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Phase Transition of the Potassium Nitrate Ferroelectric in a Nanoporous Matrix

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Abstract

Nanocomposite materials which are silicate nanoporous matrices filled with KNO3 are studied by the calorimetric method. The anomalies observed in the specific heat related to the ferroelectric phase transitions are studied in the framework of the smeared phase transition theory. The extrapolation of results confirms the assumption made before that there is the minimum pore size in the nanocomposite at which KNO3 at room temperature will be completely in the ferroelectric state.

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REFERENCES

  1. S. V. Baryshnikov, E. V. Charnaya, A. Yu. Milinskiy, and Yu. V. Patrushev, Phys. Solid State 55, 2566 (2013).

    Article  ADS  Google Scholar 

  2. Ferroelectrics — Material Aspect, Ed. by M. Lallart (InTech, Rijeka, 2011).

    Google Scholar 

  3. J. S. Beck, J. C. Vartuli, and W. J. Roth, J. Am. Chem. Soc. 114, 10834 (1992).

    Article  Google Scholar 

  4. F. Jona and D. Shirane, Ferroelectric Crystals (Dover, New York, 1993).

    Google Scholar 

  5. G. A. Smolenskii, V. A. Bokov, V. A. Isupov, N. N. Krainik, R. E. Pasynkov, and M. S. Shur, Ferroelectrics and Antiferroelectrics (Nauka, Moscow, 1971) [in Russian].

    Google Scholar 

  6. V. V. Deshpande, M. D. Karkhanavala, and U. R. K. Rao, J. Therm. Anal. Calorim. 6, 613 (1974).

    Article  Google Scholar 

  7. K. Illers, Eur. Polym. J. 10, 911 (1974).

    Article  Google Scholar 

  8. V. A. Bershtein and V. M. Egorov, Differential Scanning Calorimetry of Polymers: Physics, Chemistry, Analysis, Technology (Ellis Horwood, New York, 1994).

    Google Scholar 

  9. M. Fisher, The Nature of Critical Points (Univ. Colorado Press, Boulder, CO, 1965).

  10. G. A. Malygin, Phys. Usp. 44, 173 (2001).

    Article  ADS  Google Scholar 

  11. W. Kanzig, Ferroelectrics and Antiferroelectrics (Academic, New York, 1964).

    Google Scholar 

  12. G. A. Malygin, Phys. Solid State 43, 1909 (2001).

    Article  ADS  Google Scholar 

  13. S. V. Baryshnikov, E. V. Charnaya, A. Yu. Milinskii, Yu. A. Shatskaya, and D. Michel, Phys. Solid State 54, 636 (2012).

    Article  ADS  Google Scholar 

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Correspondence to V. M. Egorov.

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Translated by Yu. Ryzhkov

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Egorov, V.M., Markov, Y.F., Roginskii, E.M. et al. Phase Transition of the Potassium Nitrate Ferroelectric in a Nanoporous Matrix. Phys. Solid State 63, 1165–1169 (2021). https://doi.org/10.1134/S1063783421080096

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  • DOI: https://doi.org/10.1134/S1063783421080096

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