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Spin state of Co3+ ions in EuBaCo2–x O5.5–δ in the paramagnetic temperature range

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Abstract

The magnetic studies of EuBaCo2O5.50, EuBaCo1.93O5.40, and EuBaCo1.90O5.36 have been performed. Layered cobaltites EuBaCo2–x O5.5–δ demonstrated the ferrimagnetic ordering in the temperature range 200 K < T < 650 K. The ferromagnetic Curie temperature T C almost did not change as the number of Co3+–O–Co3+ bonds decreased. The contributions of the ferro- and antiferromagnetic interactions were nearly the same and determine the relationship T C > T N and T C < T N. At T > T C, the antiferromagnetic order was retained in the EuBaCo1.90O5.36. As temperature increased, EuBaCo2–xO5.5–δ conserved the IS state in pyramids, and gradual LS → IS → HS transitions occurred in octahedron sites. The increase in the effective magnetic moment μeff in EuBaCo1.90O5.36 at T > 580 K demonstrated the transition of Co3+ ions to the HS state at lower temperatures as compared to the EuBaCo2O5.50 stoichiometric composition, and the structural distortions and the increase in the unit cell volume favored to this transition.

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References

  1. A. A. Taskin, A. N. Lavrov, and Yoichi Ando, Phys. Rev. B: Condens. Matter 71, 134414 (2005).

    Article  ADS  Google Scholar 

  2. B. Raveau, M. D. Motin Seikh, V. Pralong, and V. Caignaert, Bull. Mater. Sci. 32, 305 (2009).

    Article  Google Scholar 

  3. C. Martin, A. Maignan, D. Pelloquin, N. Nguyen, and B. Raveau, Appl. Phys. Lett. 71, 1421 (1997).

    Article  ADS  Google Scholar 

  4. J. B. Goodenough, Magnetism and the Chemical Bond (Wiley, New York, 1963; Metallurgiya, Moscow, 1966).

    Google Scholar 

  5. M. A. Korotin, S. Yu. Ezhov, I. V. Solovyev, V. I. Anisimov, D. I. Khomskii, and G. A. Sawatzky, Phys. Rev. B: Condens. Matter 54, 5309 (1996).

    Article  ADS  Google Scholar 

  6. T. Sarkar, V. Pralong, and B. Raveau, Phys. Rev. B: Condens. Matter 83, 214428 (2011).

    Article  ADS  Google Scholar 

  7. B. Raveau, Ch. Simon, V. Caignaert, V. Pralong, and F. X. Lefevre, J. Phys.: Condens. Matter 18, 10237 (2006).

    ADS  Google Scholar 

  8. A. K. Kundu, V. Pralong, B. Raveau, and V. Caignaert, J. Mater. Sci. 46, 681 (2011).

    Article  ADS  Google Scholar 

  9. S. V. Telegin, S. V. Naumov, O. G. Reznitskikh, and E. I. Patrakov, Phys. Solid State 57 (11), 2290 (2015).

    Article  ADS  Google Scholar 

  10. M. Respaud, C. Frontera, J. L. García-Muñoz, M. A. G. Aranda, B. Raquet, J. M. Broto, H. Rakoto, M. Goiran, A. Llobet, and J. Rodríguez-Carvajal, Phys. Rev. B: Condens. Matter 64, 214401 (2001).

    Article  ADS  Google Scholar 

  11. C. Frontera, J. L. Garcia-Munoz, A. Llobet, and M. A. G. Aranda, Phys. Rev. B: Condens. Matter 65, 180405 (2002).

    Article  ADS  Google Scholar 

  12. J. Smith and H. P. J. Wijn, Ferrites (Philips Technical Library, Eindhoven, The Netherlands, 1959; Inostrannaya Literatura, Moscow, 1962).

    Google Scholar 

  13. J. H. Van Vleck, The Theory of Electric and Magnetic Susceptibilities (Oxford University Press, Oxford, 1952).

    MATH  Google Scholar 

  14. C. Zobel, M. Kriener, D. Bruns, J. Baier, M. Grüninger, T. Lorenz, P. Reutler, and A. Revcolevschi, Phys. Rev. B: Condens. Matter 66, 020402(R) (2002).

  15. Y. Moritomo, T. Akimoto, M. Takeo, A. Machida, E. Nishibori, M. Takata, M. Sakata, K. Ohoyama, and A. Nakamura, Phys. Rev. B: Condens. Matter 61, R13325 (2000).

