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Thermal Effects Due to Crystallization of Alloys with Unlimited and Limited Solubility of Components

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Abstract

High-resolution differential scanning calorimetry has been used to study the crystallization of binary alloys with unlimited and limited solubility of their constituents. A sharp and intense emission of crystallization heat has been invariably observed immediately below the liquidus curve. Standard techniques to describe crystallization in the intercritical temperature range cannot explain the above phenomena. It is assumed that they may be associated with a large number of local microvolumes enriched with a crystallization-controlling component (concentration fluctuations) that appear in the liquid as approaching the liquidus curve. The appearance of such microvolumes precedes the spontaneous formation of many crystallites in a large volume of the liquid phase.

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REFERENCES

  1. Ya. S. Umanskii, B. I. Finkel’shtein, and M. E. Blanter, Physical Metallography (Metallurgizdat, Moscow, 1958).

    Google Scholar 

  2. Ya. S. Umanskii and Yu. A. Skakov, Metal Physics (Atomizdat, Moscow, 1978).

    Google Scholar 

  3. H. Biloni and W. J. Boetinger, in Physical Metallurgy, 4th ed., Ed. by R. W. Cahn and P. Haasen (North-Holland, Amsterdam, 1996), p. 669.

    Google Scholar 

  4. M. E. Glicksman, Principles of Solidification: An Introduction to Modern Casting and Crystal Growth Concepts (Springer, New York, 2011).

    Book  Google Scholar 

  5. W. Kurz and D. J. Fisher, Fundamentals of Solidification, 4th ed. (Trans Tech, 1998).

    Book  Google Scholar 

  6. N. S. Kurnakov, Introduction to Physicochemical Analysis, 4th ed. (Akad. Nauk SSSR, Moscow, Leningrad, 1940).

    Google Scholar 

  7. B. Cantor, J. Therm. Anal. 42, 647 (1994).

    Article  ADS  Google Scholar 

  8. L. Heusler and W. Schneider, J. Light Metals 2, 17 (2002).

    Article  Google Scholar 

  9. J. Piatkowski, V. Przeliorz, and V. Szymszal, Arch. Foundry Eng. 17, 207 (2017).

    Article  Google Scholar 

  10. J. Piatkowski and B. Gajdzik, Metalurgija 52, 469 (2013).

    Google Scholar 

  11. A. V. Skripov and V. P. Skripov, Sov. Phys. Usp. 22, 389 (1979).

    Article  ADS  Google Scholar 

  12. E. S. Venttsel’ and L. A. Ovcharov, Probability Theory and Its Engineering Applications, 2nd ed. (Vysshaya Shkola, Moscow, 2000).

  13. L. V. Spivak and N. E. Shepina, Fundam. Probl. Sovrem. Materialoved. 11, 376 (2014).

    Google Scholar 

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Authors and Affiliations

  1. Perm State National Research University, 614990, Perm, Russia

    L. V. Spivak

  2. Natural Science Institute, Perm State National Research University, 614990, Perm, Russia

    N. E. Shchepina

Authors
  1. L. V. Spivak
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  2. N. E. Shchepina
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Correspondence to L. V. Spivak or N. E. Shchepina.

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Translated by V. Isaakyan

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Spivak, L.V., Shchepina, N.E. Thermal Effects Due to Crystallization of Alloys with Unlimited and Limited Solubility of Components. Tech. Phys. 64, 1319–1323 (2019). https://doi.org/10.1134/S1063784219090184

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  • DOI: https://doi.org/10.1134/S1063784219090184

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