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Phonon Thermal Conductivity and Phase Equilibria of Fractal Bi–Sb Nanoparticles

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Abstract

The thermal conductivity component associated with lattice vibrations is one of the quantities determining the thermoelectric activity of a material. We have simulated the dependences of phase composition and the phonon component of the thermal conductivity associated with it on the shape of nanoparticles of a Bi–Sb alloy with an equiatomic composition and with core–shell configuration. The shape of a particle is simulated by a coefficient corresponding to the extent of deviation of the particle shape from spherical or by its fractal dimension. It is shown that mutual solubilities of components depend on the nanoparticle shape and on the mutual arrangement of coexisting phases, and the thermodynamic equilibrium position for particles with complex morphology corresponds to the homogeneous state. Homogenization of a nanoparticle reduces the phonon component of its thermal conductivity by 70–80%.

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FUNDING

This study was supported by the Russian Foundation for Basic Research (project no. 18-08-01356), as well as the Russian Foundation for Basic Research and Administration of Nizhegorodskaya oblast (project no. 18-43-520039).

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Authors and Affiliations

  1. Razuvaev Institute of Metalorganic Chemistry, Russian Academy of Sciences, 603137, Nizhny Novgorod, Russia

    A. V. Shishulin & V. B. Fedoseev

  2. Dzerzhinsk Polytechnic Institute, Alekseev Nizhny Novgorod State Technical University, 606026, Dzerzhinsk, Russia

    A. V. Shishulina

  3. Lobachevsky State University of Nizhny Novgorod, 603137, Nizhny Novgorod, Russia

    A. V. Shishulina

Authors
  1. A. V. Shishulin
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  2. V. B. Fedoseev
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  3. A. V. Shishulina
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Correspondence to A. V. Shishulin.

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Translated by N. Wadhwa

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Shishulin, A.V., Fedoseev, V.B. & Shishulina, A.V. Phonon Thermal Conductivity and Phase Equilibria of Fractal Bi–Sb Nanoparticles. Tech. Phys. 64, 512–517 (2019). https://doi.org/10.1134/S1063784219040200

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