Skip to main content
SpringerLink
Log in

Synthesis, Structure, and Thermophysical Properties of Pb10 – xBix(GeO4)2 + xVO4)4 – x (x = 0–3) in the Temperature Range of 350–950 K

  • SEMICONDUCTORS
  • Published:
Physics of the Solid State Aims and scope Submit manuscript

Abstract

The Pb10 – xBix(GeO4)2 + x(VO4)4 – x (x = 0–3) compounds with an apatite structure have been obtained for the first time from the initial PbO, Bi2O3, GeO2, and V2O5 oxides by the solid-state synthesis in the temperature range of 773–1073 K. The structure of the compounds has been determined by X-ray diffraction analysis. The effect of temperature on specific heat of the synthesized compounds has been investigated by differential scanning calorimetry. The thermodynamic properties of the compounds have been calculated from the experimental Cp = f(T) data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. T. Yano, Y. Nabeta, and A. Watanabe, Appl. Phys. Lett. 18, 570 (1971).

    ADS  Google Scholar 

  2. S. A. Ivanov, Zh. Strukt. Khim 31, 80 (1990).

    Google Scholar 

  3. M. Gospodinov, Cryst. Res. Technol. 25 (3 (K61)) (1990).

  4. M. Gospodinov, D. Petrova, P. Sveshtarov, and V. Marinova, Mater. Res. Bull. 31, 1001 (1996).

    Google Scholar 

  5. L. Kovács, A. Péter, M. Gospodiniv, and R. Capelletti, Phys. Status Solidi C 2, 689 (2005).

    ADS  Google Scholar 

  6. E. Chakroun-Ouadhour, R. Ternane, D. Ben Hassan-Chehimi, and M. Trabelsi-Ayadi, Mater. Res. Bull. 43, 2451 (2008).

    Google Scholar 

  7. M. Pasero, A. R. Kampf, C. Ferraris, I. V. Pekov, J. Rakovan, and T. J. White, Eur. J. Miner. 22, 163 (2010).

    Google Scholar 

  8. F. X. Zhang, M. Lang, J. M. Zhang, Z. Q. Cheng, Z. X. Liu, J. Lian, and R. C. Ewing, Phys. Rev. B 85, 214116 (2012).

    ADS  Google Scholar 

  9. L. T. Denisova, E. O. Golubeva, N. V. Belousova, V. M. Denisov, and N. A. Galiakhmetova, Phys. Solid State 61, 1343 (2019).

    ADS  Google Scholar 

  10. S. V. Dobrydnev and M. Yu. Molodtsova, Izv. TulGU, Estestv. Nauki, No. 1, 212 (2014).

    Google Scholar 

  11. A. V. Ignatov, G. M. Savinkova, E. G. Didorenko, A. Yu. Talykova, E. I. Get’man, and L. V. Pasechnik, Vestn. Donets. Nats. Univ., Ser. A 1, 152 (2014).

    Google Scholar 

  12. T. Kanazava, Inorganic Phosphate Materials (Nauk. Dumka, Kiev, 1998) [in Russian].

    Google Scholar 

  13. V. D. Zhuravlev and Yu. A. Velikodny, Russ. J. Inorg. Chem. 54, 1551 (2009).

    Google Scholar 

  14. V. K. Karzhavin, Thermodynamic Quantities of Chemical Elements. Examples of their Practical Application (Kol’sk. Nauch. Tsentr RAN, Apatity, 2011) [in Russian].

    Google Scholar 

  15. Bruker AXS TOPAS V4: General Profile and Structure Analysis Software for Powder Diffraction Data, User’s Munual (Bruker AXS, Karsruhe, Germany, 2008).

  16. L. T. Denisova, L. A. Irtyugo, Yu. F. Kargin, V. V. Beletskii, and V. M. Denisov, Inorg. Mater. 53, 93 (2017).

    Google Scholar 

  17. S. A. Ivanov and V. E. Zavodnik, Sov. Phys. Crystallogr. 34, 493 (1989).

    Google Scholar 

  18. L. T. Denisova, Yu. F. Kargin, E. O. Golubeva, N. V. Belousova, and V. M. Denisov, Inorg. Mater. 55, 162 (2019).

    Google Scholar 

  19. D. Stall, E. Westram, and G. Zinke, Chemical Thermodynamics of Organic Compounds (Wiley, New York, 1969).

    Google Scholar 

  20. C. G. Maier and K. K. Kelley, J. Am. Chem. Soc. 54, 3243 (1932).

    Google Scholar 

  21. L. T. Denisova, A. D. Izotov, Yu. F. Kargin, V. M. Denisov, and N. A. Galiakhmetova, Dokl. Phys. Chem. 62, 205 (2017).

    Google Scholar 

  22. L. F. Reznitskii, Solid State Calorimetry: Structural, Magnetic, Electronic Transformations (Mosk. Gos. Univ., Moscow, 1981) [in Russian].

    Google Scholar 

  23. G. K. Moiseev, N. A. Vatolin, L. A. Marshuk, and N. I. Il’inykh, Temperature Dependences of the Reduced Gibbs Energy of Some Inorganic Substances (Alternative Data Bank ASTRA.OWN) (Ural. Otdel. RAN, Yekaterinburg, 1997) [in Russian].

    Google Scholar 

  24. J. Leitner, P. Chuchvalec, D. Sedmidubsý, A. Strejc, and P. Abrman, Thermochim. Acta 395, 27 (2003).

    Google Scholar 

  25. J. Laitner, P. Voñka, D. Sedmidubský, and P. Svoboda, Thermochim. Acta 497, 7 (2010).

    Google Scholar 

  26. V. N. Kumok, Direct and Inverse Problems of Chemical Thermodynamics (Nauka, Novosibirsk, 1987), p. 108 [in Russian].

    Google Scholar 

Download references

ACKNOWLEDGMENTS

We are grateful to the Krasnoyarsk Regional Center for Collective Use, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences.

Funding

The study was carried out under the state assignment for science for the Siberian Federal University, project no. FSRZ-2020-0013.

Author information

Authors and Affiliations

  1. Siberian Federal University, Institute of Metallurgy and Materials Science, Krasnoyarsk, 660041, Russia

    L. T. Denisova, V. M. Denisov, E. O. Golubeva & N. A. Galiakhmetova

  2. Siberian Federal University, Institute of Engineering Physics and Radio Electronics, Krasnoyarsk, 660041, Russia

    M. S. Molokeev

  3. Kirensky Institute of Physics, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russia

    M. S. Molokeev

Authors
  1. L. T. Denisova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. S. Molokeev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. M. Denisov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. O. Golubeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. N. A. Galiakhmetova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to L. T. Denisova.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by E. Bondareva

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Denisova, L.T., Molokeev, M.S., Denisov, V.M. et al. Synthesis, Structure, and Thermophysical Properties of Pb10 – xBix(GeO4)2 + xVO4)4 – x (x = 0–3) in the Temperature Range of 350–950 K. Phys. Solid State 62, 2045–2051 (2020). https://doi.org/10.1134/S1063783420110116

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063783420110116

Keywords:

Search

Navigation