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Determination of charge states of cobalt ions in nanostructured GdBaCo2O5.5 cobaltites by means of X-ray absorption spectroscopy

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Abstract

X-ray absorption spectroscopy has been applied for a characterization of charge states of cobalt ions of nanostructured GdBaCo2O5.5 complex oxides. The analysis of experimental and theoretical data has allowed establishing a reduction in the oxidation degree from Co3+ to Co2+ for a part of cobalt ions in GdBaCo2O5.5 nanoceramics obtained by torsion under pressure.

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Authors and Affiliations

  1. Miheev Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia

    V. V. Mesilov, S. N. Shamin, S. V. Naumov, S. V. Telegin, B. A. Gizhevskii & V. R. Galakhov

  2. Ural State University of Railway Transport, Yekaterinburg, Russia

    M. S. Udintseva

Authors
  1. V. V. Mesilov
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  2. M. S. Udintseva
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  3. S. N. Shamin
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  4. S. V. Naumov
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  5. S. V. Telegin
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  6. B. A. Gizhevskii
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  7. V. R. Galakhov
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Correspondence to V. V. Mesilov.

Additional information

Original Russian Text © V.V. Mesilov, M.S. Udintseva, S.N. Shamin, S.V. Naumov, S.V. Telegin, B.A. Gizhevskii, V.R. Galakhov, 2017, published in Fizika Tverdogo Tela, 2017, Vol. 59, No. 4, pp. 810–815.

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Mesilov, V.V., Udintseva, M.S., Shamin, S.N. et al. Determination of charge states of cobalt ions in nanostructured GdBaCo2O5.5 cobaltites by means of X-ray absorption spectroscopy. Phys. Solid State 59, 829–834 (2017). https://doi.org/10.1134/S1063783417040151

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  • DOI: https://doi.org/10.1134/S1063783417040151

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