Skip to main content
SpringerLink
Log in

Dipole ordering and ionic conductivity in NASICON-Type Na3Cr2(PO4)3 structures

  • Semiconductors
  • Published:
Physics of the Solid State Aims and scope Submit manuscript

Abstract

The aspects of structure, dipole ordering, and ionic conductivity of the Na3Cr2(PO4)3 crystal with the four polymorphic phases (α, α', β, and γ) have been investigated. The features of the α-Na3Cr2(PO4)3 crystal structure and its dipole ordering and relaxation polarization in the low-temperature α and α' phases have been refined. The occurrence of Na3Cr2(PO4)3 dipole ordering in the α and α' phases and high ionic conductivity in the β and γ phases is attributed to the structural changes in the rhombohedral [Me2(PO4)3]–33∞ crystal frame upon phase transformations α → α', α' → β, and β → γ. A model for explaining the dipole ordering and ionic conductivity phenomena in Na3Cr2(PO4)3 is proposed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. S. Nogay, Young Huh, and K. N. Yugay, Phys. Solid State 47, 1076 (2005).

    Article  ADS  Google Scholar 

  2. A. Nogai, V. B. Kalinin, S. Yu. Stefanovich, Yu. N. Venevtsev, and V. V. Gagulin, Zh. Neorg. Khim. 33, 747 (1988).

    Google Scholar 

  3. L. Vijayan, R. Cheruku, G. Govindaraj, and S. Rajagopan, Mater. Chem. Phys. 130, 862 (2011).

    Article  Google Scholar 

  4. L. B. Ellis and F. Linda, Curr. Opin. Solid State Mater. Sci. 16, 168 (2012).

    Article  ADS  Google Scholar 

  5. F. d’Yvoire, M. Pintard-Serépel, E. Bretey, and M. de la Rochér, Solid State Ionics, Nos. 9–10, 851 (1983).

    Article  Google Scholar 

  6. V. B. Kalinin, S. Yu. Stefanovich, and A. C. Nogai, Neorg. Mater. 22, 107 (1986).

    Google Scholar 

  7. A. R. Hippel, Dielectrics and Waves (Wiley, New York, 1954).

    Google Scholar 

  8. Yu. M. Poplavko, Physics of Insulators (Vyssh. Shkola, Kiev, 1980) [in Russian].

    Google Scholar 

  9. V. A. Efremov and V. B. Kalinin, Sov. Phys. Crystallogr. 23, 393 (1978).

    Google Scholar 

  10. V. B. Kalinin, B. I. Lazoryak, and S. Yu. Stefanovich, Sov. Phys. Crystallogr. 28, 154 (1983).

    Google Scholar 

  11. V. B. Kalinin, S. Yu. Stefanovich, R. R. Shifrina, and Yu. N. Venevtsev, Zh. Neorg. Khim. 31, 181 (1986).

    Google Scholar 

  12. S. A. Okonenko, S. Yu. Stefanovich, V. B. Kalinin, and Yu. N. Venevtsev, Sov. Phys. Solid State 20, 1647 (1978).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kazakh Agrotechnical University, Astana, 010000, Kazakhstan

    A. S. Nogai, D. E. Uskenbaev & A. A. Nogai

  2. Karpov Scientific and Research Physicochemical Institute, Moscow, 249033, Russia

    S. Yu. Stefanovich

  3. Moscow Technological University (MIREA), Moscow, 119454, Russia

    A. A. Bush

Authors
  1. A. S. Nogai
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. Yu. Stefanovich
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. A. Bush
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. D. E. Uskenbaev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. A. Nogai
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. S. Nogai.

Additional information

Original Russian Text © A.S. Nogai, S.Yu. Stefanovich, A.A. Bush, D.E. Uskenbaev, A.A. Nogai, 2018, published in Fizika Tverdogo Tela, 2018, Vol. 60, No. 1, pp. 25–32.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Nogai, A.S., Stefanovich, S.Y., Bush, A.A. et al. Dipole ordering and ionic conductivity in NASICON-Type Na3Cr2(PO4)3 structures. Phys. Solid State 60, 23–30 (2018). https://doi.org/10.1134/S1063783418010146

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063783418010146

Search

Navigation