Abstract
Using methods of optical spectroscopy and small-angle X-ray scattering, the kinetics of the UV radiation-induced formation of gold nanoparticles in HAuCl4-doped water–acid solutions of chitosan has been studied from the very beginning of the reaction. It has been shown that, during synthesis, as the mean size of nanoparticles grows from 2.9 to 6.3 nm, the maximum of the plasmon resonance shifts toward shorter waves (535–523 nm), whereas for a fully formed ensemble of nanoparticles, the reverse trend is observed. It has been found experimentally that the particle size distribution curve changes during synthesis. Based on the inverse problem analysis, conclusions have been drawn regarding the dominant mechanisms behind nanoparticle growth.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
S. Srivastava, M. Haridas, and J. K. Basu, Bull. Mater. Sci. 31, 213 (2008).
A. Yu. Olenin and G. V. Lisichkin, Russ. Chem. Rev. 80, 605 (2011).
A. V. Korshunov, G. V. Kashkan, K. T. T. Nguen, and S. V. Zyong, Izv. Tomsk. Politekh. Univ. 318 (3), 12 (2011).
A. A. Bogdanov and A. O. Pozdnyakov, Tech. Phys. Lett. 40, 987 (2014).
L. A. Smirnova, T. A. Gracheva, A. E. Mochalova, T. A. Kuz’micheva, and E. N. Fedoseeva, Nanotechnol. Russ. 5, 78 (2010).
T. A. Gracheva, T. A. Kuz’micheva, V. N. Perevezentsev, A. E. Mochalova, L. A. Smirnova, and E. V. Salomatina, J. Surf. Invest.: X-Ray, Synchrotron Neutron Tech. 5, 426 (2011).
N. G. Khlebtsov, V. A. Bogatyrev, et al., Ross. Nanotekhnol. 2 (3–4), 69 (2007).
A. S. Koryagin, A. E. Mochalova, E. V. Salomatina, O. Yu. Eshkova, and L. A. Smirnova, Inorg. Mater.: Appl. Res. 4, 127 (2013).
B. Fasla, A. R. Senoudi, A. Boussaid, M. Benmouna, and R. Benmouna, J. Biomater. Nanobiotechnol. 2, 49 (2011).
S. Yang, Y. Wang, Q. Wang, R. Zhang, and B. Ding, Colloids Surf., A 301, 174 (2007).
U. Kreibig, G. Bour, A. Hilger, and M. Gartz, Phys. Status Solidi A 175, 351 (1999).
P. A. Obraztsov, A. V. Nashchekin, N. V. Nikonorov, A. I. Sidorov, A. V. Panfilova, and P. N. Brunkov, Phys. Solid State 55, 1272 (2013).
A. O. Rybaltovskii, S. S. Ilyukhin, N. V. Minaev, P. S. Timashev, V. I. Yusupov, and V. N. Bagratashvili, Nanotechnol. Russ. 9, 227 (2014).
B. Wang, X. Zhuang, W. Deng and B. Cheng, Engineering 2, 387 (2010).
L. Yu. Ammon, Nanotekhnika, No. 2, 93 (2011).
A. V. Rogov and S. S. Fanchenko, Tech. Phys. 57, 286 (2012).
B. Wiley, Y. Sun, B. Mayers, and Y. Xia, Chem.-Eur. J. 11, 454 (2005).
H.-B. Yi, M. Diefenbach, Y. C. Choi, C. E. Lee, H. M. Lee, B. H. Hong, and K. S. Kim, Chem.-Eur. J. 12, 4885 (2006).
C. G. Granqvist and R. A. Buhrman, J. Appl. Phys. 47, 2200 (1976).
A. Yu. Olenin, Nanotechnol. Russ. 7, 238 (2012).
D. I. Svergun and L. A. Feigin, X-Ray and Neutron Small-Angle Scattering (Nauka, Moscow, 1986).
D. I. Svergun, J. Appl. Crystallogr. 25, 495 (1992).
C. F. Bohren and D. R. Huffman, Absorption and Scattering of Light by Small Particles (Wiley, 1983).
B. G. Ershov, Ross. Khim. Zh. 45, 20 (2001).
T. A. Kuz’micheva, Extended Abstract of Candidate’s Dissertation in Mathematics and Physics (Lobachevsky State Univ. of Nizhny Novgorod, Nizhny Novgorod, 2013).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © T.A. Gracheva, T.A. Kuz’micheva, V.N. Perevezentsev, L.A. Smirnova, A.E. Mochalova, E.B. Salomatina, 2017, published in Zhurnal Tekhnicheskoi Fiziki, 2017, Vol. 87, No. 8, pp. 1216–1220.
Rights and permissions
About this article
Cite this article
Gracheva, T.A., Kuz’micheva, T.A., Perevezentsev, V.N. et al. Kinetics and mechanisms of the UV-radiation-assisted formation of gold nanoparticles in HAuCl4-doped chitosan solutions. Tech. Phys. 62, 1228–1232 (2017). https://doi.org/10.1134/S1063784217080138
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1063784217080138