Abstract
Dynamic characteristics of the quadrupole mass filter (QMF) with the parametric resonance excitation of ion oscillations by a low additional HF voltage are studied by numerical methods. The upper stability island formed by instability bands that follow the isolines of stability parameters of the unperturbed first stability band is considered. Isolines of characteristic indices on the island’s parameter plane are calculated. Ion trajectories at characteristic points near the x and y island boundaries, which have the form of beats, are presented. Parameters of the ellipses are determined as functions of the initial phase at which the ions enter the HF field. These parameters are shown to be periodic with a period of π with respect to the phase shift between the main and additional HF voltages. As a result, the QMF acceptance and, consequently, transmittance have maxima as functions of the phase shift. Therefore, to increase the QMF transmittance, the biharmonic signal must be synchronized.
Similar content being viewed by others
References
R. L. Alfred, F. A. Londry, and R. E. March, Int. J. Mass Spectrom. Ion Processes 124, 171 (1993).
M. Yu. Sudakov, N. V. Konenkov, D. J. Douglas, and T. Glebova, J. Am. Soc. Mass Spectrom. 11, 10 (2000).
M. Yu. Sudakov, Pis’ma Zh. Tekh. Fiz. 26(19), 46 (2000) [Tech. Phys. Lett. 26, 870 (2000)].
N. V. Konenkov, M. Yu. Sudakov, and D. J. Douglas, J. Am. Soc. Mass Spectrom. 13, 597 (2002).
M. Abramovitz and I. Stegun, Handbook of Mathematical Functions, Applied Mathematics, Ser. 55 (National Bureau of Standards, Washington, 1964), p. 557.
B. A. Collings and D. J. Douglas, J. Am. Soc. Mass Spectrom. 11, 1016 (2000).
N. V. Konenkov, L. M. Cousins, V. I. Baranov, and M. Yu. Sudakov, Int. J. Mass Spectrom. 208, 17 (2001).
V. I. Baranov, N. V. Konenkov, and S. D. Tunner, in Plasma Sourse Mass Spectrometry. The New Millemium, Ed. by J. Holland and S. D. Tanner (Royal Society of Chemistry, Cambridge, 2001), pp. 63–72.
X. Zhao, V. L. Ryjkov, and H. A. Schuessler, Phys. Rev. A 66, 1 (2002).
P. H. Dawson, Quadrupole Mass Spectrometry and Its Applications (American Institute of Physics, New York, 1995).
G. M. Slobodenyuk, Quadrupole Mass Specrtometry (Atomizdat, Moscow, 1974) [in Russian].
R. E. March and R. J. Hughes, Quadrupole Storage Mass Spectrometry (Wiley, New York, 1989).
F. J. Todd, F. M. Waldren, D. A. Freer, and J. F. Turner, Ion Phys. 35, 107 (1980).
P. H. Dawson, Int. J. Mass Spectrom. Ion Process 100, 41 (1990).
V. I. Baranov, J. Am. Mass Spectrom. 14, 818 (2003).
V. I. Baranov, J. Am. Mass Spectrom. 15, 48 (2004).
N. V. Konenkov, G. A. Mogil’chenko, and S. S. Silakov, Zh. Tekh. Fiz. 62(9), 165 (1993) [Tech. Phys. 37, 967 (1993)].
N. V. Konenkov, Int. J. Mass Spectrom. Ion Process 123, 101 (1993).
N. V. Konenkov, ZHTF. Zh. Tekh. Fiz. 67(10), 121 (1997) [Tech. Phys. 42, 1220 (1997)].
D. J. Douglas and N. V. Konenkov, J. Am. Soc. Mass Spectrom. 9, 1074 (1998).
Z. Du, D. J. Douglas, and N. V. Konenkov, J. Anal. At. Spectrom. 14, 1111 (1999).
T. Glebova and N. V. Konenkov, Eur. J. Mass Spectrom. 8, 201 (2002).
E. Hairer, S. Nersett, and G. Wanner, Solving Ordinary Differential Equations, Vol. 1: Nonstiff Problems (Springer, Berlin, 1987–1991; Mir, Moscow, 1990).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © N.V. Konenkov, M.N. Makhmudov, Yu.V. Strashnov, 2009, published in Zhurnal Tekhnichesko oe Fiziki, 2009, Vol. 79, No. 5, pp. 95–100.
Rights and permissions
About this article
Cite this article
Konenkov, N.V., Makhmudov, M.N. & Strashnov, Y.V. Acceptance of the quadrupole mass filter in the upper stability island under biharmonic excitation. Tech. Phys. 54, 698–703 (2009). https://doi.org/10.1134/S1063784209050144
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1063784209050144