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Synthesis of Heterogeneous ZnO/Co3O4 Nanostructures by Chemical Deposition from Solutions

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Abstract

Nanocrystalline cobalt oxide Co3O4 and composite ZnO/Co3O4 are obtained by chemical deposition from solutions followed by thermal annealing. It is shown that the presence of zinc oxide particles during synthesis radically changes the mechanism of the cobalt carbonates growth, which leads to a change in the phase composition, morphology, and properties of the material. The resistivity of the conducting layers formed from composite ZnO/Co3O4 is three orders of magnitude lower than the resistivity of Co3O4 layers, and composite ZnO/Co3O4 gas sensors demonstrate much higher gas sensitivity than that of control cobalt oxide sensors.

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Funding

This study was supported in part by the Ministry of Education and Science of the Republic of Kazakhstan, grant no. BR05236404.

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Authors and Affiliations

  1. National Nanotechnological Open-Type Laboratory, Al Farabi Kazakh National University, 050040, Almaty, Kazakhstan

    Kh. A. Abdullin, S. K. Zhumagulov, G. A. Ismailova & Zh. K. Kalkozova

  2. Satbayev University, Institute of Physics and Technology, 050032, Almaty, Kazakhstan

    V. V. Kudryashov & A. S. Serikkanov

Authors
  1. Kh. A. Abdullin
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  2. S. K. Zhumagulov
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  3. G. A. Ismailova
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  4. Zh. K. Kalkozova
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  5. V. V. Kudryashov
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  6. A. S. Serikkanov
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Correspondence to Kh. A. Abdullin.

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The authors declare that they have no conflicts of interest.

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Translated by N. Wadhwa

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Abdullin, K.A., Zhumagulov, S.K., Ismailova, G.A. et al. Synthesis of Heterogeneous ZnO/Co3O4 Nanostructures by Chemical Deposition from Solutions. Tech. Phys. 65, 1139–1143 (2020). https://doi.org/10.1134/S1063784220070026

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  • DOI: https://doi.org/10.1134/S1063784220070026

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