymj.PJ2006229
A. V. Eletskii, A. A. Knizhnik, B. V. Potapkin, and J. M. Kenny, Phys.-Usp. 58 (3), 209 (2015). https://doi.org/10.3367/UFNe.0185.201503a.0225
T. Deplancke, O. Lame, S. Barrau, K. Ravi, and F. Dalmas, Polymer 111, 204 (2017). https://doi.org/10.1016/j.polymer.2017.01.040
A. V. Maksimkin, S. D. Kaloshkin, M. S. Kaloshkina, M. V. Gorshenkov, V. V. Tcherdyntsev, K. S. Ergin, and I. V. Shchetinin, J. Alloys Compd. 536, S538 (2012). https://doi.org/10.1016/j.jallcom.2012.01.151
A. V. Maksimkin, K. S. Mostovaya, F. S. Senatov, D. I. Chukov, S. G. Nematulloev, and L. K. Olifirov, Results Phys. 7, 1044 (2017). https://doi.org/10.1016/j.rinp.2017.02.024
S. R. Bakshi, J. E. Tercero, and A. Agarwal, Composites, Part A 38 (12), 2493 (2007). https://doi.org/10.1016/j.compositesa.2007.08.004
A. V. Maksimkin, A. P. Kharitonov, K. S. Mostovaya, S. D. Kaloshkin, M. V. Gorshenkov, F. S. Senatov, D. I. Chukov, and V. V. Tcherdyntsev, Composites, Part B 94, 292 (2016). https://doi.org/10.1016/j.compositesb.2016.03.061
Y. A. Balogun and R. C. Buchanan, Composites Sci. Technol 70 (6), 892 (2010). https://doi.org/10.1016/j.compscitech.2010.01.009
I. Mazova, V. L. Kuznetsov, I. A. Simonova, A. I. Stadnichenko, A. V. Ishchenko, A. I. Romanenko, E. N. Tkachev, and O. B. Anikeeva, Appl. Surf. Sci. 258 (17), 6272 (2012). https://doi.org/10.1016/j.apsusc.2012.03.021
I. A. Markevich, G. E. Selyutin, N. A. Drokin, and B. A. Belyaev, Zh. Sib. Fed. Univ. Tekh. Tekhnol. 11 (2), 190 (2018). https://doi.org/10.17516/1999-494X-0022
D. K. Pradhan, R. N. P. Choudhary, and B. K. Samantaray, Int. J. Electrochem. Sci. 3, 597 (2008).
S. K. Bhateja, S. M. Yarbrough, and E. H. Andrews, J. Macromol. Sci., Part B: Phys. 29 (1), 1 (1990). https://doi.org/10.1080/00222349008212332
M. A. Kazakova, A. G. Selyutin, N. V. Semikolenova, A. V. Ishchenko, S. I. Moseenkov, M. A. Matsko, V. A. Zakharov, and V. L. Kuznetsova, Composites Sci. Technol. 167 (20), 148 (2018). https://doi.org/10.1016/j.compscitech.2018.07.046
ACKNOWLEDGMENTS
The authors are grateful to M.A. Mats’ko, Cand. Chem. Sci., head of the laboratory of the Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, and his colleagues for help in this work.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflicts of interest.
Additional information
Translated by E. Bondareva
Rights and permissions
About this article
Cite this article
Markevich, I.A., Selyutin, G.E., Drokin, N.A. et al. Electrical and Mechanical Properties of the High-Permittivity Ultra-High-Molecular-Weight Polyethylene-Based Composite Modified by Carbon Nanotubes. Tech. Phys. 65, 1106–1113 (2020). https://doi.org/10.1134/S1063784220070129
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1063784220070129