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Structure and Electrical Conductivity of the Perovskites Pr1 – xSrxMnO3 (x = 0, 0.15, or 0.25)

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Abstract

The manganites Pr1 – xSrxMnO3 (x = 0, 0.15, or 0.25) prepared by a solid state synthesis method at a temperature of 1250°C have an orthorhombic perovskite-like structure (the Pbnm space group). To investigate the effect that the substitution of strontium for praseodymium has on temperature-related features of crystal lattice transformation in the considered perovskites, we perform multifaceted characterization of the samples using high-temperature X-ray diffraction and differential thermal analysis. We find that adding strontium considerably lowers the temperature of Jahn–Teller effect. The conduction of all considered samples exhibits a semiconducting behavior. Doping with strontium raises the electrical conductivity of the praseodymium manganites, especially at temperatures below 450°C.

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Funding

This work was supported within a state assignment to the Institute of Metallurgy, Ural Branch, Russian Academy of Sciences, and performed using the facilities of the Center for Collective Use “Ural-M.”

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Authors and Affiliations

  1. Institute of Metallurgy, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia

    L. B. Vedmid’, O. M. Fedorova & V. F. Balakirev

  2. Ural Federal University Named after the First President of Russia B. N. Yeltsin, Yekaterinburg, Russia

    L. B. Vedmid’ & V. A. Vorotnikov

  3. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia

    V. B. Balakireva & V. A. Vorotnikov

Authors
  1. L. B. Vedmid’
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  2. O. M. Fedorova
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  3. V. B. Balakireva
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  4. V. A. Vorotnikov
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  5. V. F. Balakirev
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Correspondence to L. B. Vedmid’.

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Translated by A. Kukharuk

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Vedmid’, L.B., Fedorova, O.M., Balakireva, V.B. et al. Structure and Electrical Conductivity of the Perovskites Pr1 – xSrxMnO3 (x = 0, 0.15, or 0.25). Phys. Solid State 63, 660–665 (2021). https://doi.org/10.1134/S1063783421040235

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  • DOI: https://doi.org/10.1134/S1063783421040235

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