Abstract
The effect of an increase in the coefficient of the grain-boundary diffusion upon recrystallization and superplastic deformation of submicrocrystalline (SMC) materials prepared by severe plastic deformation has been studied. It is shown that the coefficient of the grain-boundary diffusion of the SMC materials is dependent on the intensity of the lattice dislocation flow whose value is proportional to the rate of the grain boundary migration upon annealing of SMC metals or the rate of the intragrain deformation under conditions of superplastic deformation of SMC alloys. It is found that, at a high rate of grain boundary migrations and high rates of superplastic deformation, the intensity of the lattice dislocation flow bombarding grain boundaries of SMC materials is higher than the intensity of their diffusion accommodation, which leads to an increase in the coefficient of the grain-boundary diffusion and a decrease in the activation energy. The results of the numerical calculations agree well with the experimental data.
Similar content being viewed by others
References
V. M. Segal, I. J. Beyerlein, C. N. Tome, V. N. Chuvil’deev, and V. I. Kopylov, Fundamentals and Engineering of Severe Plastic Deformation (Nova Science, New York, 2010).
V. N. Chuvil’deev, O. E. Pirozhnikova, and A. V. Petryaev, Phys. Met. Metallogr. 92, 540 (2001).
V. N. Chuvil’deev, Nonequilibrium Grain Boundaries in Metals. Theory and Applications (Fizmatlit, Moscow, 2004) [in Russian].
S. V. Divinski, G. Reglitz, H. Rösner, Y. Estrin, and G. Wilde, Acta Mater. 59, 1974 (2011).
S. V. Divinski, G. Reglitz, I. S. Golovin, M. Peterlechner, R. Lapovok, Y. Estrin, and G. Wilde, Acta Mater. 82, 11 (2015).
C. Y. Yu, P. L. Sun, P. W. Kao, and C. P. Chang, Mater. Sci. Eng. A 366, 310 (2004).
H.-K. Kim, J. Mater. Sci. 39, 7107 (2004).
J. Stráská, M. Janeček, J. Čižek, J. Stráský, and B. Hadzima, Mater. Charact. 94, 69 (2014).
X. Molodova, G. Gottstein, M. Winning, and R. J. Hellmig, Mater. Sci. Eng. A 460–461, 204 (2007).
V. N. Chuvil’deev, T. G. Nieh, M. Yu. Gryaznov, A. N. Sysoev, and V. I. Kopylov, J. Alloys. Compd. 378, 253 (2004).
R. Kapoor and J. K. Chakravartty, Acta Mater. 55, 5408 (2007).
T. Fujita, Z. Horita, and T. G. Langdon, Mater. Sci. Eng. A 371, 241 (2004).
S. V. Divinski, J. Ribbe, D. Baither, G. Schmitz, G. Reglitz, H. Rösner, K. Sato, Y. Estrin, and G. Widle, Acta Mater. 57, 5706 (2009).
H. K. Kim and W. J. Kim, Mater. Sci. Eng. A 385, 300 (2004).
Yu. R. Kolobov, G. P. Grabovetskaya, K. V. Ivanov, and N. V. Girsova, Phys. Met. Metallogr. 91, 532 (2001).
V. N. Chuvil’deev, V. I. Kopylov, M. Yu. Gryaznov, A.N. Sysoev, B. V. Ovsyannikov, and A. A. Flyagin, Dokl. Phys. 53, 584 (2008).
H. B. Geng, S. B. Kang, and B. K. Min, Mater. Sci. Eng. A 373, 229 (2004).
M. Yu. Gryaznov, A. N. Sysoev, and V. N. Chuvil’deev, Phys. Met. Metallogr. 87, 163 (1999).
I. S. Golovin, Phys. Met. Metallogr. 110, 405 (2010).
D. Prokoshkina, L. Klinger, A. Moros, G. Wilde, E. Rabkin, and S. V. Divinski, Acta Mater. 69, 314 (2014).
V. N. Chuvil’deev, Phys. Met. Metallogr. 81, 463 (1996).
H. J. Frost and M. F. Ashby, Deformation-Mechanism Maps: The Plasticity and Creep of Metals and Ceramics (Pergamon, Oxford, 1982).
A. R. Ubbelohde, Molten State of Matter: Melting and Crystal Structure (Wiley, New York, 1978).
S. S. Gorelik, S. V. Dobatkin, and L. M. Kaputkina, Recrystallization of Metals and Alloys (MISiS, Moscow, 2005) [in Russian].
A. V. Piskunov, V. N. Chuvil’deev, and Yu. G. Lopatin, in Proceedings of the 5th All-Russia Conference of Students and Young Scientists VNKSF-15, Yekaterinburg, Kemerovo, March 26–Apr. 2, 2009, p. 759.
T. G. Nieh, D. Wadsworth, and O. D. Sherby, Superplasticity in Metals and Ceramics (Cambridge Univ. Press, Cambridge, 1997).
V. N. Perevezentsev, V. V. Rybin, and V. N. Chuvil’deev, Acta Met. Mater. 40, 887 (1992).
T. G. Langdon, J. Mater. Sci. 44, 5998 (2009).
V. N. Chuvil’deev and A. V. Petryaev, Phys. Met. Metallogr. 89, 122 (2000).
M. Furukawa, A. Utsunomiya, K. Matsubara, Z. Horita, and T. G. Langdon, Acta Mater. 49, 3829 (2001).
F. Musin, R. Kaibyshev, Y. Motohashi, and G. Itoh, Scripta Mater. 50, 511 (2004).
S. V. Zemskii, N. E. Fomin, and G. K. Mal’tseva, Fiz. Khim. Obrab. Mater. 4, 91 (1978).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.N. Chuvil’deev, A.V. Nokhrin, O.E. Pirozhnikova, M.Yu. Gryaznov, Yu.G. Lopatin, M.M. Myshlyaev, V.I. Kopylov, 2017, published in Fizika Tverdogo Tela, 2017, Vol. 59, No. 8, pp. 1561–1569.
Rights and permissions
About this article
Cite this article
Chuvil’deev, V.N., Nokhrin, A.V., Pirozhnikova, O.E. et al. Changes in the diffusion properties of nonequilibrium grain boundaries upon recrystallization and superplastic deformation of submicrocrystalline metals and alloys. Phys. Solid State 59, 1584–1593 (2017). https://doi.org/10.1134/S1063783417080066
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1063783417080066