Abstract
The melt method is used for synthesizing monodispersed spherical silica nanoparticles Gdx-SiyOz:Eu3+. The particle diameter is 450 nm, and the standard deviation does not exceed 5%. The nanoparticles have a line luminescence spectrum with a dominant band at 614 nm. The effect of a constant magnetic field up to 15 T on the intensity and shape of the luminescence spectra of Eu3+ ions is studied. It is shown that the obtained material has a stable photoluminescence, the intensity of which does not depend on the magnetic field in the entire studied range. The synthesized nanoparticles GdxSiyOz : Eu3+ are promising for use as a contrast agent for magnetic resonance tomography and luminescent marker.
Similar content being viewed by others
REFERENCES
Z. R. Stephen, F. M. Kievit, and M. Zhang, Mater. Today 14, 330 (2011).
Z. Zhou and Z.-R. Lu, Wiley Interdisc. Rev. Nanomed. Nanobiotechnol. 5, 1 (2013).
H. U. Ahmed, A. Kirkham, M. Arya, R. Illing, A. Freeman, C. Allen, and M. Emberton, Nat. Rev. Clin. Oncol. 6, 197 (2009).
P. Caravan, Chem. Soc. Rev. 35, 512 (2006).
S. E. Cowper, H. S. Robin, S. M. Steinberg, L. D. Su, S. Gupta, and P. E. le Boit, Lancet 356, 1000 (2000).
P. Marckmann, L. Skov, K. Rossen, A. Dupont, M. B. Damholt, J. G. Heaf, and H. S. Thomsen, J. Am. Soc. Nephrol. 17, 2359 (2006).
M. Rogosnitzky and S. Branch, Biometals 29, 365 (2016).
M. A. Sieber, P. Lengsfeld, T. Frenzel, S. Golfier, H. Schmitt-Willich, F. Siegmund, J. Walter, H.‑J. Weinmann, and H. Pietsch, Eur. Radiol. 18, 2164 (2008).
A. Hedlund, M. Ahrén, H. Gustafsson, N. Abrikossova, M. Warntjes, J.-I. Jönsson, K. Uvdal, and M. Engström, Int. J. Nanomed. 6, 3233 (2011).
G. H. Lee, Y. Chang, and T.-J. Kim, Eur. J. Inorg. Chem. 2012, 1924 (2012).
H. Wang, L. Zheng, C. Peng, R. Guo, M. Shen, X. Shi, and G. Zhang, Biomaterials 32, 2979 (2011).
D.-E. Lee, H. Koo, I. C. Sun, J. H. Ryu, K. Kim, and I. C. Kwon, Chem. Soc. Rev. 41, 2656 (2012).
D. J. Irvine, Nat. Mater. 10, 342 (2011).
C.-H. Huang and A. Tsourkas, Curr. Top. Med. Chem. 13, 411 (2013).
X. Tian, F. Yang, C. Yang, Y. Peng, D. Chen, J. Zhu, F. He, L. Li, and X. Chen, Int. J. Nanomed. 9, 4043 (2014).
J. Jung, M. A. Kim, J.-H. Cho, S. J. Lee, I. Yang, J. Cho, S. K. Kim, C. Lee, and J. K. Park, Biomaterials 33, 5865 (2012).
K. Binnemans, Chem. Rev. 109, 4283 (2009).
J. C. G. Bünzli, Chem. Rev. 110, 2729 (2010).
C. P. Montgomery, B. S. Murray, E. J. New, R. Pal, and D. Parker, Acc. Chem. Res. 42, 925 (2009).
N. M. K. Tse, D. F. Kennedy, N. Kirby, B. A. Moffat, B. W. Muir, R. A. Caruso, and C. J. Drummond, Adv. Healthcare Mater. 2, 836 (2013).
Y. Parganihaa, J. Kaura, N. Dubeya, V. Dubeyb, R. Shrivastavac, S. J. Dhobled, and H. C. Swart, Ceram. Int. 43, 9084 (2017).
