Advertisement

Physics of the Solid State

, Volume 61, Issue 6, pp 1128–1135 | Cite as

Study of Kinetics of Solid Phase Transition in Tetracosane С24Н50 by High-Resolution Synchrotron X-Ray Powder Diffraction

  • V. A. MarikhinEmail author
  • P. V. Dorovatovskii
  • Ya. V. Zubavichus
  • M. V. Baidakova
  • E. M. Ivan’kova
  • L. P. Myasnikova
POLYMERS
  • 42 Downloads

Abstract

Using the small-angle synchrotron X-ray diffraction method at the research facility “BELOK” of the Kurchatov synchrotron radiation source at the NRC Kurchatov Institute, it was shown that the first-order solid phase transition in tetracosane C24H50 passes according to a heterogeneous mechanism in a narrow temperature range ΔT ~ 1 K in accordance with the theory of diffuse phase transitions.

Notes

FUNDING

This work was supported by the Program of the Presidium of the Russian Academy of Sciences no. 32 “Nanostructures: physics, chemistry, biology, fundamentals of technologies” and the Russian Foundation for Basic Research (project code 16-03-00493А) using the Kurchatov synchrotron radiation source equipment.

REFERENCES

  1. 1.
    A. S. Fleischer, Thermal Energy Storage Using Phase Change Materials (Springer, Heidelberg, 2015).CrossRefGoogle Scholar
  2. 2.
    D. M. Small, The Physical Chemistry of Lipids (Plenum, New York, 1986).CrossRefGoogle Scholar
  3. 3.
    K. Mukherjee, Phys. Rep. 588, 1 (2015).ADSMathSciNetCrossRefGoogle Scholar
  4. 4.
    M. Dirand, M. Bouroukba, V. Chevallier, D. Petitjean, E. Behar, and V. Ruffier-Meray, J. Chem. Eng. Data 47, 115 (2002).CrossRefGoogle Scholar
  5. 5.
    V. M. Egorov, V. A. Marikhin, and L. P. Myasnikova, Polym. Sci., A 49, 1366 (2007).Google Scholar
  6. 6.
    V. M. Egorov, V. A. Marikhin, L. P. Myasnikova, and P. N. Yakushev, Phys. Solid State 59, 2070 (2017).ADSCrossRefGoogle Scholar
  7. 7.
    B. K. Rolov and V. E. Yurkevich, Physics of Blurred Phase Transitions (Rostov. Univ., Rostov, 1983) [in Russian].Google Scholar
  8. 8.
    G. A. Malygin, Phys. Usp. 44, 173 (2001).ADSCrossRefGoogle Scholar
  9. 9.
    T. Yamamoto, K. Nozaki, and T. Hara, J. Phys. Chem. 92, 631 (1990).CrossRefGoogle Scholar
  10. 10.
    R. Popovitz-Biro, J. L. Wang, J. Majewski, E. Shavit, L. Leiserowitz, and M. Lahav, J. Am. Chem. Soc. 116, 1179 (1994).CrossRefGoogle Scholar
  11. 11.
    S. Abrahamson, G. Larsson, and E. Sydov, Acta Crystallogr. 13, 770 (1960).CrossRefGoogle Scholar
  12. 12.
    S. Amelincksx, Acta Crystallogr. 9, 217 (1956).CrossRefGoogle Scholar
  13. 13.
    I. M. Dawson, Brit. J. Appl. Phys. 4, 177 (1956).ADSCrossRefGoogle Scholar
  14. 14.
    A. I. Kitaigorodskii, Molecular Crystals (Nauka, Moscow, 1971) [in Russian].Google Scholar
  15. 15.
    A. I. Kitaigorodskii, Organic Crystal Chemistry (Akad. Nauk SSSR, Moscow, 1955) [in Russian].Google Scholar
  16. 16.
    E. Segerman, Acta Crystallogr. 19, 789 (1965).CrossRefGoogle Scholar
  17. 17.
    A. E. Smith, J. Chem. Phys. 21, 2229 (1953).ADSCrossRefGoogle Scholar
  18. 18.
    R. G. Snyder, J. Mol. Spectr. 7, 116 (1961).ADSCrossRefGoogle Scholar
  19. 19.
    R. F. Holland and J. R. Nielsen, J. Mol. Spectrosc. 9, 436 (1962).ADSCrossRefGoogle Scholar
  20. 20.
    J. L. Koenig, Spectroscopy of Polymers (Am. Chem. Soc., 1992).Google Scholar
  21. 21.
    V. A. Marikhin, L. P. Myasnikova, E. I. Radovanova, B. Z. Volchek, and D. A. Medvedeva, Phys. Solid State 59, 331 (2017).ADSCrossRefGoogle Scholar
  22. 22.
    M. G. Broadhurst, J. Res. Nat. Bur. Standard A 66, 241 (1962).CrossRefGoogle Scholar
  23. 23.
    R. E. Dickerson, H. B. Gray, and G. P. Haight, Chemical Principles (Benjamin/Cummings, Menio Park, CA, 1984).Google Scholar
  24. 24.
    S. R. Craig, G. P. Hastie, K. J. Roberts, and J. N. Sherwood, J. Mater. Chem. 4, 977 (1994).CrossRefGoogle Scholar
  25. 25.
    S. C. Nyburg and J. A. Potworowski, Acta Crystallogr., B 29, 347 (1973).CrossRefGoogle Scholar
  26. 26.
    S. C. Nyburg and H. Luth, Acta Crystallogr., B 28, 2992 (1972).CrossRefGoogle Scholar
  27. 27.
    V. Chevallier, D. Petitjean, V. Ruffier-Meray, and M. Dirand, Polymer 40, 5953 (1999).CrossRefGoogle Scholar
  28. 28.
    T. Malkin, Trans. Faraday Soc. 29, 977 (1933).CrossRefGoogle Scholar
  29. 29.
    T. Malkin, J. Chem. Soc. 133, 2796 (1931).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • V. A. Marikhin
    • 1
    Email author
  • P. V. Dorovatovskii
    • 2
  • Ya. V. Zubavichus
    • 3
  • M. V. Baidakova
    • 1
  • E. M. Ivan’kova
    • 4
  • L. P. Myasnikova
    • 1
  1. 1.Ioffe InstituteSt. PetersburgRussia
  2. 2.National Research Center Kurchatov InstituteMoscowRussia
  3. 3.Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of SciencesNovosibirskRussia
  4. 4.Institute of High-Molecular Compounds, Russian Academy of Sciences St. PetersburgRussia

Personalised recommendations