Abstract
The subject of investigation is the kinetic mechanisms intensifying chain reactions that proceed in a hydrogen-air mixture when O2 molecules dissociate under the action of laser radiation with wavelength λ I = 193.3 nm and are excited into the b 1Σ + g electron state by radiation with λ I = 762.346 nm. The efficiencies of both methods to initiate ignition are compared. Numerical simulation shows that the ignition temperature for the laser-induced excitation of O2 molecules into theb 1Σ + g state is lower than for the dissociation of O2 molecules by UV laser radiation, with the energy supplied to the mixture being the same. However, both photochemical methods are much more efficient than mere heating of the mixture by laser radiation or another source of heat.
Similar content being viewed by others
References
D. Lucas, D. Dunn-Rankin, K. Hom, and N. J. Brown, Combust. Flame 69, 171 (1987).
M. Lavid, Y. Nachshon, S. K. Gulati, and J. G. Stevens, Combust Sci. Technol. 96, 231 (1994).
P. D. Ronney, Opt. Eng. 33, 510 (1994).
A. M. Starik and N. S. Titova, Zh. Tekh. Fiz. 73(3), 59 (2003) [Tech. Phys. 48, 334 (2003)].
A. M. Starik, N. S. Titova, and B. I. Loukhovitskii, Zh. Tekh. Fiz. 74(1), 77 (2004) [Tech. Phys. 49, 76 (2004)].
B. I. Loukhovitskii, A. M. Starik, and N. S. Titova, Fiz. Goreniya Vzryva 41, 29 (2005).
M. Nicolet, S. Cleslik, and R. Kennes, Planet. Space Sci. 31, 427 (1989).
K. J. Ritter and T. D. Wilkerson, J. Mol. Spectrosc. 121, 1 (1987).
N. Seiser and D. C. Robie, Chem. Phys. Lett. 282, 263 (1998).
Y. Yoshino, D. E. Freeman, and W. H. Parkinson, J. Phys. Chem. Ref. Data 13, 207 (1984).
A. M. Starik and N. S. Titova, Kinet. Katal. 44, 35 (2003).
V. I. Dimitrov, Doctoral Dissertation in Mathematical and Physics (Institute of Theoretical and Applied Mechanics Siberian Branch of Russian Academy of Sciences, Novosibirsk, 1981).
E. P. Dougherty and H. Rabitz, J. Chem. Phys. 72, 6571 (1980).
N. G. Dautov and A. M. Starik, Teplofiz. Vys. Temp. 31, 292 (1993).
N. M. Emmanuel’ and D. G. Knorre, Lectures on Chemical Kinetics (Vysshaya Shkola, 1974) [in Russian].
R. R. Craig, A Shock Tube Study of the Ignition Delay of Hydrogen-Air Mixtures Near the Second Explosion Limit, Air Force Aero-Propulsion Lab., Wright-Patterson, Technical Report No. AFAPL-TR-66-74, 1966.
A. D. Snyder, J. Robertson, D. L. Zanders, and G. B. Skinner, Shock Tube Studies of Fuel-Air Ignition Characteristics, Technical Report No. AFAPL-TR-65-93, 1965.
M. Slack and A. Grillo, Investigation of Hydrogen-Air Ignition Sensitized by Nitric Oxide and Nitrogen Dioxide, NASA Report No. CR-2896, 1977.
E. Schultz and J. Shepherd, Validation of Detailed Reaction Mechanisms for Detonation Simulation, California Institute of Technology, Report No. FM99-5, 2000.
G. P. Smith, D. M. Golden, M. Frenklach, N. W. Moriarty, B. Eiteneer, M. Goldenberg, C. T. Bowman, R. Hanson, S. Song, W. C. Gardiner, V. Lissianski, and Z. Qin, http://www.me.berkeley.edu/gri_mech/.
T. Just and F. Schmalz, AGARD Conf. Proc., No. 34, Pt. 2, p. 19.
L. T. Cupitt, G. A. Takacs, and G. P. Glass, Int. J. Chem. Kinet. 14, 487 (1982).
V. Ya. Basevich and V. I. Vedeneev, Khim. Fiz. 4, 1102 (1985).
M. A. Mueller, T. J. Kim, R. A. Yetter, and F. L. Dryer, Int. J. Chem. Kinet. 31, 113 (1999).
V. V. Azatyan, N. M. Rubtsov, G. I. Tsvetkov, and V. I. Chernysh, Zh. Fiz. Khim. 79, 397 (2005).
D. L. Baulch, C. T. Bowman, C. J. Cobos, et al., J. Phys. Chem. Ref. Data 34, 757 (2005).
M. Capitelli, C. M. Ferreira, B. F. Gordiets, and A. I. Osipov, Plasma Kinetics in Atmospheric Gases (Springer, Berlin, 2000), Springer Series on Atomic Optical and Plasma Physics, No. 31.
T. G. Slanger and R. A. Copeland, Chem. Rev. 103, 4731 (2003).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.M. Starik, P.S. Kuleshov, N.S. Titova, 2009, published in Zhurnal Tekhnicheskoĭ Fiziki, 2009, Vol. 79, No. 3, pp. 28–38.
Rights and permissions
About this article
Cite this article
Starik, A.M., Kuleshov, P.S. & Titova, N.S. Laser-initiated ignition of hydrogen-air mixtures. Tech. Phys. 54, 354–364 (2009). https://doi.org/10.1134/S1063784209030050
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1063784209030050