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Order–order transition structural state in titanium monoxide TiO1.0

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Abstract

A new class of defect structures in which point defects of a crystal lattice simultaneously occupy sites of two different superstructures is proposed. The formation of these structural modifications is due to a second-order order–order phase transition that does not occur to the end. The allowable relation between the long-range order parameters in the structural modification formed by a combination of the monoclinic (M 5 X 5)mon (space group C2/m (A2/m)) and the cubic (M 5 X 5)cub (space group Pm3m) of the superstructures is studied using an atom–vacancy ordering in titanium monoxide TiO1.0. The thermodynamic calculations show that the proposed structural modification is equilibrium and must form instead of assumed high-temperature cubic phase (Ti5O5)cub.

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References

  1. A. I. Gusev, A. A. Rempel, and A. J. Magerl, Disorder and Order in Strongly Nonstoichiometric Compounds: Transition Metal Carbides, Nitrides and Oxides (Springer-Verlag, Berlin, 2001).

    Book  Google Scholar 

  2. V. Bragaglia, F. Arciprete, W. Zhang, A. M. Mio, E. Zallo, K. Perumal, A. Giussani, S. Cecchi, J. E. Boschker, H. Riechert, S. Privitera, E. Rimini, R. Mazzarello, and R. Calargo, Sci. Rep. 6, 23843 (2016).

    Article  ADS  Google Scholar 

  3. C. Xie, A. R. Oganov, D. Li, T. T. Debela, N. Liu, D. Dong, and Q. Zeng, Phys. Chem. Chem. Phys. 18, 12299 (2016).

    Article  Google Scholar 

  4. X. Chong, Y. Jiang, R. Zhou, and J. Feng, RSC Adv. 4, 44959 (2014).

    Article  Google Scholar 

  5. A. I. Gusev, J. Exp. Theor. Phys. 120 (5), 851 (2015).

    Article  ADS  Google Scholar 

  6. A. A. Valeeva, S. Z. Nazarova, and A. A. Rempel, JETP Lett. 101 (4), 258 (2015).

    Article  ADS  Google Scholar 

  7. A. I. Gusev, J. Exp. Theor. Phys. 120 (1), 91 (2015).

    Article  ADS  MathSciNet  Google Scholar 

  8. A. I. Gusev, A. S. Kurlov, I. A. Bobrikov, and A. M. Balagurov, JETP Lett. 102 (3), 154 (2015).

    Article  ADS  Google Scholar 

  9. D. Watanabe, J. R. Castles, A. Jostsons, and A. S. Marlin, Nature (London) 210, 934 (1966).

    Article  ADS  Google Scholar 

  10. D. Watanabe, J. R. Castles, A. Jostsons, and A. S. Marlin, Acta Crystallogr. 23, 307 (1967).

    Article  Google Scholar 

  11. E. Hilti, Naturwissenschaften 55, 130 (1968).

    Article  ADS  Google Scholar 

  12. M. D. Banus, T. B. Reed, and A. J. Strauss, Phys. Rev. B: Solid State 5, 2775 (1972).

    Article  ADS  Google Scholar 

  13. A. A. Valeeva, A. A. Rempel’, and A. I. Gusev, JETP Lett. 71 (11), 460 (2000).

    Article  ADS  Google Scholar 

  14. A. A. Valeeva, A. A. Rempel’, and A. I. Gusev, Inorg. Mater. 37 (6), 603 (2001).

    Article  Google Scholar 

  15. A. A. Valeeva, G. Tang, A. I. Gusev, and A. A. Rempel, JETP Lett. 77 (1), 25 (2003).

    Article  ADS  Google Scholar 

  16. A. A. Valeeva, G. Tang, A. I. Gusev, and A. A. Rempel’, Phys. Solid State 45 (1), 87 (2003).

    Article  ADS  Google Scholar 

  17. A. A. Valeeva and A. I. Gusev, Phys. Solid State 48 (9), 1689 (2006).

    Article  ADS  Google Scholar 

  18. A. I. Gusev and A. A. Valeeva, JETP Lett. 96 (6), 364 (2012).

    Article  ADS  Google Scholar 

  19. A. I. Gusev, J. Exp. Theor. Phys. 117 (2), 293 (2013).

    Article  ADS  Google Scholar 

  20. A. I. Gusev, J. Solid State Chem. 199, 181 (2013).

    Article  ADS  Google Scholar 

  21. J. B. Goodenough, Phys. Rev. B: Solid State 5, 2764 (1972).

    Article  ADS  Google Scholar 

  22. J. Graciani, A. Márquez, and J. F. Sanz, Phys. Rev. B: Condens. Matter 72, 054117 (2005).

    Article  ADS  Google Scholar 

  23. M. G. Kostenko, A. V. Lukoyanov, V. P. Zhukov, and A. A. Rempel, J. Solid State Chem. 204, 146 (2013).

    Article  ADS  Google Scholar 

  24. M. G. Kostenko, A. A. Rempel, S. V. Sharf, and A. V. Lukoyanov, JETP Lett. 102 (2), 85 (2015).

    Article  ADS  Google Scholar 

  25. A. A. Rempel and A. I. Gusev, Phys. Status Solidi B 160, 389 (1990).

    Article  ADS  Google Scholar 

  26. M. G. Kostenko and A. A. Rempel’, Phys. Solid State 53 (9), 1909 (2011).

    Article  ADS  Google Scholar 

  27. M. G. Kostenko, A. A. Rempel, and A. V. Lukoyanov, J. Exp. Theor. Phys. 116 (6), 945 (2013).

    Article  ADS  Google Scholar 

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Authors and Affiliations

  1. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, 620990, Russia

    M. G. Kostenko & A. A. Rempel

  2. Institute of Mathematics and Mechanics, Ural Branch, Russian Academy of Sciences, Yekaterinburg, 620049, Russia

    S. V. Sharf

Authors
  1. M. G. Kostenko
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  2. S. V. Sharf
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  3. A. A. Rempel
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Correspondence to A. A. Rempel.

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Original Russian Text © M.G. Kostenko, S.V. Sharf, A.A. Rempel, 2017, published in Fizika Tverdogo Tela, 2017, Vol. 59, No. 6, pp. 1167–1172.

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Kostenko, M.G., Sharf, S.V. & Rempel, A.A. Order–order transition structural state in titanium monoxide TiO1.0 . Phys. Solid State 59, 1190–1195 (2017). https://doi.org/10.1134/S1063783417060129

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  • DOI: https://doi.org/10.1134/S1063783417060129

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