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Physics of the Solid State

, Volume 60, Issue 12, pp 2424–2435 | Cite as

On Possible States of the Crystal Structure Preceding to a Phase Transition in Zn1 – xVxSe (0.01 ≤ x ≤ 0.10) Crystals

  • V. I. MaksimovEmail author
  • E. N. Maksimova
  • T. P. Surkova
  • A. P. Vokhmyanin
SEMICONDUCTORS
  • 17 Downloads

Abstract

The systematic new formations observed in the reciprocal lattice of the cubic structural modification of a II–VI compound are characterized using a detailed neutron diffraction study of bulk semiconducting ZnSe crystals with an increased vanadium content. Direct evidence that the additional sites k = (1/3 1/3 1/3) 2π/a (k is the wave vector and a is cubic unit cell parameter) observed by neutron scattering in the crystals, in the case when they belong to mutually penetrated rotated sublattices, contain a superstructure contribution formed by short-wave deformation, is obtained for the first time. This structure state is determined as a pretransition to the concentration fcc–hcp phase transformation, and the basis functions that allow one to analyze atomic displacements, the correlation between which create distortion-type superstructures, are indicated for the transition through one-arm channel, considering the transitions by the star of wave vector k5 of the fcc lattice.

Notes

ACKNOWLEDGMENTS

This work was performed in the framework of the state test by the themes (S.R. No. AAAA-A18-118020190112-8) and “Electron” (S.R. No. AAAA-A18-118020190098-5, using UNU “NMK IMP.”

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • V. I. Maksimov
    • 1
    Email author
  • E. N. Maksimova
    • 1
  • T. P. Surkova
    • 1
  • A. P. Vokhmyanin
    • 1
  1. 1.Mikheev Institute of Metal Physics, Ural Branch, Russian Academy of SciencesYekaterinburgRussia

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