Study of Kinetics of Solid Phase Transition in Tetracosane С24Н50 by High-Resolution Synchrotron X-Ray Powder Diffraction

Abstract

Using the small-angle synchrotron X-ray diffraction method at the research facility “BELOK” of the Kurchatov synchrotron radiation source at the NRC Kurchatov Institute, it was shown that the first-order solid phase transition in tetracosane C24H50 passes according to a heterogeneous mechanism in a narrow temperature range ΔT ~ 1 K in accordance with the theory of diffuse phase transitions.

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REFERENCES

  1. 1

    A. S. Fleischer, Thermal Energy Storage Using Phase Change Materials (Springer, Heidelberg, 2015).

    Google Scholar 

  2. 2

    D. M. Small, The Physical Chemistry of Lipids (Plenum, New York, 1986).

    Google Scholar 

  3. 3

    K. Mukherjee, Phys. Rep. 588, 1 (2015).

    ADS  MathSciNet  Article  Google Scholar 

  4. 4

    M. Dirand, M. Bouroukba, V. Chevallier, D. Petitjean, E. Behar, and V. Ruffier-Meray, J. Chem. Eng. Data 47, 115 (2002).

    Article  Google Scholar 

  5. 5

    V. M. Egorov, V. A. Marikhin, and L. P. Myasnikova, Polym. Sci., A 49, 1366 (2007).

  6. 6

    V. M. Egorov, V. A. Marikhin, L. P. Myasnikova, and P. N. Yakushev, Phys. Solid State 59, 2070 (2017).

    ADS  Article  Google Scholar 

  7. 7

    B. K. Rolov and V. E. Yurkevich, Physics of Blurred Phase Transitions (Rostov. Univ., Rostov, 1983) [in Russian].

    Google Scholar 

  8. 8

    G. A. Malygin, Phys. Usp. 44, 173 (2001).

    ADS  Article  Google Scholar 

  9. 9

    T. Yamamoto, K. Nozaki, and T. Hara, J. Phys. Chem. 92, 631 (1990).

    Article  Google Scholar 

  10. 10

    R. Popovitz-Biro, J. L. Wang, J. Majewski, E. Shavit, L. Leiserowitz, and M. Lahav, J. Am. Chem. Soc. 116, 1179 (1994).

    Article  Google Scholar 

  11. 11

    S. Abrahamson, G. Larsson, and E. Sydov, Acta Crystallogr. 13, 770 (1960).

    Article  Google Scholar 

  12. 12

    S. Amelincksx, Acta Crystallogr. 9, 217 (1956).

    Article  Google Scholar 

  13. 13

    I. M. Dawson, Brit. J. Appl. Phys. 4, 177 (1956).

    ADS  Article  Google Scholar 

  14. 14

    A. I. Kitaigorodskii, Molecular Crystals (Nauka, Moscow, 1971) [in Russian].

    Google Scholar 

  15. 15

    A. I. Kitaigorodskii, Organic Crystal Chemistry (Akad. Nauk SSSR, Moscow, 1955) [in Russian].

    Google Scholar 

  16. 16

    E. Segerman, Acta Crystallogr. 19, 789 (1965).

    Article  Google Scholar 

  17. 17

    A. E. Smith, J. Chem. Phys. 21, 2229 (1953).

    ADS  Article  Google Scholar 

  18. 18

    R. G. Snyder, J. Mol. Spectr. 7, 116 (1961).

    ADS  Article  Google Scholar 

  19. 19

    R. F. Holland and J. R. Nielsen, J. Mol. Spectrosc. 9, 436 (1962).

    ADS  Article  Google Scholar 

  20. 20

    J. L. Koenig, Spectroscopy of Polymers (Am. Chem. Soc., 1992).

  21. 21

    V. A. Marikhin, L. P. Myasnikova, E. I. Radovanova, B. Z. Volchek, and D. A. Medvedeva, Phys. Solid State 59, 331 (2017).

    ADS  Article  Google Scholar 

  22. 22

    M. G. Broadhurst, J. Res. Nat. Bur. Standard A 66, 241 (1962).

    Article  Google Scholar 

  23. 23

    R. E. Dickerson, H. B. Gray, and G. P. Haight, Chemical Principles (Benjamin/Cummings, Menio Park, CA, 1984).

    Google Scholar 

  24. 24

    S. R. Craig, G. P. Hastie, K. J. Roberts, and J. N. Sherwood, J. Mater. Chem. 4, 977 (1994).

    Article  Google Scholar 

  25. 25

    S. C. Nyburg and J. A. Potworowski, Acta Crystallogr., B 29, 347 (1973).

    Article  Google Scholar 

  26. 26

    S. C. Nyburg and H. Luth, Acta Crystallogr., B 28, 2992 (1972).

    Article  Google Scholar 

  27. 27

    V. Chevallier, D. Petitjean, V. Ruffier-Meray, and M. Dirand, Polymer 40, 5953 (1999).

    Article  Google Scholar 

  28. 28

    T. Malkin, Trans. Faraday Soc. 29, 977 (1933).

    Article  Google Scholar 

  29. 29

    T. Malkin, J. Chem. Soc. 133, 2796 (1931).

    Article  Google Scholar 

Download references

FUNDING

This work was supported by the Program of the Presidium of the Russian Academy of Sciences no. 32 “Nanostructures: physics, chemistry, biology, fundamentals of technologies” and the Russian Foundation for Basic Research (project code 16-03-00493А) using the Kurchatov synchrotron radiation source equipment.

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Correspondence to V. A. Marikhin.

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Translated by A. Bannov

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Marikhin, V.A., Dorovatovskii, P.V., Zubavichus, Y.V. et al. Study of Kinetics of Solid Phase Transition in Tetracosane С24Н50 by High-Resolution Synchrotron X-Ray Powder Diffraction. Phys. Solid State 61, 1128–1135 (2019). https://doi.org/10.1134/S1063783419060106

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