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Anomalous Dependence of the Intensity of X-Ray Reflections of Cs2SO4 on the Crystallite Size and Shape

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Abstract

Detailed X-ray and electron microscopy analyses of Cs2SO4 powders consisting of sphere- and platelike crystallites have been carried out. It is established that the intensity distributions of X-ray reflections in both cases radically differ, with the position on the diffraction-angle axis retained in accordance with the PDF-2 database. Electron microscopy microdiffraction investigations of the orientation of developed surfaces of platelike crystallites revealed four different directions; however, these directions could not provide texture amplification of a number of observed (hkl) reflections. It is suggested that the intensity redistribution is based on the sphericity of X-ray waves incident on the sample.

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Authors and Affiliations

  1. Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    I. M. Shmyt’ko, V. V. Kedrov & A. S. Aronin

Authors
  1. I. M. Shmyt’ko
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  2. V. V. Kedrov
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  3. A. S. Aronin
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Correspondence to I. M. Shmyt’ko.

Additional information

Original Russian Text © I.M. Shmyt’ko, V.V. Kedrov, A.S. Aronin, 2018, published in Fizika Tverdogo Tela, 2018, Vol. 60, No. 2, pp. 383–389.

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Shmyt’ko, I.M., Kedrov, V.V. & Aronin, A.S. Anomalous Dependence of the Intensity of X-Ray Reflections of Cs2SO4 on the Crystallite Size and Shape. Phys. Solid State 60, 390–396 (2018). https://doi.org/10.1134/S1063783418020269

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  • DOI: https://doi.org/10.1134/S1063783418020269

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