S. L. Pinho, H. Faneca, C. F. Geraldes, M. H. Delville, L. D. Carlos, and J. Rocha, Biomaterials 33, 925 (2012).
W. Jiang, J. Zhang, W. Chen, P. Chen, J. Han, B. Xu, S. Zheng, Q. Guo, X. Liu, and J. Qiu, J. Appl. Phys. 116, 123103 (2014).
Y. Zhang, Q. Xiao, H. He, J. Zhang, G. Dong, J. Han, and J. Qiu, J. Mater. Chem. C 3, 10140 (2015).
P. Chen, H. Jia, J. Zhang, J. Han, X. Liu, and J. Qiu, J. Phys. Chem. C 119, 5583 (2015).
C.-C. Huang, W. Huang, C.-H. Su, C.-N. Feng, W.‑S. Kuoa, and C.-S. Yeh, Chem. Commun. 0, 3360 (2009).
E. Yu. Trofimova, D. A. Kurdyukov, Yu. A. Kukushkina, M. A. Yagovkina, and V. G. Golubev, Glass Phys. Chem. 37, 378 (2011).
E. Yu. Trofimova, D. A. Kurdyukov, S. A. Yakovlev, D. A. Kirilenko, Y. A. Kukushkina, A. V. Nashchekin, A. A. Sitnikova, M. A. Yagovkina, and V. G. Golubev, Nanotechnology 24, 155601 (2013).
D. A. Kurdyukov, D. A. Eurov, D. A. Kirilenko, J. A. Kukushkina, V. V. Sokolov, M. A. Yagovkina, and V. G. Golubev, Micropor. Mesopor. Mater. 223, 225 (2016).
E. Y. Stovpiaga, D. A. Kurdyukov, Y. A. Kukushkina, V. V. Sokolov, and M. A. Yagovkina, Glass Phys. Chem. 41, 316 (2015).
D. A. Eurov, D. A. Kurdyukov, D. A. Kirilenko, J. A. Kukushkina, A. V. Nashchekin, A. N. Smirnov, and V. G. Golubev, J. Nanopart. Res. 17, 82 (2015).
K. N. Orekhova, D. A. Eurov, D. A. Kurdyukov, V. G. Golubev, D. A. Kirilenko, V. A. Kravets, and M. V. Zamoryanskaya, J. Alloys Compd. 678, 434 (2016).
S. P. Feofilov, A. B. Kulinkin, D. A. Eurov, D. A. Kur-dyukov, and V. G. Golubev, Mater. Res. Express 1, 025019 (2014).
E. Yu. Stovpiaga, D. A. Eurov, D. A. Kurdyukov, A. N. Smirnov, M. A. Yagovkina, V. Yu. Grigorev, V. V. Romanov, D. R. Yakovlev, and V. G. Golubev, Phys. Solid State 59, 1623 (2017).
D. A. Eurov, D. A. Kurdyukov, A. V. Medvedev, D. A. Kirilenko, D. R. Yakovlev, and V. G. Golubev, Tech. Phys. Lett. 43, 716 (2017).
H. Kanithi, D. Blasiak, J. Lajewski, C. Berriaud, P. Ved-rine, and G. Gilgrass, IEEE Trans. Appl. Supercond. 24, 1 (2014).
P. R. Luijten and D. W. J. Klomp, Drug Discov. Today Technol. 8, 103 (2011).
FUNDING
This work was supported by the Russian Foundation for Basic Research (grant no. 15-52-12011) and the DFG in the framework of ICRC TRR 160.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by V. A. Alekseev
Rights and permissions
About this article
Cite this article
Eurov, D.A., Kurdyukov, D.A., Shornikova, E.V. et al. Monodispersed Spherical Nanoparticles GdxSiyOz:Eu3+ for Magnetic Resonance Tomography and Optical Imaging. Phys. Solid State 61, 627–631 (2019). https://doi.org/10.1134/S1063783419040103
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1063783419040103