  16. H. Kubo, K. Zenmyo, M. Itoh, N. Nakayama, T. Mizota, and Y. Ueda, J. Magn. Magn. Mater. 272–276, 581 (2004).

    Article  Google Scholar 

  17. T. I. Arbuzova, S. V. Telegin, S. V. Naumov, E. I. Patrakov, and O. G. Reznitskih, Solid State Phenom. 215, 83 (2014).

    Article  Google Scholar 

  18. G. Aurelio, J. Curiale, R. D. Sánchez, and G. J. Cuello, Physica B (Amsterdam) 398, 223 (2007).

    Article  ADS  Google Scholar 

  19. D. D. Khalyavin, Phys. Rev. B: Condens. Matter 72, 134408 (2005).

    Article  ADS  Google Scholar 

  20. D. D. Khalyavin, D. N. Argyriou, U. Amann, A. A. Yaremchenko, and V. V. Kharton, Phys. Rev. B: Condens. Matter 75, 134407 (2007).

    Article  ADS  Google Scholar 

  21. S. Roy, I. S. Dubenko, M. Khan, E. M. Condon, J. Craig, and N. Ali, Phys. Rev. B: Condens. Matter 71, 024419 (2005).

    Article  ADS  Google Scholar 

  22. M. Soda, Y. Yasui, T. Fujita, M. Sato, and K. Kakurai, J. Phys. Soc. Jpn. 72, 1729 (2003).

    Article  ADS  Google Scholar 

  23. Yu. P. Chernenkov, V. P. Plakhty, V. I. Fedorov, S. N. Barilo, S. V. Shiryaev, and G. L. Bychkov, Phys. Rev. B: Condens. Matter 71, 184105 (2005).

    Article  ADS  Google Scholar 

  24. H. Luetkens, M. Stingaciu, Yu. G. Pashkevich, K. Conder, E. Pomjakushina, A. A. Gusev, K. V. Lamonova, P. Lemmens, and H.-H. Klauss, Phys. Rev. Lett. 101, 017601 (2008).

    Article  ADS  Google Scholar 

  25. F. Fauth, E. Suard, V. Caignaert, and I. Mirebeau, Phys. Rev. B: Condens. Matter 66, 184421 (2002).

    Article  ADS  Google Scholar 

  26. H. Kusuya, A. Machida, Y. Moritomo, K. Kato, E. Nishibori, M. Takata, M. Sakata, and A. Nakamura, J. Phys. Soc. Jpn. 70, 3577 (2001).

    Article  ADS  Google Scholar 

  27. W. R. Flavell, A. G. Thomas, D. Tsoutsou, A. K. Mallick, M. North, E. A. Seddon, C. Cacho, A. E. R. Malins, S. Patel, R. L. Stockbauer, R. L. Kurtz, P. T. Sprunger, S. N. Barilo, S. V. Shiryaev, and G. L. Bychkov, Phys. Rev. B: Condens. Matter 70, 224427 (2004).

    Article  ADS  Google Scholar 

  28. R. R. Heikes, R. C. Miller, and R. Mazelsky, Physica (Amsterdam) 30, 1600 (1964).

    Article  ADS  Google Scholar 

  29. P. M. Raccah and J. B. Goodenough, Phys. Rev. 155, 932 (1967).

    Article  ADS  Google Scholar 

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Authors and Affiliations

  1. Institute of Metal Physics. Ural Branch, Russian Academy of Sciences, ul. S. Kovalevskoi 18, Yekaterinburg, 620990, Russia

    T. I. Arbuzova, S. V. Naumov & S. V. Telegin

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  1. T. I. Arbuzova
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  2. S. V. Naumov
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  3. S. V. Telegin
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Correspondence to T. I. Arbuzova.

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Original Russian Text © T.I. Arbuzova, S.V. Naumov, S.V. Telegin, 2017, published in Fizika Tverdogo Tela, 2017, Vol. 59, No. 3, pp. 517–522.

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Arbuzova, T.I., Naumov, S.V. & Telegin, S.V. Spin state of Co3+ ions in EuBaCo2–x O5.5–δ in the paramagnetic temperature range. Phys. Solid State 59, 532–537 (2017). https://doi.org/10.1134/S1063783417030040

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